Preparation of Ag nanoparticles termini‐protected side‐chain liquid crystalline azobenzene polymers by RAFT polymerization

A new synthetic approach to prepare Ag nanoparticles protected side‐chain liquid crystalline (LC) azobenzene polymers was reported. It is based on the reduction of silver ions in presence of a LC polymer polymerized by RAFT. The formation of Ag colloidal nanoparticles was confirmed by TEM and UV analysis. At the same time, according to the results of DSC, XPS, and FTIR spectra, Ag nanoparticles were protected by the side‐chain LC azobenzene polymers through surface attachment interactions between thiol groups and Ag. The out‐plane orientation of side‐chain LC is confirmed by surface‐enhanced Raman spectra analysis and scanning near‐field optical microscope, resulting from the large electromagnetic field arising from the excitation of surface plasmon polariton of Ag nanoparticles. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5380–5386, 2007     

New technique of processing highly oriented poly(vinylidene fluoride) films exclusively in the β phase

Oriented β‐phase films were obtained by utilizing two different techniques: conventional uniaxial drawing at 80 °C of predominantly α‐phase films, and by drawing almost exclusively β‐phase films obtained by crystallization at 60 °C from dimethylformamide (DMF) solution with subsequent pressing. Wide angle X‐ray diffraction (WAXD) and pole figure plots showed that with the conventional drawing technique films oriented at a ratio (R) of 5 still contained about 20% of phase α, a crystallinity degree of 40% and β‐phase crystallographic c ‐axis orientation factor of 0.655. Drawing at 90 °C and with R = 4 of originally β‐phase films results in exclusively β‐phase films with crystallinity degree of 45% and orientation factor of 0.885. Crystalline phase, crystallinity degree, and crystallographic c‐axis orientation factor of both phases were also determined for α‐phase oriented films obtained by drawing α‐phase films at 140 °C. For films drawn at 140 °C the α to β phase transition drops to about 22%. Reduction in crystallinity degree with increasing R is more pronounced at draw temperature of 140 °C compared with 80 °C. Moreover, for both phases the c ‐axis orientation parallel to the draw direction is higher at draw temperature of 140 °C than at 80 °C. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2793–2801, 2007     

Remarks on the second neighborhood problem

The second neighborhood conjecture of Seymour asserts that for any orientation G = (V,E), there exists a vertex υ ∈ V so that |N⁺(υ)| ≤ |N⁺⁺(υ)|. The conjecture was resolved by Fisher for tournaments. In this article, we prove the second neighborhood conjecture for several additional classes of dense orientations. We also prove some approximation results, and reduce an asymptotic version of the conjecture to a finite case. © 2007 Wiley Periodicals, Inc. J Graph Theory 55: 208–220, 2007     

互相关函数在几何量测量中的应用

以汽车转向器中变速比齿扇节曲线的测量为例，介绍利用互相关函数找定基准的原理及其实现方法。     

用于纳米生物膜层厚度测试的光纤生物传感器

研制出光纤感应生物传感器,用以测试nm级的生物膜层的厚度.给出了测试的实现过程、实验结果和提高信噪比的方法,并与表面等离子体共振(SPR)技术进行了比较.     

Miscibility level and mechanical characterization of blends of two liquid‐crystalline polymers based on p‐hydroxybenzoic acid

Injection‐molded blends composed of two liquid‐crystalline polymers (LCPs) based on 60/40 p‐hydroxybenzoic acid/ethylene terephthalate (R3) and 73/27 p‐hydroxybenzoic acid/2,6‐hydroxynaphthoic acid (VA) copolymers, respectively, were obtained across the whole composition range. The two amorphous phases of the blends contained only slight amounts of the minority component, and the occurrence of some chemical reaction, mainly at high VA contents, was detected by Fourier transform infrared. Synergisms in the modulus of elasticity and in the tensile strength were seen in most of the blend compositions. The largest synergism was in the 50/50 R3/VA blend, which showed a modulus of elasticity 26% higher than that of either of the two components and a 17% positive deviation in the tensile strength with respect to the rule of mixtures. The different orientation of the LCPs in the blends explains the differences in the mechanical behavior. However, contrary to previous works on LCP blends and despite the almost complete immiscibility, the observed negative volume of mixing appears to be the main parameter that determines the synergistic mechanical behavior. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1022–1032, 2003     

The theory of non-linear molecular orientation and stress in polymer fluids

Non-linear stress, and orientation characteristics for polymer fluids (melts, solutions) composed of chain macromolecules of finite length have been derived. Freelyjointed chains with inverse Langevin statistics have been assumed, and their behaviour in potential hydrodynamic fields analyzed. Numerical calculations have been performed for uniaxial extensional flow in a wide range of flow rates (and stresses). In the range of small stresses, orientation is a linear function of stress. At higher stresses, orientation factor levels off, asymptotically approaching unity.Flow orientation characteristics significantly differ from those derived from affine deformation of polymer networks. This difference is a natural consequence of constraints imposed by network junctions on chain deformation.This work is dedicated to Professor Hanns-Georg Kilian on his 60th birthday in appreciation of his contribution to Polymer Physics.     

高分子材料注塑固化阶段的残余应力分析

在结晶性高分子材料注塑过程的固化阶段，温度分布、材料细观结构和应力应变之间相互耦合，因而其变化规律非常复杂．本文在井上等人考虑材料细观结构变化的金属热加工工艺应力分析［３～６］的基础上，发展了一套用于高分子注塑固化阶段残余应力分析的本构描述和有限元分析方法．在本构模型中，同时考虑了温度变化、结晶和“冻结取向”对变形的贡献．     

Local fracture resistance based on microstructural efficiency concept and simulation of injection molding

Local fracture resistance (FR) of short (SGF) and discontinuous long glass fibre (LGF) reinforced polypropylene (PP) was predicted using the ‘microstructural efficiency concept’ together with a simulation program for fibre orientation in injection molding. The ‘microstructural efficiency concept’ describes the relation between microstructural parameters such as the fibre content, the fibre aspect ratio and the processing (injection molding) induced layer structure taking also into account the local fibre orientation. The local fibre orientation in injection molding was predicted with the MOLDFLOW^®-software. The predicted local FR was compared with the measured one, which was determined by using compact tension samples and linear elastic fracture mechanics (LEFM). The comparison showed, that for SGF-PP good consistence between the predicted and measured FR existed, for LGF-PP the discrepancy was higher. Yet for both materials, the ‘microstructural efficiency concept’ together with the results obtained from the simulation of the fibre orientation can be used for FR prediction of an injection molded workpiece.     

一种通过改进Canny算子提取光弹条纹骨架线的方法

光弹性法是确定应力集中系数的有效手段，在实际工程中应力参数都是通过分析光弹干涉条纹图获得的，由于光弹干涉条纹图的复杂性，且影响成像质量的因素较多，因此如何从光弹干涉条纹图中撇开其复杂性，较高精度的提取骨架线，是一项较困难的工作，本文提出一种由改进的Canny算子对条纹方位图进行直接运算提取光弹条纹骨架线的算法，实验表明此方法对光弹条纹图很有效。