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101.
沿垂等温平板的自然对流问题的近似解析解 总被引:1,自引:0,他引:1
本文用加权残值得到了沿垂等温平板的自然对流问题的近似解析解。和已有准确解的比较表明,在平板表面附近,近似解有很好的精度,而且速度场的精度比温度场更好一些。文末还对配域法的准收敛问题作了说明。 相似文献
102.
Rivelino M. Cavalcante Márcia V.F. de Andrade Rozane V. Marins Lincoln D.M. Oliveira 《Microchemical Journal》2010,96(2):337-343
An analytical protocol combining a headspace technique with gas chromatography and detection by photoionization detector and flame ionization detector (HS-GC-PID-FID) was developed. This procedure was used to measure volatile organic compounds (VOCs) in environmental aqueous matrices and was applied in determination of VOCs on the coast of Fortaleza, Brazil. At optimum operating conditions, analytical figures of merit such as linearity (R ranged from 0.9983 to 0.9993), repeatability (5.62 to 9.63% and 0.02 to 0.19% for the quantitative and qualitative analyses, respectively), detection limits (0.22 to 7.48 μg L−1) and sensibility were estimated. This protocol favors a fast sampling/sample preparation (in situ), minimizes the use of laboratory material, eliminates the matrix effect from environmental samples, and can be applied to river, estuarine and oceanic waters. The advantage of detectors in series is that a low sensitivity in detection in one is compensated by the other. Toluene was the most abundant VOC in the studied area, with an average concentration of 1.63 μg L−1. It was followed by o-xylene (1.15 μg L−1), trichloroethene (1.08 μg L−1), benzene (0.86 μg L−1), ethylbenzene (0.74 μg L−1), carbon tetrachloride (0.55 μg L−1), m/p-xylene (0.48 μg L−1) and tetrachloroethene (0.46 μg L−1), compounds which are very commonly detected in urban runoff from most cities. The results of the VOC distribution showed that port activity was not the main source of VOCs along the Fortaleza Coast, but that the contribution from urban runoff seemed more significant. 相似文献
103.
Andrea Speltini Michela Sturini Federica Maraschi Antonella Profumo 《Journal of separation science》2010,33(8):1115-1131
The aim of this review is to provide a general overview on the analytical methods proposed in the last decade for trace fluoroquinolone (FQ) determination in environmental waters. A large number of studies have been developed on this topic in reason of the importance of their monitoring in the studies of environmental mobility and potential degradation pathways. Every step of the analysis has been carefully considered, with a particular attention to sample preparation, in relationship with the problems involved in the analysis of real matrices. The different strategies to minimise interference from organic matter and to achieve optimal sensitivity, especially important in those samples with lower FQ concentrations, were also highlighted. Results and progress in this field have been described and critically commented. Moreover, a worldwide overview on the presence of FQs in the environmental waters has been reported. 相似文献
104.
Riin Rebane Ivo LeitoSergei Yurchenko Koit Herodes 《Journal of chromatography. A》2010,1217(17):2747-2757
Sudan dyes are a family of lipophilic azo dyes, extensively used in industrial and scientific applications but banned for use as food colorants due to their carcinogenicity. Due to the continuing illicit use of Sudan dyes as food colorants their determination in different food matrices – especially in different chilli and tomato sauces and related products – has during the recent years received increasing attention all over the world. This paper critically reviews the published determination methods of Sudan I–IV dyes. LC–UV–vis and LC–MS are the dominating methods for analysis of Sudan I–IV dyes. Sudan dyes are usually found in food at mg kg−1 levels at which it may be necessary to use a preconcentration step in order to attain the desired detection limits. Liquid–solid extraction is the dominating sample preparation procedure. In recent years it has been supplemented by ultrasonic-assisted extraction and pressurized liquid extraction. Various solid phase extraction types have been used for sample cleanup. The large majority of works use conventional C18 columns and conventional LC eluents. Traditionally the UV–vis absorbance detection has been the most frequently used. In the recent years MS detection is applied more and more often as it offers more reliable identification possibilities. 相似文献
105.
Anna Moosmann Jessica Christel Heiner Boettinger Egbert Mueller 《Journal of chromatography. A》2010,1217(2):209-215
The effect of PEGylation on cation exchange chromatography was studied with poly(ethylene glycol) of different chain lengths (5 kDa, 10 kDa and 30 kDa) using lysozyme as a model system. A stable binding via reduction of a Schiff base was formed during random PEGylation on lysine residues with methoxy-PEG-aldehyde. A purification method for PEGylated proteins using cation exchange chromatography was developed, and different isoforms of mono-PEGylated lysozyme were isolated. TSKgel SP-5PW and Toyopearl GigaCap S-650M showed the best performance of all tested cation exchange resins, and the separation of PEGylated lysozyme could be also scaled up to semi-preparative level. Size-exclusion chromatography, SDS-PAGE and MALDI-TOF mass spectrometry were used for analysis. Separated mono-PEGylated lysozyme of different sizes was used to determine dynamic binding capacities (DBC) and selectivity of cation exchange chromatography resins. An optimization of binding conditions resulted in a more than 20-fold increase of DBC for Toyopearl GigaCap S-650M with 30 kDa mono-PEGylated lysozyme. 相似文献
106.
107.
Leonid A. Dombrovsky Jaona H. Randrianalisoa Wojciech Lipiński 《Journal of Quantitative Spectroscopy & Radiative Transfer》2011,112(12):1987-1994
A two-step approximate analytical solution for the normal emittance of a plane layer of an absorbing, scattering and refracting medium is derived analytically. The analysis is based on the transport approximation and the two-step solution method for radiative transfer. The high accuracy of the approximate solution, examined by comparing its results to those obtained independently by the discrete ordinates and Monte Carlo methods, makes it suitable for application in combined experimental-analytical studies to identify selected spectral radiative properties of dispersed media in the range of semi-transparency. 相似文献
108.
The purpose of this study was to demonstrate a simple and fast method for solving the time-dependent Bloch equations. First, the time-dependent Bloch equations were reduced to a homogeneous linear differential equation, and then a simple equation was derived to solve it using a matrix operation. The validity of this method was investigated by comparing with the analytical solutions in the case of constant radiofrequency irradiation. There was a good agreement between them, indicating the validity of this method. As a further example, this method was applied to the time-dependent Bloch equations in the two-pool exchange model for chemical exchange saturation transfer (CEST) or amide proton transfer (APT) magnetic resonance imaging (MRI), and the Z-spectra and asymmetry spectra were calculated from their solutions. They were also calculated using the fourth/fifth-order Runge-Kutta-Fehlberg (RKF) method for comparison. There was also a good agreement between them, and this method was much faster than the RKF method. In conclusion, this method will be useful for analyzing the complex CEST or APT contrast mechanism and/or investigating the optimal conditions for CEST or APT MRI. 相似文献
109.
In this paper, to consider all surface effects including surface elasticity, surface stress, and surface density, on the nonlinear free vibration analysis of simply-supported functionally graded Euler–Bernoulli nanobeams using nonlocal elasticity theory, the balance conditions between FG nanobeam bulk and its surfaces are considered to be satisfied assuming a cubic variation for the component of the normal stress through the FG nanobeam thickness. The nonlinear governing equation includes the von Kármán geometric nonlinearity and the material properties change continuously through the thickness of the FG nanobeam according to a power-law distribution of the volume fraction of the constituents. The multiple scale method is employed as an analytical solution for the nonlinear governing equation to obtain the nonlinear natural frequencies of FG nanobeams. The effect of the gradient index, the nanobeam length, thickness to length ratio, mode number, amplitude of deflection to radius of gyration ratio and nonlocal parameter on the frequency ratios of FG nanobeams is investigated. 相似文献
110.
Innovations in chemometrics are required for studies of chemical systems which are governed by nonlinear responses to chemical parameters and/or interdependencies (coupling) among these parameters. Conventional and linear multivariate models have limited use for quantitative and qualitative investigations of such systems because they are based on the assumption that the measured data are simple superpositions of several input parameters. ‘Predictor Surfaces’ were developed for studies of more chemically complex systems such as biological materials in order to ensure accurate quantitative analyses and proper chemical modeling for in-depth studies of such systems. Predictor Surfaces are based on approximating nonlinear multivariate model functions by multivariate Taylor expansions which inherently introduce the required coupled and higher-order predictor variables. 相似文献