极谱分析法连续测定痕量铅和镉

研究了 Pb2 + 和 Cd2 + 与 KCl-酒石酸钠 -三乙醇胺 -明胶体系的二次导数极谱波。在 p H=4 .5的 HAc-Na Ac介质中 ,Pb2 + 和 Cd2 + 分别于 - 0 .4 6 V和 - 0 .6 4V电位处产生一良好的极谱波。峰电流与 Pb2 + 和Cd2 + 的浓度分别在 1× 10 -5— 3× 10 -1g· L-1和 5× 10 -5— 6× 10 -3 g· L-1范围内呈线性关系。 Pb2 + 和Cd2 +的检出限分别为 1× 10 -7g·L-1和 5× 10 -7g·L-1。本法准确、简便、快速、选择性高。已直接用于饮料中铅和镉的连续测定 ,同时也对酒及面粉样品进行了测定 ,回收率分别为 99.9%— 10 0 .1%和 97.0 %—10 4 .8%。     

Selective grafting of amine groups on polyethylene by means of NH3−H2 RF glow discharges

Plasma treatments in Radio Frequency Glow Discharges fed with NH₃−H₂ mixtures have been performed for modifying polyethylene surfaces. Treatment kinetics and the role of species present in the glow have been investigated. Actinometric Optical Emission Spectroscopy has been utilized as a plasma diagnostic technique. Electron Spectroscopy for Chemical Analysis has been utilized for studying surface composition of treated substrates, which have been examined both astreated and after derivatization of amine-functionalities with 4-trifluoromethylbenzaldehyde vapors. It has been found that experimental plasma parameters and plasma density of active species can be controlled to achieve selective grafting of-NH₂ among all other nitrogen-containing groups.     

水杨醛缩二乙基三胺铜配合物的合成与结构分析

合成了水杨醛缩二乙基三胺 (配体 L,2 - [(N- Salicylideneamino) ethyl]amine)与 Cu( )形成的配合物[Cu L(H2 O) ]Cl,通过元素分析、红外光谱、X射线单晶衍射进行了结构分析。配合物为单斜晶系 ,空间群P2 (1) / c,晶体学结构数据 ,a=0 .912 3(5 ) nm,b=1.382 1(7) nm,c=1.0 82 9(5 ) nm,β=10 1.712 (7)°,V=1.336 9(11) nm3 ,Z=4 ,Dcalcd=1.6 0 6 mg/ m3 ,F(0 0 0 ) =6 6 8,R1=0 .0 377,w R2 =0 .10 18。结构分析表明 ,配合物通过氢键形成二聚结构     

Order-free Recursion on the Real Numbers

We investigate operations, computable in the sense of Recursive Analysis, which can be generated recursively from the arithmetic operations and the limit operation without using any tests on the real numbers. These functions, called order-free recursive, can be shown to include a large class of computable functions. As main tools we provide an effective version of the Stone-Weierstraß Approximation Theorem, as well as recursive partitions of unity.     

二苯并18-冠-6配合物[NH4(DB18-C-6)]2[Pd(SCN)4]的合成与结构分析

研究了二苯并18-冠-6(DB18-C-6)与(NH4)2[Pd(SCN)4]的反应,通过元素分析、红外光谱、单晶X射线衍射对生成的配合物[NH4(DB18-C-6)]2[Pd(SCN)4](1)进行了结构分析.1为三斜晶系,空间群P-1,晶体学数据:a=0.8705(3)nm,b=1.1954(4)nm,c=1.3044(4)nm,α=73.216(5)°,β=78.897(5)°,γ=81.105(6)°,V=1.2682(7)nm3,Z=1,F(000)=568,R1=0.0301,wR2=0.0431.配合物由二个[NH4(DB18-C-6)]+配阳离子和一个[Pd(SCN)4]2-配阴离子组成,二者通过N-H…N氢键形成中性配合物,配合物中不存在阳离子-π相互作用.     

S-PLUS code for simple and multiple correspondence analysis

An exploration of the application of S-PLUS code designed to perform classical correspondence analysis is made in this paper. This code allows for the “classical” analysis to be performed on categorical data consisting of two or more variables. For multi-way contingency tables, correspondence analysis can be performed by considering either the indicator matrix or the Burt matrix. The code also allows the user to incorporate into the analysis confidence circles (to identify categorical responses that deviate from the hypothesis of independence) and for an asymmetrical analysis to be performed. The function includes various warnings and stoppages to help the user properly analyse their data.     

基于SPA联系数的大连产业结构演化规律研究

SPA联系数是把研究对象各种测度联系起来加以系统性地描述、计算、分析的一种结构函数,其一般形式为a+bi+cj,用于城市第一产业、第二产业、第三产业相互联系和演化规律的研究有其合理和创新之处,其特点是把城市第一产业、第二产业、第三产业看成一个系统.用于大连产业结构演化规律研究后发现,大连市在1978~1999年20年间经历了稳定——剧烈调整——稳定这样三个阶段.在今后的10~20年间,对于第三产业的投资仍将处在首位.     

运用因子分析法建立教学质量评估指标体系

在大量抽样调查的基础上，本文运用因子分析（Ｆａｃｔｏｒ Ａｎａｌｙｓｉｓ）的方法，在Ｍ—３４０计算机上利用ＡＮＡＬＹＳＴ统计分析软件包中因子分析软件程序，求得因子载荷矩阵．依据因子载荷矩阵，并结合教学质量评估的特点，建立起适用于学生为参评者的教学质量评估指标体系．     

混合二肽的场解吸质谱

为了探索生物化学、生物医学中混合寡肽的分析问题,对未衍生的混合二肽场解吸质谱进行了研究(图1和图2)。在图1图2中出现了所有二肽的准分子离子[M+H]~+,除此外还出现了[2M+H]~+、[M_(AB)+H]~+、[M_(AC)+H]~+等集聚离子,这些集聚离子能用于进一步确定各个肽的分子量。