流动注射-电感耦合等离子体发射光谱法测定天然水中的钙和镁

本文采用流动注射－电感耦合等离子体发现光谱联用技术测定了天然水中的钙、镁元素。考察了试液的雾化和曝光时间及载气压力等因素对分析信号的影响。通过与气动连续进样的对比，测出了钙、镁在流动注射进样下的分散系数。本法在测定钙、镁含量高的水性时，不需对试样进行稀释处理。对五个水样中钙、镁的分析结果与EDTA络合滴定法相吻合。     

Interlaboratory comparisons between results from testing metallurgical products for precious metal content

Problems verifying the accuracy of analyses of non-standardized materials for precious metal (PM) content have arisen at the Norilsky Nickel plant, which is a major producer of nickel, copper, and PMs in Russia. Because of the unavailability of certified reference samples for direct accuracy verification, a program of interlaboratory comparisons (ILC) was developed. This program was based on testing three semi-products of the PM production process for PM content. On program completion, a total of 826 results in 98 runs had been obtained. For each run, the calculated mean value of PM concentration was taken to be the reference value. The results obtained by Norilsky Nickel were in agreement with the reference values within the standard deviations calculated for the values. The quality of results yielded with the ILC program, as assessed via the Z-criterion, is regarded as satisfactory.Presented at the Second International Conference on Metrology – Trends and Applications in Calibration and Testing Laboratories, November 4–6, 2003, Eilat, Israel.     

数字光处理背投电视色度学特性的研究

以色度学的基本理论为基础,结合数字光处理光学引擎的工作原理,探讨了单片式数字光处理光学引擎的彩色显示原理和色温调节原理.提出了单片式数字光处理光学引擎色度学特性的理论计算公式,并利用该公式对夏新DL52HWT型投影电视光学引擎的显示三原色色度坐标、白场平衡的色度坐标和相关色温以及颜色复现误差等色度学特性进行了计算和分析,并对理论计算公式进行了验证.     

Effective Hamiltonian approach to doubly degenerate electronic states

Effective vibronic Hamiltonian models are built for E ⊗e Jahn-Teller systems and analytical solutions are obtained through Lie algebraic methods. Although approximate, we show that these models allow in particular to recover the possible ground state crossover when quadratic couplings are present. The equivalence of E ⊗e and G' ⊗e vibronic systems in cubic symmetry is precisely established through a particular realization of the electronic operators for an orbital quadruplet. We show how this equivalence is broken by a rovibronic interaction which, for a G' ⊗e system, still gives an exactly solvable model.     

Total analysis of surface structure and properties by UHV transfer system

We have developed an ultrahigh-vacuum (UHV) complex sample preparation and analysis system, which realizes a reliable surface science analyzing various characters on an identical surface. The system contains three sample-preparation-and-characterization chambers and five analysis chambers. They are (1) an electronic-properties-characterization chamber, (2) a magnetic-properties-characterization chamber, (3) an organic-molecule chamber, (4) UHV SEM, (5) a high-energy-resolution angle-resolved photoelectron spectrometer, (6) a high-energy-resolution display-type spherical mirror analyzer, (7) a room-temperature (RT) STM, and (8) an optical-properties characterization chamber. A special sample holder is used with six electrodes on it, which enables accurate temperature measurement of a sample by connecting a thermocouple directly to the sample even if it is transferred. Four other electrodes can be used for construction of various circuits including evaporators. Some examples are shown.     

基于结构元的复模糊数及其序列极限

复模糊数是模糊复分析中的基本概念,在模糊复分析中,它的运算是基于扩张原理的形式给出的,是对元素遍历某个条件所对应的结果进行运算,这种遍历过程给实际操作带来了很多的不便,因此,在一定程度上也阻碍了模糊复分析理论的应用.对此,本文基于模糊结构元的理论基础,探讨了复模糊数运算的另一种新的途径,这种方法简化了复模糊数的运算,也...     

Study of molecular interactions between lipids and proteins using dynamic surface tension measurements: a review

Molecular interactions between small molecules and proteins, such as binding of lipids to proteins, are of fundamental importance in various biological processes. A recently-developed method based on dynamic surface tension measurement is efficient and versatile in detecting such molecular interactions: Axisymmetric Drop Shape Analysis (ADSA) provides a tool for measuring the surface tension (γ) response to surface area changes. Through the analysis of the γ response pattern, surface competitive adsorption between small organic molecules and protein molecules can be detected. Surface squeeze-out of small molecules by proteins can also be observed. Molecular binding of lipids to proteins manifests itself in a modification of the γ response which is not compatible with a simple superposition of the two individual patterns. The specific binding can be studied in terms of dose effects and specificity.     

The development of an integrated platform to identify breast cancer glycoproteome changes in human serum

Protein glycosylation represents one of the major post-translational modifications and can have significant effects on protein function. Moreover, changes in the carbohydrate structure are increasingly being recognized as an important modification associated with cancer etiology. In this report, we describe the development of a proteomics approach to identify breast cancer related changes in either concentration and/or the carbohydrate structures of glycoprotein(s) present in blood samples. Diseased and healthy serum samples were processed by an optimized sample preparation protocol using multiple lectin affinity chromatography (M-LAC) that partitions serum proteins based on glycan characteristics. Subsequently, three separate procedures, 1D SDS-PAGE, isoelectric focusing and an antibody microarray, were applied to identify potential candidate markers for future study. The combination of these three platforms is illustrated in this report with the analysis of control and cancer glycoproteomic fractions. Firstly, a molecular weight based separation of glycoproteins by 1D SDS-PAGE was performed, followed by protein, glycoprotein staining, lectin blotting and LC–MS analysis. To refine or confirm the list of interesting glycoproteins, isoelectric focusing (targeting sialic acid changes) and an antibody microarray (used to detect neutral glycan shifts) were selected as the orthogonal methods. As a result, several glycoproteins including alpha-1B-glycoprotein, complement C3, alpha-1-antitrypsin and transferrin were identified as potential candidates for further study.     

The analysis of process gases: a review

 A general review of key issues involved in the analysis of process gases is presented. The reasons for such measurements – which include safety, quality, environmental and economic factors are considered. The technical issues arising from these measurements are dependent upon a variety of factors, including the overall sampling system, the type of analytical instrumentation, methods of data collection and the specified calibration protocols. The use of gas calibration cylinders as transfer standards is detailed and issues of stability and traceability to reference material discussed. Received: 1 March 2000 / Accepted: 31 March 2000     

SPH分析中的齿轮建模方法研究

对利用光滑粒子动力学(SPH-Smoothed Particle Hydrodynanlics)方法进行轮齿动态力学数值分析中的齿轮建模方法进行了研究.确定了齿轮齿根过渡曲线以及其他部分的参数方程,并根据所确定的参数方程建立了三维齿轮离散粒子模型的数学模型.编制了划分齿轮整体及局部离散粒子的SPH前处理程序.并对划分后齿轮离散粒子与齿轮理论轮廓之间进行了误差分析.分析结果表明,利用此办法可正确划分齿轮的SPH离散化粒子,是一种较好的前处理方法.