全文获取类型
收费全文 | 229篇 |
免费 | 6篇 |
国内免费 | 15篇 |
专业分类
化学 | 206篇 |
晶体学 | 8篇 |
力学 | 4篇 |
综合类 | 1篇 |
数学 | 7篇 |
物理学 | 24篇 |
出版年
2022年 | 6篇 |
2020年 | 2篇 |
2019年 | 7篇 |
2018年 | 2篇 |
2017年 | 8篇 |
2016年 | 8篇 |
2015年 | 7篇 |
2014年 | 12篇 |
2013年 | 28篇 |
2012年 | 17篇 |
2011年 | 7篇 |
2010年 | 10篇 |
2009年 | 14篇 |
2008年 | 13篇 |
2007年 | 18篇 |
2006年 | 14篇 |
2005年 | 18篇 |
2004年 | 15篇 |
2003年 | 13篇 |
2002年 | 2篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 5篇 |
1998年 | 3篇 |
1997年 | 1篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1985年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有250条查询结果,搜索用时 0 毫秒
21.
《Comptes Rendus Chimie》2014,17(4):310-315
Submicron non-aqueous emulsions, of interest for biomedical and cosmetic formulations, were developed for the system comprising poly(ethylene glycol) (PEG) 400 and Miglyol 812, an enzymatic degradable liquid glycerine ester. These emulsions, with PEG 400 as continuous phase and Miglyol 812 droplets, in the size range of 200 nm, were stabilized by a poly(butadiene)-b-poly(2-vinylpyridine) (PBut-b-P2VP) block copolymer with a composition close to 50/50 wt%. The droplet size, stability and the rheological characteristics were examined as a function of the copolymer concentration. An original aspect of these anhydrous emulsions, with a water miscible continuous phase, is their water dispersibility without additional surfactant. In fact, the initial anhydrous emulsion is sterically stabilized and after water addition at low pH, the protonated P2VP sequence of the copolymer provides the electro-steric stabilization. This oil-in-water emulsion is characterized by sub micron sized Miglyol 812 droplets in an aqueous phase of PEG 400 and water at pH 1. 相似文献
22.
A. Sibirtsev J. Haidenbauer H. -W. Hammer U. -G. Meißner 《The European Physical Journal A - Hadrons and Nuclei》2006,29(3):363-367
We show that the recently measured asymmetry in helicity-angle spectra of the Λ-hyperons, produced in the reaction pp → K
+Λp reaction, and the energy dependence of the total pp → K
+Λp cross-section can be explained consistently by the same Λp final-state interaction. Assuming that there is no final-state interaction in the Σ0
p channel, as suggested by the available data for the reaction pp → K
+Σ0
p, we can also reproduce the energy dependence of the Λ/Σ0 production ratio and, in particular, the rather large ratio observed near the reaction thresholds. The nominal ratio of the
Λ and Σ0 production amplitudes squared, i.e. when disregarding the final-state interaction, turns out to be about 3, which is in line with hyperon production data from
proton and nuclear targets available at high energies. 相似文献
23.
Vural E. Kafadar 《Physica B: Condensed Matter》2011,406(3):537-540
The dosimetric characteristics of many TL materials are influenced by changes in location, size and shape of the glow curves due to changes in the heating rate. In this study, the effect of heating rate on the integrated peak areas of CaF2:Dy (TLD-200), CaF2:Tm (TLD-300) and CaF2:Mn (TLD-400) crystals have been investigated after β-irradiation. It was observed that the peak temperatures of all peaks shifted to the high temperature sides and the integrated peak areas decrease as the heating rate increases due to thermal quenching, whose efficiency increases as temperature increases. 相似文献
24.
An expeditious synthesis of 2-aryl-benzimidazoles by the condensation of o-phenylenediamine with various araldehydes is described. This greener protocol is catalyzed by Amberlite IR-120, and proceeds efficiently in the absence of any organic solvent under microwave irradiation within 3–5 min. 相似文献
25.
《Analytical letters》2012,45(13):2089-2101
Abstract A procedure for the spectrophotometric determination of aluminum traces in water using a flow injection (FI) preconcentration system has been proposed. The flow system was made up of a peristaltic pump, an injector‐commutator, and a minicolumn filled with 300.0 mg of Amberlite IR‐120 cationic exchange resin. After the preconcentration step, aluminum was eluted by a 4.0 mol l?1 HCl solution. In a second stage, out of the flow system, the eluate was neutralized with a 4.0 mol l?1 NaOH solution. The aluminum was submitted to the reaction with eriochrome cyanine to form a chelate in solution buffered to pH 5.85, according to the Standard Method's procedure with some modifications, and this was followed by spectrophotometric detection. Chemical and flow variables were studied in the preconcentration system. The precision of the proposed method was calculated for a solution containing 46.8 µg l?1 of Al(III), when 40.0 ml of solution were preconcentrated (n=7), and their respective relative standard deviation (RSD) was 1.8%. The detection limit obtained was 1.7 µg l?1 of Al(III) (sample volume=40.0 ml). The proposed method was successful in determining aluminum in water certified reference material. 相似文献
26.
S.P. Avdeyev V.A. Karnaukhov W.D. Kuznetsov L.A. Petrov V.K. Rodionov A.S. Zubkevich H. Oeschler O.V. Bochkarev L.V. Chulkov E.A. Kuzmin A. Budzanovski W. Karcz M. Janicki E. Norbeck A.S. Botvina W.A. Friedman W. Nörenberg G. Papp 《The European Physical Journal A - Hadrons and Nuclei》1998,3(1):75-83
Multiple emission of intermediate-mass fragments has been studied for the collisions p + Au at 2.16, 3.6 and 8.1 GeV with
the FASA setup. The mean IMF multiplicities for events with at least one IMF are equal to 1.7, 1.9 and 2.1 (±0.2) respectively.
The multiplicity, charge distributions and kinetic energy spectra of IMF are described in the framework of a intranuclear
cascade model followed by the statistical multifragmentation model. However, between the two parts of the calculation the
excitation energies and the residual masses and charges are modified to take into account the losses during expansion. The
results support a scenario of true thermal multifragmentation of a hot and expanded target spectator.
Received: 15 December 1997 / Revised version: 24 April 1998 相似文献
27.
A High-Power Reflector Impulse Antenna with Dual-Tem Source 总被引:1,自引:0,他引:1
Chen Guo An-xue Zhang Hui Wu Yan-sheng Jiang Wen-bing Wang 《International Journal of Infrared and Millimeter Waves》2008,29(9):832-838
There are different demands on radiation efficiency and direction pattern according to various ultra-wideband (UWB) antennas
and high power applications. To obtain more radiating gain on bore-sight of paraboloidal reflector and centralized radiating
direction, a novel feeding structure called dual-TEM source has been designed and applied in half-paraboloidal reflector impulse
radiating antenna (IRA) applications. Simulation results proved that this proposed half-paraboloidal reflector IRA with dual-TEM
source provided greater radiation performance on bore-sight as a result of the synthesized power in the aperture space of
paraboloid. Moreover, lots of simulation work and comparison have been done in different feeding models to summarize a relative
optimal feeding structure. 相似文献
28.
Infrared spectroscopy measurements were performed on Lysozyme aqueous solutions also in the presence of PolyEthylene Glycol (PEG 400) as a function of an increasing temperature from T = 27 °C to 90 °C, and, successively in sequence, by decreasing temperatures from T = 90 °C to 27 °C. Data were analyzed by evaluating the spectral difference with respect to the initial spectrum collected at 27 °C. This procedure allows to quantitatively evaluate the thermal restraint related to the thermal scan from T = 27 °C to 90 °C, as well as to introduce a spectral resilience concerning the entire increasing and decreasing thermal paths which allow to highlight the bioprotectant effectiveness of low molecular weight PEG. In particular, the main purpose of the present work is to highlight the effects of a thermal treatment on a mixture of Lysozyme/water and of Lysozyme/water/PEG 400 during an increasing temperature scan, and then after a successive decreasing temperature scan, in order to highlight the bioprotectant role of PEG 400. On that score, an evaluation of the spectral distances of the registered spectra as a function of increasing and decreasing temperatures has been performed and analyzed. 相似文献
29.
A simple and efficient protocol for CuI‐catalyzed C? S bond formation of aryl halides with KSCN to symmetrical diaryl sulfides was reported in PEG‐400 without any other additives. A variety of aryl halides were converted to the corresponding diaryl sulfides in good to excellent yields. The present procedure tolerated a variety of functional groups and the steric hindrance of ortho‐substituents on aryl halides did not affect the outcome. 相似文献
30.
Summary Hydroxypropyl methyl cellulose (HPMC) and polyethylene glycol 400 (PEG 400) content in HypoTears™ Daily Dose ophthalmic solution
are determined simultaneously by size exclusion chromatography. The retention times of HPMC and PEG 400 are 10.6 and 15.4
minutes, respectively. The method requires minimal sample pretreatment and is accurate and reproducible. The peak area response
from a refractive index detector versus HPMC and PEG 400 concentration is linear over the range of 50–150 % of their label
claims of 2.5 mg/mL and 10 mg/mL, respectively. The mean absolute recoveries of HPMC and PEG 400 at their label claim using
the described method are 98.9±1.3 % and 100.4±1.2 % (mean±SD, n=12), respectively. 相似文献