全文获取类型
收费全文 | 159篇 |
免费 | 4篇 |
国内免费 | 10篇 |
专业分类
化学 | 78篇 |
力学 | 4篇 |
数学 | 46篇 |
物理学 | 45篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 1篇 |
2020年 | 8篇 |
2019年 | 3篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 6篇 |
2015年 | 4篇 |
2014年 | 7篇 |
2013年 | 16篇 |
2012年 | 5篇 |
2011年 | 14篇 |
2010年 | 5篇 |
2009年 | 8篇 |
2008年 | 10篇 |
2007年 | 5篇 |
2006年 | 9篇 |
2005年 | 11篇 |
2004年 | 2篇 |
2003年 | 1篇 |
2002年 | 2篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1999年 | 2篇 |
1997年 | 4篇 |
1996年 | 2篇 |
1994年 | 6篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有173条查询结果,搜索用时 0 毫秒
11.
Karunanithi Masilan Neethirajan Neethiselvan Robinson Jeya Shakila Arjunan Karthy Ulaganathan Arisekar Nagarajan Muralidharan Thangaraji Ravikumar Balasubramanian Sivaraman Chellapa Kalidas Lakshmanan Ranjith Dhanasekaran Linga prabhu 《印度化学会志》2022,99(3):100376
The study dealt with evolving an artificial fish bait by incorporating bioattractant concentrates derived from seafood processing wastes by enzymatic hydrolysis namely fish waste concentrate (FWC), squid waste concentrate (SWC), and shrimp processing concentrate (SPWC). They were characterized based on amino acid content and presence of different functional groups using FTIR. Among them, SWC was found to have the highest amino acid content of 60.85mg/100 mg followed by FWC (42.21mg/100 mg) and SPWC (24.82mg/100 mg). The developed artificial fish baits were subjected to protein leaching, solubility in seawater besides testing for acceptability by the red snapper. The study revealed that the bait incorporated with SWC at 3% level was found be the most ideal, with the protein leaching rate of 24.82 mg/g/h, solubility rate of 36.6 mg/g/h and the attractability score of 29/30. The amino acid leaching rate was 3.11 mg/h/100 mg and it was found to contain five amino acids such as glycine, proline, glutamic acid, alanine and serine. The study revealed that the hydrolyzed squid waste concentrate can be incorporated at 3% (w/w) with fish gelatin based biomatrix during gelation to prepare artificial bait. 相似文献
12.
马来酸二丁基锡的合成及其共聚合 总被引:1,自引:0,他引:1
马来酸二丁基锡的合成及其共聚合刘云桥金根河李福绵(北京大学化学与分子工程学院北京100871)关键词马来酸二丁基锡,醋酸乙烯酯,交替共聚物,光聚合关于马来酸酐[1],马来酰亚胺 N 取代物[2,3]与富电子烯类单体如苯乙烯,醋酸乙烯酯,乙烯基烷基醚... 相似文献
13.
Mario Ficker Søren W. Svenningsen Thomas Larribeau Jørn B. Christensen 《Tetrahedron letters》2018,59(12):1125-1129
The simple reduction of a number of alkenes and alkynes was performed with a typical reaction time of 20?min using a copper-cobalt catalytic system. The reduction did not cleave benzyl protecting groups which are usually vulnerable to catalytic hydrogenation reactions. The catalyst can be prepared in situ by reduction of the inexpensive precursor salts CuSO4 and CoCl2 with NaBH4. Sodium borohydride was also used as an easily handled hydrogen source for the catalytic reductions. No pressure, heating or inert atmosphere is required and purification/catalyst removal is achieved using extraction procedures, making this approach simple and efficient. 相似文献
14.
Ibrahim Kayali Mohammad Karaein Khawla Qamhieh Salam Wadaah Wisam Ahmad Ulf Olsson 《Journal of Dispersion Science and Technology》2013,34(1):10-17
Bicontinuous and water-in-diesel microemulsions were formulated using single nonionic alkyl poly glycol ethers combined with hydrophilic alcohol ethoxylates. The phase behavior at temperatures ranging from 0°C to 50°C was investigated. Visual inspection as well as cross-polarizers were used to detect anisotropy. The fish phase diagrams were determined. The presence of the hydrophilic alcohol ethoxylates was necessary to initiate both types of microemulsions. Increasing the hydrophobic chain length of the surfactant led to a wider range of temperature stability at lower surfactant concentration. Meanwhile, increasing the ethylene oxide units in the headgroup by two units led to a phase diagram that is dominated by lyotropic liquid crystal. The formulated water in diesel microemulsions were tested experimentally in a 4-cylinder diesel engine. From this it is observed that the emissions of NOx, soot, and CO2 were reduced substantially compared to neat diesel, while for the CO the reduction occurs just at low load. 相似文献
15.
Ru-Ir-Ti氧化物阳极正反电流电解失效机理研究 总被引:2,自引:0,他引:2
应用热分解法制备适用于海水电解的钛基金属氧化物阳极.由SEM、EDX和XRD分析表征该阳极的形貌、成分及相结构,结果表明,烧结后阳极表面形成了固溶体结构,分别为(Ru,Ir,Ti)O2和(Ir,Ti)O2,失效后氧化物阳极的固溶体结构几乎完全消失,活性物质丧失.强化正反向电流寿命测试、循环伏安曲线和电化学阻抗谱等测试表明,失效后氧化物阳极表面的电化学活性点大大减少,同时膜电阻增加,这是由于活性物质脱落导致的,进一步说明正反向电流导致阳极表面活性物质脱落是氧化物阳极失效的根本原因. 相似文献
16.
《Electroanalysis》2018,30(9):1902-1905
The second order voltammetric technique Differential Alternative Pulses Voltammetry (DAPV) was applied in anodic stripping mode for simultaneous quantification of traces of species having close E1/2. The potential‐time waveform and the signal processing allowing the DAPV application in stripping mode are presented. The pulses widths and amplitudes were optimized to obtain maximal sensitivity and resolution at traces of In3+ and Cd2+ (having E1/2 difference of 45 mV) simultaneous quantification in presence of excess of Pb2+. Precise results for both species concentrations were obtained up to In3+ to Cd2+ concentration ratio as high as 1 to 10 without any sample pre‐treatment in purified industrial waste waters using 0.1 mol L−1 HCl as supporting electrolyte. 相似文献
17.
Bochu W Hucheng Z Yiyao L Yi J Sakanishi A 《Colloids and surfaces. B, Biointerfaces》2001,20(4):367-325
The effects of alternative stress, which was generated through a strong sound field apparatus set up in our lab, on cultured chrysanthemum callus cells were studied. Meanwhile we measured the deformability of chrysanthemum cell membranes and studied the influence of the cytoskeleton after the treatment of colchicine using micropipette aspiration technique. Based on our experimental results, we found that the deformability of cell membrane decreased in stress condition. However, the effect disappeared after the treatment of cytochalasin. Therefore, we thought that the reason on the deformability of cells decreasing was the microfilament rearranging and consequently the cells becoming more rigid under the alternative stress. 相似文献
18.
本文研究作用在C2周期函数空间上的微分算子u→u″ g(u) ,其中g(u)为连续有界函数.我们将证明上述微分算子的值域限制在周期函数空间的“超曲面”中. 相似文献
19.
《代数通讯》2013,41(10):3479-3487
We study the structure of alternative superalgebras that satisfy the descending chain condition (DCC) for two-sided ideals. The main results state that the Baer radical in an alternative superalgebra of characteristic ≠ 2, 3 with DCC on two-sided ideals is solvable and every such a semiprime superalgebra (of arbitrary characteristic) is isomorphic to a subdirect sum of an associative superalgebra with this property and a finite direct sum of simple alternative non-associative superalgebras. 相似文献
20.
The paper studies a train scheduling problem faced by railway infrastructure managers during real-time traffic control. When train operations are perturbed, a new conflict-free timetable of feasible arrival and departure times needs to be re-computed, such that the deviation from the original one is minimized. The problem can be viewed as a huge job shop scheduling problem with no-store constraints. We make use of a careful estimation of time separation among trains, and model the scheduling problem with an alternative graph formulation. We develop a branch and bound algorithm which includes implication rules enabling to speed up the computation. An experimental study, based on a bottleneck area of the Dutch rail network, shows that a truncated version of the algorithm provides proven optimal or near optimal solutions within short time limits. 相似文献