内燃机磨合与表面改性实验研究

针对EQ6100型汽油机,利用内燃机磨合台架试验装置对所研制的内燃机专用磨合油与普通15W／40内燃机油进行对比磨合试验,对磨合油液进行直读铁谱分析,对缸套－活塞环磨合表面形貌及元素组成进行测试分析。结果表明：专用磨合油的磨合效果明显优于普通内燃机油;超细金刚石微粉可以加速磨合进程,分化并减小磨屑尺寸,从而避免缸壁拉伤和改善缸套－活塞环摩擦副的摩擦学特性。     

考虑运营期收益的项目建设期时间/费用交换问题(TCTP/R)研究

给出了考虑运营期收益的项目建设期时间/费用交换问题DTCTP/R的概念,讨论了项目工期/收益的函数关系,建立了优化的数学模型,并且将遗传算法应用于问题的求解.最后,结合一个案例说明了在对建设期优化时,应当考虑其对项目运营收入的影响,从全局的角度来进行时间/费用的优化,所得结果才准确与可靠.     

Critical evaluation of buffering solutions for pKa determination by capillary electrophoresis

The performance of the most common and also some other less common CE buffers has been tested for the pKa determination of several types of compounds (pyridine, amines, and phenols). The selected buffers cover a pH ranging from 3.7 to 11.8. Whereas some buffers, like acetic acid/acetate, BisTrisH+/BisTris, TrisH+/Tris, CHES/CHES-, and CAPS/CAPS- can be used with all type of analytes, others like ammonium/ammonia, butylammonium/butylammonia, ethylammonium/ethylammonia, diethylammonium/diethylammonia, and hydrogenphosphate/phosphate are not recommended because they interact with a wide range of compounds. The rest of the tested buffers (dihydrogenphosphate/hydrogenphosphate, MES/MES-, HEPES/HEPES-, and boric acid/borate) can show specific interactions depending on the nature of the analytes, and their use in some applications should be restricted.     

Towards minimum loss job routing to parallel heterogeneous multiserver queues via index policies

This paper considers a Markovian model for the optimal dynamic routing of homogeneous traffic to parallel heterogeneous queues, each having its own finite input buffer and server pool, where buffer and server-pool sizes, as well as service rates, may differ across queues. The main goal is to identify a heuristic index-based routing policy with low complexity that consistently attains a nearly minimum average loss rate (or, equivalently, maximum throughput rate). A second goal is to compare alternative policies, with respect to computational demands and empirical performance. A novel routing policy that can be efficiently computed is developed based on a second-order extension to Whittle’s restless bandit (RB) index, since the latter is constant for this model. New results are also given for the more computationally demanding index policy obtained via policy improvement (PI), including that it reduces to shortest queue routing under symmetric buffer and server-pool sizes. A numerical study shows that the proposed RB index policy is nearly optimal across the instances considered, and substantially outperforms several previously proposed index policies.     

几种内燃机磨合油的摩擦学性能评价及在缸套和活塞环摩擦副上的应用

在分析内燃机缸套和活塞环摩擦副的运行环境和运行机制的基础上,针对内燃机频繁出现的缸套和活塞环摩擦副擦伤现象,研制出了2种内燃机磨合油,在四球摩擦磨损试验机上评价了其磨合效果,采用扫描电子显微镜对磨合表面进行了形貌观察,并通过热分析考察了其热稳定性和热氧化安定性,结果表明,在物理化学指标符合内燃机油的前提条件下,所研制的2种磨合油的承载和抗磨能力较高,经其磨合后的缸套-活塞环表面光滑,磨合效果良好,两种磨合油的热稳定性和热氧化安定性亦较坑,是潜在的优良的内燃机磨合油。     

磨石磨损分形预测研究

磨合是新机器投入正常运行前所必须经历的一个过程。合理的磨合可防止机器在早期发生咬合,从而极大地延长其使用寿命,基于磨损表面的分形表征,经典接触理论和磨损理论,建立了磨合磨损预测分形模型,以铜合金销和４５＃钢盘试样组成摩擦副,在销－盘摩擦磨损试验机上进行了磨合试验。研究结果表明,基于所建立的模型的磨损率预测结果与试验结果基本吻合。     

Marginal productivity index policies for scheduling a multiclass delay-/loss-sensitive queue

This paper addresses the problem of scheduling a Markovian multiclass queue with a finite dedicated buffer for each class, where class-dependent linear holding and rejection cost rates model differing levels of tolerance to delay and loss. The goal is to design well-grounded and tractable scheduling policies that nearly minimize expected total discounted or long-run average cost. New dynamic index policies are introduced, awarding higher priority to classes with larger index values, where a class’ index measures the marginal productivity of work at its current state. The results are obtained by deploying the work-cost analysis approach to marginal productivity indices (MPIs) for restless bandits developed by the author, which is extended to the bias criterion. The MPI furnishes new insights: for a loss-sensitive class, it is a decreasing function of the number of empty buffer spaces, independent of the buffer size; for a delay-sensitive class, it is a decreasing function of the queue length. Such opposite orderings show that preventive work is more valuable than reactive work for the latter classes, whereas the opposite holds for the former. The results of a computational study on two-class instances are reported, shedding light on how the MPI policy’s relative performance varies with each parameter. Parameter ranges are thus identified where the MPI policy is near optimal, and substantially outperforms conventional benchmark policies. 2000 Mathematics Subject Classification 90B22 · 90B36 · 90B18 · 60K25 · 60K30 · 68M20     

Modelling of Pb-(TAPS)x-(OH)y system and refinement of stability constants in the region of lead hydrolysis and lead hydroxide precipitation

The influence of [(2-hydroxy-1,1-bis(hydroxymethyl)ethyl)amino]-1-propanesulfonic acid (TAPS) on solutions containing lead(II) was studied by direct current polarography (DCP) and glass electrode potentiometry (GEP). The readings were taken at fixed total TAPS to total lead(II) concentration ratios and various pH values, at 25.0 ± 0.1 °C and ionic strength 0.1 M KNO₃.Due to the basic pK_a of the ligand, which occurs in the pH range where large amount of lead polynuclear species are formed, and the occurrence of ligand adsorption, that disabled the use of high concentrations of TAPS on DCP experiments, GEP and DCP experimental conditions were put to the limit in order to provide the correct Pb-TAPS-OH model and reliable stability constants.The proposed final model is: PbL, PbL₂, PbL₂(OH) and PbL₂(OH)₂ with overall stability constants values, as log β, 3.27 ± 0.06, 6.5 ± 0.1, 12.7 ± 0.1 and 17.27 ± 0.06, respectively.A comparative analysis of the strength of complexation of TAPS and a structural related buffer, 2-hydroxy-3-[tris(hydroxymethyl)methylamino]-1-propanesulfonic acid (TAPSO), with lead is also discussed.     

Cyclodextrin-modified micellar electrokinetic chromatography for separation of norgestrel enantiomers

A simple method for the separation of highly hydrophobic neutral enantiomers by cyclodextrin-modified micellar electrokinetic chro-matography (MEKC) is presented and strongly supported by experiments. The separation depends on the ratio between the concentrations of cyclodextrin (CD) and sodium dodecylsulfate (SDS) micelles and there is an optimum value of the ratio for the separation of the enantiomers of norgestrel and 4-androstene-3,17-dione. At the optimum value of the ratio, obtained by adjusting the absolute concentrations of CD and SDS. The electrophoretic mobility difference between two enantiomers can be maintained nearly constant.     

Photoacidity of Indolinospirobenzopyrans in Water

The reversible isomerism of indolinospirobenzopyrans is perhaps among the most studied phenomena in the field of molecular switches. Although they began to gain attention as early as 70 years ago following the seminal work of Hirshberg and Fischer, who were the first to recognize their photochromic behaviours, their implementation as photoacids emerged prominently only in the last decade. In this Review, we contextualize the prerequisites underlying the photo-triggered proton release that occurs in these molecular switches, highlighting the most recent advances in their characterization and application as “metastable-state photoacids” in water.