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101.
Abstract Novel moni-β-lactams derived from esters of amino acids have been prepared in one step by the high pressure promoted [2 + 2] cycloaddition of enol ethers with isocyanates derived from esters of amino acids. The effect of substituents in the enol ether and in the isocyanate on the scope of the synthesis has been demonstrated. 相似文献
102.
103.
Martín A. Iglesias Arteaga Roxana Pérez Gil Vivian Leliebre Lara Carlos S. Pérez Martinez Francisco Coll Manchado Arístides Rosado Pérez 《合成通讯》2013,43(8):1381-1386
The synthesis of a plant growth promoter furostanol which bears the characteristic functionality of teasterone on rings A and B is described. 相似文献
104.
Yu Shinke Arihiro Kanazawa Shokyoku Kanaoka Sadahito Aoshima 《Journal of polymer science. Part A, Polymer chemistry》2012,50(24):5041-5048
Living cationic polymerization of a vinyl ether with a naphthyl group [2‐(2‐naphthoxy)ethyl vinyl ether, βNpOVE] was achieved using base‐assisting initiating systems with a Lewis acid. The Et1.5AlCl1.5/1,4‐dioxane or ethyl acetate system induced the living cationic polymerization of βNpOVE in toluene at 0 °C. The living nature of this reaction was confirmed by a monomer addition experiment, followed by 1H NMR and matrix‐assisted laser desorption ionization time‐of‐flight mass spectrometry (MALDI‐TOF‐MS) analyses. In contrast, the polymerization of αNpOVE was not fully controlled; under similar conditions, it produced polymers with broad molecular weight distributions. The 1H NMR and MALDI‐TOF‐MS spectra of the resultant poly(αNpOVE) revealed that the products had undesirable structures derived from Friedel–Crafts alkylation. The higher reactivity of αNpOVE in electrophilic substitution reactions, such as the Friedel–Crafts reaction, was attributable to the greater electron density of the naphthyl ring, which was calculated based on frontier orbital theory. The naphthyl groups significantly affected the properties of the resultant polymer. For example, the glass transition temperatures (Tg) of poly(NpOVE)s are higher by approximately 40 °C than that of poly(2‐phenoxyethyl vinyl ether). © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
105.
Hiroaki Shimomoto Dai Fukami Tomomi Irita Ken‐ichi Katsukawa Takabumi Nagai Shokyoku Kanaoka Sadahito Aoshima 《Journal of polymer science. Part A, Polymer chemistry》2012,50(8):1547-1555
Various types of fluorine‐containing star‐shaped poly(vinyl ether)s were successfully synthesized by crosslinking reactions of living polymers based on living cationic polymerization. Star polymers with fluorinated arm chains were prepared by the reaction between a divinyl ether and living poly(vinyl ether)s with fluorine groups (C4F9, C6F13, and C8F17) at the side chain using cationogen/Et1.5AlCl1.5 in a fluorinated solvent (dichloropentafluoropropanes), giving star‐shaped fluorinated polymers in high yields with a relatively narrow molecular weight distribution. The concentration of living polymers for the crosslinking reaction and the molar feed ratio of a bifunctional vinyl ether to living polymers affected the yield and molecular weight of the star polymers. Star polymers with block arms were prepared by a linking reaction of living block copolymers of a fluorinated segment and a nonfluorinated segment. Heteroarm star‐shaped polymers containing two‐ or three‐arm species were synthesized using a mixture of different living polymer species for the reaction with a bifunctional vinyl ether. The obtained polymers underwent temperature‐induced solubility transitions in various organic solvents, and their concentrated solutions underwent sol–gel transitions, based on the solubility transition of a thermoresponsive fluorinated segment. Furthermore, a slight amount of fluorine groups were shown to be effective for physical gelation when those were located at the arm ends of a star polymer. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
106.
Ramesh Naik 《合成通讯》2013,43(10):1723-1726
Dimethylsulfoxide (DMSO) oxidizes benzyl ethers into corresponding benzaldehydes at 110°C; the reaction is accelerated by 49% aq. HBr. The conditions work well for different aryl‐substituted benzyl ethers. This protocol is inert toward dialkyl ethers. 相似文献
107.
J. Albaiges 《International journal of environmental analytical chemistry》2013,93(7):535-538
This work is a thorough investigation on the major operating parameters of the programmable temperature vaporisation (PTV) inlet used for gas chromatographic injection, including injection mode and volume, inlet temperature, vent and purge flow rates. The results clearly demonstrate the advantage of large volume injection in enhancing the detection of polybrominated diphenyl ethers (PBDEs). Partial loss of injected PBDEs occurred during solvent venting and due to incomplete sample transfer. Such loss was minimised by lowering the initial inlet temperature and vent flow and elevating the final inlet temperature. The results show that 50 mL/min vent flow, as low as 0°C initial and higher than 300°C final inlet temperatures produced the relatively high responses. Two mass spectrometric parameters were also evaluated. Indoor dust, lake sediment and human placenta tissue samples were analysed to demonstrate reliability and sensitivity improvement of the PTV large volume injection. 相似文献
108.
Abstract Two trithiamacrocycles have been designed by molecular modelling to have preorganised endodentate sulfur donor atoms. These new macrocycles have five- and six-membered saturated heterocycles inserted into 2,5,8-trithia[9]-m-benzenophane; molecular dynamics simulations suggest that the endo forms will be rigid on a nanosecond timescale. Optimum metal-sulfur distances which the new ligands will accommodate lie between 2.76 Å and 2.95 Å, suggesting they will be particularly suitable for a large soft metal ion such as silver(I). 相似文献
109.
The syntheses of four aza-15-crown-5 ethers bearing phenyl and phenoxymethyl moieties attached to a stereogenic centre on the crown ring were achieved. Macrocycles have exhibited strong binding ability (Ka = 5364–12,969 M? 1) and modest enantiomeric discrimination towards the enantiomers of amino acid methyl ester salts by UV titration method in CHCl3 at 25°C. Computer modelling results supported experimental data providing a detailed understanding of the molecular recognition mode between hosts and guests and the likely binding sites involved. Macrocycles were used for chiral discrimination of amino acids in their zwitterionic forms or as potassium and sodium salts in transport experiments across a bulk chloroform membrane with satisfactory selectivity. 相似文献
110.
Özlem Sarıöz Osman Serindaĝ Meysun İ. Abdullah 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1785-1795
Functionalized bis(amino)phosphines of the type PhP(NHR)2 ( 1a–c ) and aminophosphines of the type Ph2PNHR ( 2a–c ) have been synthesized by treating PhPCl2 or Ph2PCl with corresponding primary amines of H2N-R where R = -CH2SO3H, -C6H4SO3H, and benzo-15-crown-5. The molybdenum(0) complex of the aminophosphine ( 3 ) has been obtained by reacting cis-[Mo(CO)4(bipy)] with aminophosphine ( 2c ). The synthesized aminophosphines, bis(amino)phosphines, and the molybdenum(0) complex have been characterized by IR, 1H NMR, 31P NMR, and MS spectroscopic techniques and by elemental analysis. 相似文献