全文获取类型
收费全文 | 1047篇 |
免费 | 128篇 |
国内免费 | 42篇 |
专业分类
化学 | 1154篇 |
晶体学 | 6篇 |
综合类 | 1篇 |
数学 | 1篇 |
物理学 | 55篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 25篇 |
2021年 | 26篇 |
2020年 | 52篇 |
2019年 | 40篇 |
2018年 | 29篇 |
2017年 | 22篇 |
2016年 | 38篇 |
2015年 | 40篇 |
2014年 | 54篇 |
2013年 | 73篇 |
2012年 | 65篇 |
2011年 | 42篇 |
2010年 | 39篇 |
2009年 | 52篇 |
2008年 | 60篇 |
2007年 | 68篇 |
2006年 | 61篇 |
2005年 | 63篇 |
2004年 | 61篇 |
2003年 | 50篇 |
2002年 | 19篇 |
2001年 | 27篇 |
2000年 | 19篇 |
1999年 | 37篇 |
1998年 | 17篇 |
1997年 | 30篇 |
1996年 | 13篇 |
1995年 | 12篇 |
1994年 | 8篇 |
1993年 | 15篇 |
1992年 | 9篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 8篇 |
1987年 | 1篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1973年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有1217条查询结果,搜索用时 31 毫秒
21.
22.
An application of coupled column ion chromatography (IC)-inductively coupled plasma mass spectrometry (ICP-MS) is presented for speciation of chromium in waste waters. By coupling an anion column with a cation column, both the cationic Cr(III) and anionic Cr(VI) species can be analyzed with detection limits below 0.5 μg/1. The separation of the interfering ions (chloride, chlorate, perchlorate, sulphate, sulphite, sulphide, thiosulphate, carbonate, cyanide and some organic compounds) from the chromium peaks is discussed, and the use of different chromium isotopes for data acquisition is compared. Based on the results, m/z 52 was considered as an ideal isotope for speciation of chromium in waste waters by the coupled column IC-ICP-MS, because it did not suffer from polyatomic interferences and due to the high sensitivity for chromium. The analysis of the waste water samples should be performed as soon as possible after sampling according to the stability tests of the species. 相似文献
23.
The crystal-chemical structure of the minerals and inorganic compounds kuznetsovite [Hg3](AsO4)Cl and terlinguaite [Hg3][HgO2]Cl2, as well as [Hg3]3(AsO4)4 and [Hg3]2[HgO2](PO2 and their analogs, is considered from the viewpoint of the packing of large supramolecular atomic groups. The cationic layer of polyhedra around the large [Hg3]4+ cations, alternating with the anionic layer of [HgO2]2-, (AsO4)3-, (PO4)3-, Cl-, plays the major role in structure formation. Segregation of mercury cations of different valences possibly reflects the solid-state transformations occurring in nature and accompanied by mercury liberation. 相似文献
24.
金属离子在煤界面吸附对煤成浆性的影响 总被引:7,自引:1,他引:7
本文研究了六种金属离子在三种煤表面的吸附规律,研究结果表明:铜离子能够改善煤的制浆效果,即铜离子加入煤浆中,分散剂的用量降低50%,煤浆浓度提高;钙、镁、钴、锌离子对煤的成浆性不利的原因是它们不能有效地被吸附到煤表面,游离的金属离子和分散剂发生反应,使得吸附到煤表面的分散剂相对减少,煤的成浆性变差。 相似文献
25.
S. G. Zlotin O. V. Prokshits N. F. Karpenko Yu. A. Strelenko O. A. Luk'yanov 《Russian Chemical Bulletin》1992,41(8):1400-1413
We have worked out a method for the synthesis of 1,3,3-trisubstituted triazene 1-oxides based upon reaction of 1,1-disubstituted hydrazines with bromine in the presence of aryl- and heteroarylnitroso compounds in acid media. Obtained are a broad range of triazene 1-oxides, among which hitherto unknown compounds of the series of pyrazole and 3,3-dialkyltriazene 1-oxides that contain functional groups at the alkyl part of the molecule. We propose a reaction scheme which includes in situ formation of diazenium cations and reaction of them with nitroso compounds that are present in the system. By means of PMR,13C, and14N NMR spectroscopy, and mass spectroscopy, it has been shown that in all the prepared compounds the oxidated nitrogen atom is at the N1 position of the triazene N-oxide group.N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 8, pp. 1804–1820, August, 1992. 相似文献
26.
27.
以常见的阴、阳离子的检验为例,研究了如何实施基于标准的教学。校本教材的开发为标准、教材、教学、评价的一致性提供保障;以学生应知的和能做的驱动课堂活动;根据达成标准应有怎样的质量表现,试卷编制先于教学设计。课堂上,“教”“学”双方都明确学习目标,教师提供多种策略来满足学生多样的学习需要,如提供工具,搭建脚手架,并以“微”研究性学习的方式展开教学,给学生提供了充分的进步空间。 相似文献
28.
The partition of the spin label TEMPO in the hydrophobic region of di-palmitoyl-phosphatidylcholine unilamellar vesicles has been used to investigate the influence of high concentration (up 3M) of Li+, Na+, K+, and Cs+ on the phase transitions at 20–60°C. All of the above salts increase the permeation of TEMPO. The efficiency of monovalent cations in inducing the partition of the spin label in the hydrophobic environment of the bilayer increases in the order: Cs++++. The disappearing of the pretransition and the downward shift of the main phase transition temperature from 37°C to 33.5°C is related to the increased permeation of TEMPO into the bilayer. The presence of salts in the bulk solution disturbs the hydration of the zwitterionic polar head of the DPPC molecules and changes the electrical interaction between the polar groups of the bilayer. This reduces the packing density of the lipid molecules and promotes the permeation of TEMPO. 相似文献
29.
A. N. Bovin V. I. Evreinov Z. V. Safronova E. N. Tsvetkov 《Russian Chemical Bulletin》1993,42(5):912-916
A number of monopodands havingo-diphenylphosphinyl terminal groups were synthesized by alkylating sodium derivatives of oligoethylene glycols witho-(bromomethyl)phenyldiphenylphosphine. The stability constants of the complexes of these ligands with alkali metal cations at 25 °C were determined conductometrically in a THF—chloroform solution (41, v/v). The complexing ability of monopodands with respect to the cations studied increases monotonically as the number of electron-donating sites increases (from 3 to 8) for all of the cations except Li+ and, to some extent, Na+. In the case of Li+ a smooth decrease in the stability of the complexes is observed. The monopodands obtained in this work differ drastically in this regard from their structural isomers, bis[o-(diphenylphosphinylmethyl)phenyl] ethers of oligoethylene glycols, which had been studied previously.For part 10, see ref. 1.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 952–956, May, 1993. 相似文献
30.
Two new ditopic receptors for α,ω-alkanediyldiammonium cations based on a tetraazamacrocyclic (cyclidene) nickel(II) complex bearing two crown-ether residues were synthesized. The studies of the host-guest interaction between the receptors and a series of α,ω-diammonium salts by NMR titration in acetonitrile-d3 showed that 1:1 complexes are formed with Kassoc∼103-105 M−1. Receptor 1 with benzo-15-crown-5 arms showed substantial selectivity in binding of trimethylene- and tetramethylenediammonium dications, and 1-2 orders of magnitude weaker binding of shorter (C2) or longer (C5 and C6) diammonium cations. Receptor 2 with benzo-18-crown-6 arms showed higher affinity to all studied diammonium cations, but the recognition of the length of α,ω-diammonium cations was less pronounced. 相似文献