A 15-year record of seasonal variation in the isotopic composition of precipitation water over continental Portugal

The Nuclear and Technological Institute (Instituto Tecnológico e Nuclear—ITN) in cooperation with the International Atomic Energy Agency (IAEA) has been conducting a nationwide survey of hydrogen (²H/¹H) and oxygen (¹⁸O/¹⁶O) isotopic composition of monthly precipitation since 1988. This paper focuses on basic features of spatial and temporal distribution of δ¹⁸O and δ²H in the precipitation over Continental Portugal derived from ITN database. Phenomenological relationships between stable isotopes composition of precipitation and various climate-related parameters (local air temperature, distance to the Atlantic coast, altitude, amount of precipitation) are established and discussed.     

The integral operator with logarithmic kernel has only one positive eigenvalue

The aim of this short note is to show that the integral operator with the kernel log(x + y) being indefinite has only one positive eigenvalue.     

Intermediary rings in normal pairs

We establish in this paper a result that gives the number of intermediary rings between R and S where (R,S) is a normal pair of rings. This result answers in particular a question which was left open in [A. Jaballah, Finiteness of the set of intermediary rings in a normal pair, Saintama Math. J. 17 (1999) 59-61]. Further applications are also given.     

Global Hochschild (co-)homology of singular spaces

We introduce Hochschild (co-)homology of morphisms of schemes or analytic spaces and study its fundamental properties. In analogy with the cotangent complex we introduce the so-called (derived) Hochschild complex of a morphism; the Hochschild cohomology and homology groups are then the Ext and Tor groups of that complex. We prove that these objects are well defined, extend the known cases, and have the expected functorial and homological properties such as graded commutativity of Hochschild cohomology and existence of the characteristic homomorphism from Hochschild cohomology to the (graded) centre of the derived category.     

Unoriented Laplacian maximizing graphs are degree maximal

A connected graph is said to be unoriented Laplacian maximizing if the spectral radius of its unoriented Laplacian matrix attains the maximum among all connected graphs with the same number of vertices and the same number of edges. A graph is said to be threshold (maximal) if its degree sequence is not majorized by the degree sequence of any other graph (and, in addition, the graph is connected). It is proved that an unoriented Laplacian maximizing graph is maximal and also that there are precisely two unoriented Laplacian maximizing graphs of a given order and with nullity 3. Our treatment depends on the following known characterization: a graph G is threshold (maximal) if and only if for every pair of vertices u,v of G, the sets N(u)?{v},N(v)?{u}, where N(u) denotes the neighbor set of u in G, are comparable with respect to the inclusion relation (and, in addition, the graph is connected). A conjecture about graphs that maximize the unoriented Laplacian matrix among all graphs with the same number of vertices and the same number of edges is also posed.     

On the tensor rank of the multiplication in the finite fields

First, we prove the existence of certain types of non-special divisors of degree g−1 in the algebraic function fields of genus g defined over Fq. Then, it enables us to obtain upper bounds of the tensor rank of the multiplication in any extension of quadratic finite fields Fq by using Shimura and modular curves defined over Fq. From the preceding results, we obtain upper bounds of the tensor rank of the multiplication in any extension of certain non-quadratic finite fields Fq, notably in the case of F₂. These upper bounds attain the best asymptotic upper bounds of Shparlinski-Tsfasman-Vladut [I.E. Shparlinski, M.A. Tsfasman, S.G. Vladut, Curves with many points and multiplication in finite fields, in: Lecture Notes in Math., vol. 1518, Springer-Verlag, Berlin, 1992, pp. 145-169].     

Complete assignments of the 1H and 13C NMR spectra of five rearranged abietane diterpenoids

An NMR study of five highly functionalized and rearranged abietane diterpenoids is described. In addition to 1D NMR methods, including 1D NOESY spectra, 2D shift‐correlated experiments [¹H, ¹³C‐gHSQC‐¹J (C,H) and ¹H, ¹³C‐gHMBC‐ⁿJ (C,H) (n = 2 and 3)] were used for the complete and unambiguous ¹H and ¹³C chemical shift assignments of these substances. Copyright © 2002 John Wiley & Sons, Ltd.     

On the category Q-Mod

In this paper we consider the category Q-Mod of modules over a given quantale Q. The paper is motivated by constructions and results from the category of modules over a ring. We show that the category Q-Mod is monadic, consider its relation to the category Q-Top of Q-topological spaces and generalize a method of completion of partially ordered sets. Received December 20, 2005; accepted in final form December 4, 2006.     

Higher Hopf formulae for homology via Galois Theory

We use Janelidze's Categorical Galois Theory to extend Brown and Ellis's higher Hopf formulae for homology of groups to arbitrary semi-abelian monadic categories. Given such a category A and a chosen Birkhoff subcategory B of A, thus we describe the Barr-Beck derived functors of the reflector of A onto B in terms of centralization of higher extensions. In case A is the category Gp of all groups and B is the category Ab of all abelian groups, this yields a new proof for Brown and Ellis's formulae. We also give explicit formulae in the cases of groups vs. k-nilpotent groups, groups vs. k-solvable groups and precrossed modules vs. crossed modules.