球形壳聚糖树脂制备方法及吸附性能研究

本文采用滴加成球法制备球形壳聚糖树脂,对影响壳聚糖树脂粒径分布的多种因素进行了研究。研究了用戊二醛,环氧氯丙烷及乙二醇环氧丙基醚作交联剂时,不同交联剂对树脂吸附Ｎｉ＾２＋、Ｃｕ＾２＋、Ｚｎ＾２＋的吸附动力学曲线及吸附等温线的影响。研究了ｐＨ值,颗粒粒径、离子强度对吸附容量的影响。     

含偕胺肟基纤维对铬离子吸附性能的初步研究

本文制备了一种含胺肟基鳌合纤维,研究了纤维对六价铬吸附性能的影响因素,结果表明,纤维能将六价铬还原为三价铬,吸附量与温度、时间、溶液ｐＨ值有关,在ｐＨ值为２时,纤维对铬的吸附量最大．     

Liquidus Curves of NaNO3(aq) Calculatedfrom the Modified Adsorption Isotherm Modelfor Aqueous Electrolytes

Summary.  The Stokes-Robinson modification of the Brunauer-Emmett-Teller (BET) adsorption isotherm is used to calculate the liquidus curve of NaNO₃(aq) including the eutectic point and metastable phases. The method described here represents a simplified approach to predict the liquidus curves with sparse information. Received August 9, 1999. Accepted November 4, 1999     

Coupled radiotracer and voltammetric study of the adsorption of 1-hydroxy-ethane-1,1-diphosphonic acid on polycrystalline gold

Coupled application of a version of the in-situ radiotracer ‘foil’ method and voltammetry provided information on the time-, potential-, concentration- and pH-dependent adsorption of 1-hydroxy-ethane-1,1-diphosphonic acid (HEDP) on a polycrystalline gold electrode, and on the effect of Zn²⁺ ions on the adsorption phenomena. Adsorption processes on the oxide-free surface of gold were observed to be potential-dependent in the potential range 0.05–1.00 V (versus RHE), while formation and irreversible accumulation of oxidation products of HEDP could be detected at E>1.00 V. The relative adsorption strength of HEDP (its dissociation and/or oxidation products) was found to be higher on an oxide-free gold surface than on an oxide-covered one. The surface excess of HEDP increased with increasing pH. Addition of Zn²⁺ ions to the solution exerted a substantial effect on the HEDP accumulation. Namely, significant differences in the surface coverage, as well as in the kinetics and mechanism of HEDP adsorption could be detected in the potential regions below and above E=0.2 V. Reduction of Zn(II) species at E≤0.1 V is probably coupled with the induced adsorption of HEDP on an Au electrode, leading to the formation of a polymolecular HEDP–Zn surface complex layer.     

H2,CO和H2/CO在ZrO2催化剂上吸附行为研究

用insituFTIR法研究了H₂、CO及CO/H₂在ZrO₂表面的吸附行为.结果表明,H₂在ZrO₂表面吸附存在两种形态的羟基(即ZrOH和ZrOHZr),吸附温度增加,羟基数量增加.CO在200℃易与ZrO₂表面羟基作用形成甲酸盐物种,吸附温度升高时,该物种逐渐分解生成CO和ZrOH.当CO和H₂共存时,表面甲酸盐的量明显增加,并随温度增加,逐渐加氢形成甲氧基,最后生成甲烷.甲氧基的加氢过程较慢,所需反应温度也较高,被认为是CO加氢合成醇的速控步骤.     

酪氨酸在活性炭/水界面上的吸附

研究了不同pH值介质中酪氨酸在活性炭上的吸附行为.结果表明,pH值4.2～6.1时吸附量较大,在酪氨酸的等电点时吸附量最大;酪氨酸被吸附的主要形式是兼性离子;酪氨酸离子靠VanderWaals力吸附在活性炭/水界面上.用介质pH值对酪氨酸溶解度的影响和活性炭的表面性质解释了实验结果     

Compression behavior and structure of dense helium at high temperatures by molecular dynamics simulation

In this work,the isotherm and energy distribution at T=304 K of dense helium are studied by molecular dynamic (MD) simulations with exp-6 potential r*=2.9673 ? (the position of the well minimum) and ε/kB=10.8 K (ε is the well-depth and kB is the Boltzmann constant) given by Peter et al.,and different values of stiffness parameter α.The optimized value of α=12.7 is deduced that can describe the atomic interactions for dense helium satisfactorily.This optimized α in exp-6 potential is used to conduct MD simulations of two isotherms of dense helium at T=300 K and T=298K.The calculations are in good agreement with the experimental.We further employed this method to investigate the equation-of-state and structure of dense helium at higher temperatures and found that when the density remained 1.6 g/cm3,the second peak of the radial distribution function would disappear in the temperature range from 2000 to 3040 K,demonstrating that a solid-liquid transition or decrystallization had occurred.     

In Vitro Investigation on Interaction of Ranitidine Hydrochloride in the Presence of Cross-Linked Carboxymethyl Cellulose Sodium.

Summary: The adsorbance of ranitidine hydrochloride – drug selective H₂ histamine receptor inhibitor used In the treatment of gastric and duodenal ulcer was investigated in the presence of croscarmellose, a cross- linked polymer of polysaccharide character used as a swelling additive in oral pharmaceutical formulations – capsules, tablets and granules. The evaluation of adsorbance capability was carried out by means of a statistical method in in vitro conditions, taking into account environmental pH, concentration of the investigated drug as well as the properties of the polymer. Obtained results prove that the analyzed active agent is adsorbed on polymer at all the investigated pH ranges and the capability of polymer binding depends on environmental pH. The highest binding capability was revealed in samples with pH of 7.6, (adsorbance capacity k = 0.6958) while the lowest binding capability was observed at pH 1.5 (adsorbance capacity k = 0.0005) in the presence of croscarmellose sodium. Level of adsorption depends on the analyzed drug concentration and adsorption on polymer in increasing concentration and pH environment.     

用吸附数据对硅胶表面的分形分析

根据一种中孔硅胶对甲酸、乙酸、丙酸和四氯化碳蒸气吸附等温线的单层区域和毛细凝结区域的数据以及自四氯化碳稀溶液中吸附系列脂肪醇的结果计算了该硅胶表面分形维数D.除了由吸附四氯化碳等温线毛细凝结区域所得D值低于2外,由其它吸附数据得出的该硅胶的分维D近似相等(D=2.06±0.05).中孔硅胶低D值可用其孔结构特性解释.     

吸附相反应技术制备纳米TiO2/SiO2复合材料

以SiO₂表面形成的吸附层为反应器,在载体表面制备了纳米TiO₂粒子.溶剂置换实验直接给出了吸附层的存在以及吸附层作为纳米反应器的实验证据,TEM,XRD和电子能谱分析表明,载体表面形成一层比较均匀的纳米粒子.初步探讨了温度和反应物浓度对产物分布的影响,分析了各种现象产生的可能成因.