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41.
Poly(acrylamide) (PAM) with controlled molecular weight and tacticity was prepared by UV-irradiation-initiated controlled/living radical polymerization in the presence of dibenzyl trithiocarbonate (DBTTC) and Y(OTf)3. The rapid and facile photo-initiated controlled/living polymerization at ambient temperature led to controlled molecular weight and narrow polydispersity (Mw/Mn = 1.12-1.24) of PAM. The coordination of Y(OTf)3 with the last two amide groups in the growing chain radical effectively enhanced isotacticity of PAM. The isotactic sequence of dyads (m), triads (mm) and pentads (mmmm) in PAM were 70.32%, 50.95%, and 29.97%, respectively, which were determined by the resonance of methine (CH) groups in PAM under 13C NMR experiment. Factors affecting stereocontrol during the polymerization were studied, including the type of Lewis acids, concentration of Y(OTf)3, and monomer conversion. It is intriguing that the meso tacticity increased gradually with chain propagation and quite higher isotacticity (m = 93.01%, mm = 86.57%) was obtained in the later polymerization stage (conversion 65-85%). 相似文献
42.
以丙烯酰胺(AM)为亲水单体,脂肪醇聚氧乙烯醚丙烯酸酯(AEO-AC-n-m,n为疏水端烷基链碳的数目,m为亲水端PEG链的长度,n,m=13,5;10,5;13,10)为疏水单体,十二烷基硫酸钠(SDS)为表面活性剂,过硫酸钾(KPS)为引发剂,通过胶束聚合制备了3种聚丙烯酰胺-co-脂肪醇聚氧乙烯醚丙烯酸酯(AM-co-AEO-AC)疏水缔合水凝胶.以疏水烷基链为直链的疏水单体AEO-AC-13-5合成的直链型水凝胶的网络结构均匀且强度高,其形态在水中可维持180 d.而以疏水烷基链为支链的疏水单体AEO-AC-10-5与AEO-AC-13-10合成的支链型水凝胶的机械性能较弱,60 d内即溶解于水中.在相同条件下,直链型水凝胶断裂时的最大应力是支链型水凝胶的4~5倍.利用弹性橡胶理论中的新胡克方程计算了直链型和支链型水凝胶的有效交联密度ν0和有效交联点间的分子量Mc. 相似文献
43.
44.
对苯乙烯磺酸钠聚合动力学及与丙烯酰胺共聚合的研究 总被引:7,自引:1,他引:6
采用膨胀计法研究了对苯乙烯磺酸钠(SSS)在水溶液中聚合动力学,确定了聚合速率方程,测定了聚合表观活化能,并研究了对苯乙烯磺酸钠与丙烯酰胺(AM )在水溶液中共聚合的动力学行为,利用聚电解质———共聚物P(SSS -co -AM)与阳离子表面活性剂N ,N ,N- 三甲基十六烷基溴化铵(CTAB)的复合作用,采用电导滴定法测定了共聚物的组成,从而测得了对苯乙烯磺酸钠与丙烯酰胺的竞聚率.研究结果表明,对苯乙烯磺酸钠聚合速率方程为RP =K[M]1 .0 [I]0 .53,说明链终止为双基终止方式,引发过程与单体浓度无关;聚合表观活化能为84 . 96kJ·mol- 1 ;采用Kelen Tudos方法,求得对苯乙烯磺酸钠(SSS)和丙烯酰胺(AM)两单体的竞聚率分别为rSSS =0 . 2 7,rAM =2 . 2 1;采用Alfrey Price经验规则估算了单体苯乙烯磺酸钠的Q、e值为QSSS=0 .2 2 ,eSSS=0 .4 6 . 相似文献
45.
UV光引发的丙烯酰胺反相乳液聚合 总被引:7,自引:0,他引:7
报道了不透明丙烯酰胺反相乳液体系的UV光引发聚合新方法 .使用普通中压汞灯并辅以适当搅拌 ,UV光引发丙烯酰胺 水 煤油 Span80 +OP 10反相乳液聚合可在 2 0min左右完成 ,所得聚合物分子量达千万 ;聚合过程中不存在恒速期 ,扫描电镜未观察到聚合前后乳胶粒径有数量级的变化 ,表明聚合反应以单体液滴成核为主 .此外 ,考察了光引发剂类型及浓度、单体浓度、乳化剂用量、反应温度等对聚合反应的影响 ,结果表明不同光引发剂的引发活性为Irgacure 2 95 9>(ITX +EDAB) >BDK ,引发剂浓度增加 ,反应速度先增加而后降低 ,存在一最大值 ;单体浓度增加 ,反应速度加快 ,聚合物分子量提高 ;乳化剂用量增加 ,反应速度加快而分子量变化不明显 ;聚合表观活化能为 13 34kJ mol. 相似文献
46.
CO2对硅酸钠-丙烯酰胺溶液聚合行为及产物性质的影响 总被引:2,自引:0,他引:2
赵仁保 《高等学校化学学报》2009,30(3):596-600
研究了不同CO2分压下低浓度丙烯酰胺(AM)在硅酸钠溶液中的聚合反应行为, 用环境扫描电子显微镜、流变仪及激光粒度仪等研究了产物的微观结构及其流变特性. 结果表明, 随着CO2浓度的增加, 产物的储能模量增加, 即黏弹性增大; 反应后生成的硅酸凝胶镶嵌在聚丙烯酰胺高分子凝胶网格中形成了复杂的网状结构. 在超声波作用下, 硅酸凝胶颗粒从体系中脱离, 检测到的颗粒粒径范围在280~900 nm之间, 且随着超声时间的增加, 颗粒的平均粒径减小. 结果表明, CO2的存在使得AM及交联剂的分子扩散速度增加, 提高了AM分子之间及其与交联剂分子的接触几率, 从而提高了产物的分子量. 相似文献
47.
玻璃微流控通道中水凝胶固定寡核苷酸探针的方法及应用 总被引:1,自引:0,他引:1
核酸杂交是分子生物学研究中最常用和最基本的分析方法之一.杂交技术有多种,主要区别在于探针的固定.目前常用的是将探针直接固定在载体表面(尼龙膜或硅烷化的玻片)或用磁珠法和水凝胶法固定,其中水凝胶法兼有三维立体和简单实用的优势,其发展颇为引人注意.微流控芯片技术具有集成化和自动化的优势.将水凝胶和微流控技术相结合,将使核酸分析中的杂交、变性以及重新杂交等操作更为简单、快速、易行. 相似文献
48.
The present paper describes an analytical method based on liquid chromatography coupled to tandem mass-spectrometry (LC-MS/MS) for the determination of acrylamide in foodstuffs. Atmospheric pressure chemical ionization (APCI) as ionization source and an ion-trap (LCQ) analyzer were used, and to the best of our knowledge, this hyphenated technique has not ever been employed to this purpose. In order to obtain clean extracts an improved purification procedure based on the coupling of two highly cross-linked polystyrene-divinylbenzene polymeric sorbents: Strata-X-C and ENV+, was also developed. High recoveries (85%) and good reproducibility (relative standard deviation of 12%) were obtained using the two solid-phase extraction cartridges in combination. One hundred percent water as mobile phase was used for the LC separation. The obtained figures of merit showed detection limits of 250 pg for standards and 45 ng/g for samples, and run-to-run and day-to-day precisions of 3.3 and 8%, respectively. Acrylamide (AA) was determined in several of the most frequently eaten carbohydrate-rich foodstuffs commercialized in Spain such as potato crisps and chips, biscuits, crisp breads, pastry, dried fruits, chocolates and coffee. For the first time, a typical pastry product called as “churros” and highly consumed in Spain was also studied. Some of the products tested such as french fries frozen or “churros” were household cooked. Acrylamide was determined in the selected food commodities using the developed analytical methodology. A commonly used method by liquid chromatography coupled to tandem mass-spectrometry with a triple quadrupole as mass analyzer (LC-QqQ-MS/MS) was also applied in order to validate the analytical results. Different levels of acrylamide were obtained and pastry and dried fruits showed the lower levels (<20 ng/g). Potato chips and french fries gave values of the order of 500-9250 ng/g. 相似文献
49.
Vida Buinauskait? Vytas MartynaitisSven Mangelinckx Gediminas KreizaNorbert De Kimpe Algirdas Ša?kus 《Tetrahedron》2012,68(45):9260-9266
The reaction of azaheterocyclic enamines with acrylamide was employed for the preparation of novel fluorescent scaffolds possessing a benzo[e]indoline moiety. Reaction of 3-substituted 2-methylidene-1H-benzo[e]indole with acrylamide gave rise to spiro[benzo[e]indole-2,2′-piperidin]-6′-ones. Ring opening reactions of the latter spiro compounds were investigated. Benzo[e]indoline derivatives possessing 2-(3-carbamoylpropyl), 2-[3-(ethoxycarbonyl)propyl] and 2-(4-aminobutyl) side chains were synthesised. The optical properties of the benzo[e]indoline derivatives were studied by UV-vis and fluorescence spectroscopy. 相似文献
50.