Inhibit化学逻辑门: 基于Al3＋和Fe3＋的β-二酮荧光开关的研究

合成了1,3-二苯基-4-苯乙酰-5-吡唑酮(HDPP-PA)与Al^3＋, Fe^3＋形成的配合物, 通过元素分析、质谱、红外光谱、紫外-可见吸收、荧光光谱等测试方法, 对其组成和结构进行了表征, 发现Fe^3＋能有效地减弱Al配合物的荧光, 为此将HDPP-PA与Al^3＋和Fe^3＋组成一个具有INHIBIT操作功能的化学逻辑门.     

Reprint of : Scattering approach to scanning gate microscopy

We present a perturbative approach to the conductance change caused by a weakly invasive scattering potential in a two-dimensional electron gas. The resulting expressions are used to investigate the relationship between the conductance change measured in scanning gate microscopy as a function of the position of a scattering tip and local electronic quantities like the current density. We use a semiclassical approach to treat the case of a strong hard-wall scatterer in a half-plane facing a reflectionless channel. The resulting conductance change is consistent with the numerically calculated quantum conductance.     

Soundscape quality analysis by fuzzy logic: A field study in Cordoba,Argentina

This research studies urban soundscapes through the comparative analysis of twelve public open spaces in the city of Córdoba (Argentina), taken as case studies. The work aims to examine selection of indicators and assessment tools intended to characterize soundscape quality. The field study was carried out through surveys and acoustic and psychoacoustic indicators, that are used together to objectively describe the sound quality of urban spaces.     

HL-2A的中央逻辑控制PLC环网设计

PLC逻辑控制是HL-2A中央控制系统的重要组成部分,改造前的逻辑控制系统基本使用硬连接,维护耗时耗力。结合新一代实时工业以太网PROFINET为HL-2A逻辑控制系统的改造设计了环形冗余网络。采用8台西门子交换机SCALANCE X200通过光纤依次连接成环,交换机的电口连接S7-400和上位机,与等离子体放电相关的重要信号仍走硬连接,其他所有信号都走网络传送。中控系统作为管理站对其他7个子系统进行集中化管理,中控可以轻松快速地获取每个子系统的状态,在等离子体放电错误时能很快的预测事故地点和故障分析。根据放电实验结果表明,光纤环网非常适用于设备分散的慢控制系统,整个控制系统逻辑关系清楚,后期扩展和改造也非常方便。改造后的逻辑控制系统能满足HL-2A和HL-2M两套装置的慢控制,维护简便,事故定位快准,提高了放电效率。     

Ruthenium‐Amine Conjugated Organometallic Materials for Multistate Near‐IR Electrochromism and Information Storage

Monometallic and dimetallic complexes with the ruthenium‐amine conjugated structural unit have been prepared. These complexes display consecutive redox waves with low potentials and rich and intense absorptions in the near‐infrared region. The electrochemical and spectroscopic properties can be modulated using substituents or auxiliary ligands with different electronic natures. Through simple functionalization, electropolymerized or monolayer thin films of these complexes have been prepared. These films display multistate near‐infrared electrochromism with good contrast ratios and long optical retention times. In addition, flip‐flop and flip‐flap‐flop memories have been demonstrated on the basis of these thin films.

     

Molecular logic circuits and a security keypad lock based on a novel colorimetric azo receptor with dual detection ability for copper(II) and fluoride ions

A novel azoimine dye-based colorimetric chemosensor (1) has been designed and synthesised for dual recognition of copper(II) and fluoride ions in aqueous media. Significantly, the outstanding dual-ion recognition properties along with the excellent reversibility prompted us to consider 1 as an ideal candidate for fabrication of multiple logic circuits. According to the response profile of 1 towards Cu²⁺ and F^? inputs, we developed a unique tunable system integrated with one INHIBIT logic gate as well as one OR gate. Also, 1 behaved as a molecular keypad lock with sequential addition of Cu²⁺ and F^? inputs. In accession, a reversible ‘Write–Read–Erase–Read’ function with complementary ‘IMP/INH’ logic gate has been demonstrated through a feedback loop using F^? and trifluoroacetic acid as two chemical inputs. To the best of our knowledge, this is the first report where the symmetrical bis azo-azomethine dye has been exploited as a molecular keypad lock.     

二次耦合直流输出的金属氧化物TFT行驱动电路

为了弥补现有氧化物TFT的行驱动电路输出模块在功率消耗、响应速度、输出摆幅等方面的不足,提出了基于二次耦合的直流输出模块,并由此研究设计新的行驱动电路拓扑。仿真结果表明,该输出模块具有驱动能力强、响应速度快等优点。最后,基于刻蚀阻挡层(ESL)结构的氧化物TFT工艺,在玻璃衬底上成功制备了该行驱动电路,实测单级功耗为325μW。     

Adaptive fuzzy backstepping control for a class of MIMO switched nonlinear systems with unknown control directions

In this article, an adaptive fuzzy output tracking control approach is proposed for a class of multiple‐input and multiple‐output uncertain switched nonlinear systems with unknown control directions and under arbitrary switchings. In the control design, fuzzy logic systems are used to identify the unknown switched nonlinear systems. A Nussbaum gain function is introduced into the control design and the unknown control direction problem is solved. Under the framework of the backstepping control design, fuzzy adaptive control and common Lyapunov function stability theory, a new adaptive fuzzy output tracking control method is developed. It is proved that the proposed control approach can guarantee that all the signals in the closed‐loop system are bounded and the tracking error remains an adjustable neighborhood of the origin. A numerical example is provided to illustrate the effectiveness of the proposed approach. © 2015 Wiley Periodicals, Inc. Complexity 21: 155–166, 2016