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91.
The initial sticking probability of chlorine on Fe(100) at room temperature is calculated to be 0.13, and there is evidence to suggest that the chlorine adsorbs into a short lived mobile precursor state above the surface. The work function change, Δφ, is proportional to coverage and reaches a maximum value of 1.43 eV at saturation. At this coverage a c(2 × 4) LEED pattern is formed. On heating, chlorine is lost from the surface, but the mechanism is such that no detectable loss is incurred at a constant elevated temperature. The c(2 × 4) pattern is shown to be a coincidence structure formed from a net of chlorine atoms on the Fe(100) substrate. This structure is a special case of the more general structure formed at lower concentrations of chlorine. The c(2 × 4) is formed when α = 56.31°, which gives the chlorine atoms a hard sphere diameter of 0.345 nm and a concentration of 0.75 atoms per four-fold site. 相似文献
92.
E. Ekici 《Acta Mathematica Hungarica》2007,117(4):325-333
The main purpose of this paper is to introduce the concepts of *-sets, *-continuous functions and to obtain new decompositions of continuous and ηζ-continuous functions. Moreover, properties of *-sets and some properties of -sets are discussed.
相似文献
93.
We develop structural formulas
satisfied by some families of
orthogonal matrix polynomials of size $2\times 2$ satisfying
second-order differential equations with polynomial coefficients. We consider
here two one-parametric families of weight matrices,
namely
\[
H_{a,1}(t)\;=\;e^{-t^2} \left( \begin{array}{@{}cc@{}}
1+\vert a\vert ^2t^2 & at \\bar at & 1 \end{array} \right) \quad {\rm and} \quad H_{a,2}(t)\;=\;e^{-t^2} \left( \begin{array} {@{}cc@{}}
1+\vert a\vert ^2t^4 & at^2 \\bar at^2 & 1
\end{array} \right),
\]
$a\in \mbox{\bf C} $ and $t\in \mbox{\bf R} $, and their corresponding orthogonal
polynomials. 相似文献
94.
95.
In this paper, we establish Ekeland’s variational principle and an equilibrium version of Ekeland’s variational principle for vectorial multivalued mappings in the setting of separated, sequentially complete uniform spaces. Our approaches and results are different from those in Chen et al. (2008), Hamel (2005), and Lin and Chuang (2010) [13], [14] and [15]. As applications of our results, we study vectorial Caristi’s fixed point theorems and Takahashi’s nonconvex minimization theorems for multivalued mappings and their equivalent forms in a separated, sequentially complete uniform space. We also apply our results to study maximal element theorems, which are unified methods of several variational inclusion problems. Our results contain many known results in the literature Fang (1996) [21], and will have many applications in nonlinear analysis. 相似文献
96.
María M. Martínez 《Journal of Mathematical Analysis and Applications》2011,375(1):196-206
Let X be a Banach space and let f∈L∞(R+;X) whose Laplace transform extends analytically to some region containing iR?{0}, possibly having a pole at the origin. In this paper, we give estimates of the decay of certain slight suitable modification of f in terms of the growth of its Laplace transform along the imaginary axis. This technique is applied to obtain decay estimates of smooth orbits of bounded C0-semigroups whose infinitesimal generators have an arbitrary finite boundary spectrum. These results are close to those given recently by C.J.K. Batty and T. Duyckaerts. 相似文献
97.
采用传统固相法和水热法成功地制备出棒状La2Zr2O7:Eu3+荧光粉. 利用X射线粉末衍射仪、透射电镜和荧光光谱仪等分析了产物的结构、形貌和发光特性. 结果表明红色荧光粉La2Zr2O7:Eu3+有良好的晶相,属于立方结构,空间点群为Fd3m; 其形貌主要为纳米棒, 平均直径约47 nm, 长度为50~700 nm. 并对纳米棒的生长机理进行了探讨. 在466 nm蓝光激发下,La2Zr2O7:Eu3+荧光粉能发射出Eu3+的特征红色荧光,发射主峰位于616 nm处,归属于Eu3+的5DO→7F2超灵敏电偶极跃迁.此外,在产物的发射光谱中能够观察到5D1→7FJ (J=0, 1, 2)跃迁和5D1→7FJ (J=1, 2, 4)跃迁的劈裂峰,这说明Eu3+处在低对称性的晶体场格位中. 相似文献
98.
ABSTRACT Optimized geometrical structure and harmonic vibration frequencies of prior synthesized (E)-3-phenyl-N-[4-(phenyl-amino) quinazoline-7-yl] acrylamide were computed by ab initio HF and DFT/B3LYP methods using both 6-31G* and 6-311G** basis sets and the Moller–Plesset second-order perturbation (MP2) method merely at the 6-31G* level. The infrared (IR) spectrum of the title compound has been measured in the range of 400–4000 cm?1. Complete vibrational assignments of the IR spectra were proposed. Moreover, the calculated wavenumbers of the title compound were compared with the experimental data. The correlation analyses indicate that good linearity relationships exist between the scaled theoretical vibration frequencies and the experimental values. Additionally, the atoms in molecules (AIM) method was applied to explore the possible intramolecular interactions in the title compound. 相似文献
99.
Paulo A. R. Pires Muhammad Imran Carina Loffredo Paulo M. Donate Daniel Previdi Omar A. El Seoud 《Journal of Physical Organic Chemistry》2013,26(3):280-285
The effects of solvents on chemical phenomena (rate and equilibrium constants, spectroscopic transitions, etc.) are conveniently described by solvation free‐energy relationships that take into account solvent acidity, basicity and dipolarity/polarizability. The latter can be separated into its components by manipulating the UV–vis spectra of two solvatochromic probes, 2‐(N,N‐dimethylamino)‐7‐nitrofluorene (DMANF) and a di‐(tert‐butyl)‐tetramethyl docosanonaen probe (ttbP9) whose synthesis is laborious and expensive. Recently, we have shown that the natural dye β‐carotene can be conveniently employed instead of ttbP9 for the determination of solvent polarizability (SP) of 76 molecular solvents and four ionic liquids. In the present work, we report the polarizabilities of further 24 solvents. Based on the solvatochromism of β‐carotene and DMANF, we have calculated solvent dipolarity (SD) for 103 protic and aprotic molecular solvents, and ionic liquids. The dependence of SD and SP on the number of carbon atoms in the acyl‐ or alkyl group of several homologous series (alcohols; 2‐alkoxyethanols; carboxylic acid‐ anhydrides, and esters, ionic liquids) is calculated and briefly discussed. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
100.
In this paper we report the combustion synthesis of trivalent rare-earth (RE3+ = Dy, Eu and Ce) activated Sr4Al2O7 phosphor. The prepared phosphors were characterized by the X-ray powder diffraction (XRD) and photoluminescence (PL) techniques. Photoluminescence emission peaks of Sr4Al2O7:Dy3+ phosphor at 474 nm and 578 nm in the blue and yellow region of the spectrum. The prepared Eu3+ doped phosphors were excited by 395 nm then we found that the characteristics emission of europium ions at 615 nm (5D0?7F2) and 592 nm (5D0?7F1). Photoluminescence (PL) peaks situated at wavelengths of 363 and 378 nm in the UV region under excitation at around 326 nm in the Sr4Al2O7:Ce3+ phosphor. 相似文献