Syntheses of chiral fused 4,5-diazafluorene–bis(nopinane) derivatives

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Structure and quantum chemical study of crystalline platinum(II) acetate

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Quantum chemical calculations of hydration electrostatics and electrochemical oxidation potential of cyclic nitroxide radicals

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Hierarchical structure of SERS substrates possessing the silver ring morphology

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α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization

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Novel Route for Preparation of 7‐Methyl‐camptothecin and Its Possible Mechanism

A novel route for preparation of 7‐methyl‐camptothecin is described. Its possible mechanism is discussed.     

Fabrication of anti-poisoning core-shell TiO2 photocatalytic system through a 4-methoxycalix[7]arene film

TiO₂ nanoparticles with unique crystalline-core/disordered-shell structures were synthesized in a one step process by employing 4-methoxycalix[7]arene nanoreactors. The nanoparticles were anchored on the surface of quartz beads as a monolayer and showed high visible-light driven photocatalytic activity, excellent long term durability and anti-poisoning property. Photocatalytic performance of the TiO₂ nanoparticles was tested in a packed bed and complete decolorization of methyl orange was achieved under ultraviolet light or visible light. The decolorization process followed first-order kinetics and showed different behaviors for ultraviolet and visible radiation, while the overall rates of degradation were the same.     

Crystallographic and microstructural aspects of the superconductor YBa2Cu3O7-y —an overview

Crystal structures and structural inhomogeneities observed in YBa₂Cu₃O_7-y are reviewed. It is brought out that a proper understanding of the nature of the structural inhomogeneities is essential for exploiting the technological potential of this material. The need for an adequate characterization of specimens used for experiments is emphasized. Practical implications of the ferroelastic nature of the material are discussed.