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191.
R. M. Zolotar' A. I. Bykhovets S. N. Sokolov N. V. Kovganko 《Chemistry of Natural Compounds》2002,38(1):66-69
The toxicity of steroids 1-11 for colorado beetle (Leptinotarsa decemlineata Say.) larvae was studied by contact-intestinal treatment. Active insect-growth regulators were found among the studied compounds. 相似文献
192.
Xiongyu Wu 《Tetrahedron letters》2005,46(9):1501-1504
A fast and efficient microwave promoted one-pot method for deoxygenation of heterocyclic halo-benzyl alcohols has been developed. The method does not cause dehalogenation of the substrates and provides the deoxygenated products in high yield after only 30 min. 相似文献
193.
Mössbauer parameters of frozen aqueous solutions of Sn(ClO4)2 in 0.5 M HClO4 did not change with the concentration of NaClO4, so that it was used to keep the ionic strength at the desired level. When NaCl was added into Sn(ClO4)2 solutions, isomer shift did not change, but quadrupole splitting did. Therefore, stability constants were calculated from the quadrupole splitting data, which were in good agreement with the published values. The observed spectra could be resolved into components. 相似文献
194.
195.
The basic theory of symplectic algorithm was introduced. A comparison between Runge-Kutta method and symplectic integration method was preformed in the simulation of the long time behavior of H + H2 system on BKMP potential energy surface. Our results reveal a dis-sipative behavior in the integral of ordinary differential equation by the fourth order Runge-Kutta method, which causes incorrect simulation results in QCT calculations. However, when the symplectic integration method is applied, the dissipative behavior is not found in the same system. When the initial state is the same, the energy deviation of fourth order symplectic integral method is almost one percent of that of fourth order Runge-Kutta method in a 60000-step simulation, and that of sixth order symplectic integral method is much less. These results show that the symplectic integral methods are always the better choice in the integral calculation of the long time behavior in maintaining energy conservation. 相似文献
196.
Somashekar BS Nagana Gowda GA Ramesha AR Khetrapal CL 《Magnetic resonance in chemistry : MRC》2004,42(7):636-640
A protonation and dynamic structural study of doxylamine succinate, a 1:1 salt of succinic acid with dimethyl-[2-(1-phenyl-1-pyridin-2-yl-ethoxy)ethyl]amine, in solution using one- and two-dimensional 1H and 13C NMR experiments at variable temperature and concentration is presented. The two acidic protons of the salt doxylamine succinate are in 'intermediate' exchange at room temperature, as evidenced by the appearance of a broad signal. This signal evolves into two distinct signals below about -30 degrees C. A two-dimensional 1H-1H double quantum filtered correlation experiment carried out at -55 degrees C shows protonation of one of the acidic protons to the dimethylamine nitrogen. A two-dimensional rotating frame 1H-1H NOE experiment at the same temperature reveals that the other proton remains with the succinate moiety. Comparison of the 1H and 13C chemical shifts and the 13C T1 relaxation times of the salt with those of the free base further substantiate the findings. 相似文献
197.
198.
The subject of the investigations are precipitation zones, which grew as a result of chemical diffusion in AgPd30/CuSn6 bimetals. These precipitation zones have been characterized by metallography, electron probe microanalysis and x-ray diffraction. The growth of precipitation zones in the plating layer and in the substrate layer in dependence on time have been determined. The use of x-ray diffraction alone for the identification of the precipitates could not supply satisfying results in every case. This problem was solved by the application of electron probe microanalysis using a correction method, which allows the estimation of the chemical composition of small particles.Dedicated to Professor Dr. rer. nat. Dr. h. c. Hubertus Nickel on the occasion of his 65th birthday 相似文献
199.
200.
For the weakly coupled lattice
3
6
theory in a hierarchical model approximation a nonperturbative renormalization group analysis in the spirit of Gawedzki and Kupiainen is performed to study the flow of the effective actions. We deduce a domain of attraction to the tricritical (Gaussian) fixed point. The two relevant coupling constants of the problem are controlled by analytic continuation to complex domains, tracing their images under the renormalization group iterations. 相似文献