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81.
Diamond-like carbon (DLC) films were deposited on Si(1 0 0) substrates using plasma deposition technique. The deposited films were irradiated using 2 MeV N+ ions at fluences of 1×1014, 1×1015 and 5×1015 ions/cm2. Samples have been characterized by using Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and high-resolution transmission electron microscopy (HRTEM). Analysis of Raman spectra shows a gradual shift of both D and G band peaks towards higher frequencies along with an increase of the intensity ratio, I(D)/I(G), with increasing ion fluence in irradiation. These results are consistent with an increase of sp2 bonding. XPS results also show a monotonic increase of sp2/sp3 hybridization ratio with increasing ion fluence. Plan view TEM images show the formation of clusters in the irradiated DLC films. HRTEM micrographs from the samples irradiated at a fluence of 5×1015 ions/cm2 show the lattice image with an average interplanar spacing of 0.34 nm, revealing that the clusters are graphite clusters. The crystallographic planes in these clusters are somewhat distorted compared to the perfect graphite structure. 相似文献
82.
In [A.L. Carey, J. Phillips, A. Rennie, Twisted cyclic theory and an index theory for the gauge invariant KMS state on Cuntz algebras. arXiv:0801.4605], we presented a K-theoretic approach to finding invariants of algebras with no non-trivial traces. This paper presents a new example that is more typical of the generic situation. This is the case of an algebra that admits only non-faithful traces, namely SUq(2) and also KMS states. Our main results are index theorems (which calculate spectral flow), one using ordinary cyclic cohomology and the other using twisted cyclic cohomology, where the twisting comes from the generator of the modular group of the Haar state. In contrast to the Cuntz algebras studied in [A.L. Carey, J. Phillips, A. Rennie, Twisted cyclic theory and an index theory for the gauge invariant KMS state on Cuntz algebras. arXiv:0801.4605], the computations are considerably more complex and interesting, because there are non-trivial ‘eta’ contributions to this index. 相似文献
83.
Sie-Tiong Ha Teck-Ming Koh Guan-Yeow Yeap Hong-Cheu Lin Siew-Ling Lee Yip-Foo Win 《Phase Transitions》2013,86(3):195-204
A series of new rod-shaped mesomorphic compounds, 6-ethoxy-2-(4-alkanoyloxybenzylidenamino)benzothiazoles, consisting of a 2,6-disubstituted benzothiazole core and a Schiff base central linkage, were synthesized and their structures were ascertained via elemental analysis and spectroscopic techniques. Their mesomorphic properties were studied using differential scanning calorimetry (DSC), polarized optical microscopy (POM) and X-ray diffraction (XRD) analysis. All compounds showed enantiotropic mesomorphism. Whilst the lower members of the series, hexanoyloxy and octanoyloxy derivatives exhibited nematic phase, the higher members (decanoyloxy, dodecanoyloxy, tetradecanoyloxy, hexadecanoyloxy and octadecanoyloxy derivatives) exhibited nematic and smectic C phases. 相似文献
84.
Hiroshi Yasuoka Susumu Sasaki Takashi Imai Tadashi Shimizu Yutaka Ueda Koji Kosuge 《Phase Transitions》2013,86(4):183-199
The nuclear quadrupole resonance (NQR) technique has been utilized to characterize the local oxygen coordination of inequivalent Cu sites in YBa2Cu3O6+x(0 ≤ x ≤ 0.91). Essentially, four distinct NQR lines which correspond to 2, 3,4 oxygen coordinated Cu sites in the Cu-O chains and 5 oxygen coordinated Cu sites in the Cu-O planes have been observed. The zero-field NQR frequencies of these are centered at about 30.1, 24.0, 22.0 and 31.5 MHz for 63Cu, respectively. For the antiferromagnetic ordered state (x ≤ 0.3), antiferromagnetic nuclear resonance (AFNR) has been observed at 90 MHz with quadrupole splittings associated with the moment-bearing Cu sites in the Cu-O planes. The relative intensities of these resonance lines depend on the oxygen content, and this gives us a microscopic understanding of the Cu chemistry of this system. 相似文献
85.
Evgueni Antipov Yuri Podolsky Nikolai Platé Manfred Stamm Erhard W. Fischer 《Journal of Macromolecular Science: Physics》2013,52(4):431-450
Abstract The structure, phase composition, and temperature behavior of two trans-1,4-polybutadienes (TPBs) were studied by means of x-ray scattering and differential scanning calorimetry (DSC) techniques. The two samples examined were (1) PB synthesized using an immobilized titanium-magnesium catalyst and (2) a random copolymer based on PB prepared with a homogeneous vanadium-containing catalyst used as a reference material. It was found that the nascent structure of the first PB involves three phases: crystalline, mesomorphic (low-temperature form), and amorphous. In the vicinity of 65°C, a first-order phase transition occurs. The system becomes biphasic and contains the high-temperature form of the mesophase, as well as the amorphous phase, component. Above 165°C, the polymer melts to form a single-phase isotropic melt with a structure typical of liquids. The lateral dimension of crystallites reversibly changes at the crystal-mesophase transition. It is suggested that during annealing of the mesophase formed by cooling of the isotropic melt, the chains acquire an extended conformation. Loss of regularity of the structure of macromolecules of TPB causes a reduction of phase transition temperatures, an increase of the imperfection of the crystalline phase, and a contraction of the temperature range of existence of the mesophase. 相似文献
86.
Christian R. Ast 《Physik in unserer Zeit》2017,48(5):230-234
87.
Shibayan Roy 《哲学杂志》2013,93(5):447-463
Deformation instabilities, such as shear cracking and grain boundary cavitation, which are observed in the secondary tensile region of Ti–6Al–4V alloy during compressive deformation in the (α?+?β)-phase field, do not form in Ti–6Al–4V–0.1B alloy when processed under the same conditions. This has been attributed to the microstructural modifications, e.g. the absence of grain boundary α and adjacent grain boundary retained β layers and a lower proportion of 90o-misoriented α-colonies that occur with boron addition. 相似文献
88.
《Composite Interfaces》2013,20(8-9):787-803
Poly(amide)-6/clay nanocomposites are investigated by means of modulated temperature differential scanning calorimetry. The importance of polymer–filler interaction is explored by comparing nanocomposites based on untreated and organically modified clay. During quasi-isothermal crystallization experiments, an excess contribution is observed in the recorded heat capacity signal due to reversible melting and crystallization. The magnitude of this excess contribution depends on the nanocomposite investigated. We suggest that it is directly related to the segmental mobility of the polymer chains in the interphase region. As such, the magnitude of this excess contribution can be used to quantify the efficiency of the polymer–clay interaction. Depending on the clay type used, differences in interfacial interaction can be achieved, which is of great importance with respect to the improvement of material properties. Based on thermal analysis results, a simple interphase model is proposed that is able to account for both the thermal and mechanical properties of poly(amide)-6/clay nanocomposites. 相似文献
89.
Breakthrough mode liquid chromatography was employed to investigate calcium (Ca) isotope fractionation in methanol medium. Highly porous silica beads, the inner pores of which were embedded with a benzo-18-crown-6 ether resin, were used as column packing material. Enrichment of heavier isotopes of Ca was observed in the frontal part of the respective Ca chromatograms. The values of the isotope fractionation coefficient (?) were in the order of 10?3 at 25 °C. Use of methanol as solvent has little advantage over the aqueous system as far as the values of ? are concerned. However, a substantial improvement was observed concerning the adsorption capacity of the crown ether resin for Ca ions. Molecular orbital calculations supported the present isotopic results in a qualitative fashion. 相似文献
90.
Ordered Sr2CrReO6 has been synthesized recently. It is measured to be ferrimagnetic semiconductor, in contrary to the previous reports of metallic properties. To solve the discrepancy, we have investigated the compound by using the density functional theory. The semiconducting behavior is reproduced by including the electron correlation and spin–orbit coupling simultaneously. The calculated band gap is 0.22 eV, close to the experimental value of 0.21 eV. A large orbital moment of 0.69µB is found for Re, which is caused by the Coulomb‐enhanced spin–orbit coupling. By applying pressure, a semiconductor to half‐metal transition is observed through 5% volume compression.