全文获取类型
收费全文 | 28192篇 |
免费 | 1190篇 |
国内免费 | 4761篇 |
专业分类
化学 | 28438篇 |
晶体学 | 302篇 |
力学 | 83篇 |
综合类 | 235篇 |
数学 | 2964篇 |
物理学 | 2121篇 |
出版年
2024年 | 29篇 |
2023年 | 244篇 |
2022年 | 622篇 |
2021年 | 736篇 |
2020年 | 731篇 |
2019年 | 829篇 |
2018年 | 727篇 |
2017年 | 830篇 |
2016年 | 963篇 |
2015年 | 912篇 |
2014年 | 1102篇 |
2013年 | 2448篇 |
2012年 | 1868篇 |
2011年 | 1626篇 |
2010年 | 1459篇 |
2009年 | 1642篇 |
2008年 | 1800篇 |
2007年 | 1973篇 |
2006年 | 1817篇 |
2005年 | 1597篇 |
2004年 | 1441篇 |
2003年 | 1154篇 |
2002年 | 1007篇 |
2001年 | 744篇 |
2000年 | 731篇 |
1999年 | 626篇 |
1998年 | 503篇 |
1997年 | 519篇 |
1996年 | 515篇 |
1995年 | 485篇 |
1994年 | 396篇 |
1993年 | 356篇 |
1992年 | 332篇 |
1991年 | 235篇 |
1990年 | 172篇 |
1989年 | 193篇 |
1988年 | 133篇 |
1987年 | 105篇 |
1986年 | 74篇 |
1985年 | 74篇 |
1984年 | 66篇 |
1983年 | 35篇 |
1982年 | 56篇 |
1981年 | 47篇 |
1980年 | 34篇 |
1979年 | 50篇 |
1978年 | 42篇 |
1977年 | 17篇 |
1976年 | 15篇 |
1973年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 109 毫秒
101.
巴旦杏中脂肪酸的测定 总被引:5,自引:1,他引:4
采用气相色谱仪进行定量分析,气-联质联用仪进行定性分析,巴旦杏中脂肪酸进行了测定,并探讨了样品处理方法和气-质联用仪的分析条件,得到了较为满意的分析结果。 相似文献
102.
N. S. Oliveira J. Dorgan J. A. P. Coutinho A. Ferreira J. L. Daridon I. M. Marrucho 《Journal of Polymer Science.Polymer Physics》2007,45(5):616-625
The sorption of carbon dioxide in glassy Poly(lactic acid) (PLA) films was studied by quartz crystal microbalance (QCM) at high pressures. Two thermal treatments, melted and quenched, were performed in PLA with two different L:D contents, 80:20 and 98:2, films and compared with a third thermal protocol, annealed, and used in a previous work. The results obtained show that for pressures higher than 2 MPa, the carbon dioxide solubility is larger in PLA 80:20 than in PLA 98:2, indicating that the L:D plays a dominant role on this property. The thermal treatments only affect the gas solubility in PLA 98:2. Sorption isotherms at temperatures 303, 313, and 323 K, below the glass transition temperature of the polymer, and pressures up to 5 MPa were measured and analyzed with three different models, the dual‐mode sorption model, the Flory–Huggins equation, and a modified dual‐mode sorption model where the Henry's law term was substituted by the Flory–Huggins equation. This last model performs especially well for CO2 in PLA 80:20, due to the convex upward curvature of the solubility isotherms for that system. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 616–625, 2007 相似文献
103.
The present paper covers a salt of 2:18 heteropoly complex of tungstotitanophosphate prepared with the method of improved sequence preparation. The title compound was characterized by elemental analysis, 31P NMR spectra, polarography, cyclic voltammetry, IR, UV, X-ray powder diffraction , X-ray photoelectron spectra and TG-DTA analysis. The results show that the complex with the formula K8[TiP2W17O62]·12H2O has Dawson structure. Its properties such as spectra, redox behavior and thermal stability are discussed. 相似文献
104.
François Loiseau Jean-Mary Simone David Carcache Pavel Bobal Reinhard Neier 《Monatshefte für Chemie / Chemical Monthly》2007,138(2):121-129
Summary. Free radical couplings from furan, as cheap starting material, were studied in view of developing a rapid strategy en route to the synthesis of derivatives of nonactin. The chain containing the alcohol function was introduced in one or two steps
in 86% yield. For the introduction of the second chain with the ester function two different coupling methods were tested.
Starting from the advanced intermediates obtained nonactin derivatives can be prepared by catalytic hydrogenation of the furan
ring. 相似文献
105.
Rosário Fernandes 《Linear algebra and its applications》2007,422(1):1-16
We consider the general problem of determining the maximum possible multiplicity of an eigenvalue in a Hermitian matrix whose graph contains exactly one cycle. For some cases we express that maximum multiplicity in terms of certain parameters associated with the graph. 相似文献
106.
Pavel Shumyatsky 《Monatshefte für Mathematik》2007,152(2):169-175
The following theorem is proved. Let n be a positive integer and q a power of a prime p. There exists a number m = m(n, q) depending only on n and q such that if G is any residually finite group satisfying the identity ([x
1,n
y
1] ⋯ [x
m,n
y
m
])q ≡ 1, then the verbal subgroup of G corresponding to the nth Engel word is locally finite. 相似文献
107.
The reactions of 5-methyl-3-hydroxyisoxazole with 2, 2-dimethyl, 3-substituted cyclopropanecarboxylic chlorides give O-acyl-5-methyl-3-hydroxyisoxazole and N-acyl-5-methylisoxazolin-3-one derivatives. The ratio of O-acyl to N-acyl product depends upon the acylation reagents. O-acyl derivatives can be converted to the N-acyl compounds by isomerization under acidic conditions or heating. 相似文献
108.
The lantadenes fraction from Lantana camara was isolated and transformed to the medicinally important intermediate 22β-hydroxyoleanonic
acid. The compound was studied for hepatotoxicity using lantadene A as standard and found to be nontoxic.
Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 357–358, July–August, 2006. 相似文献
109.
M.A. Batanin 《Advances in Mathematics》2007,211(2):684-725
It is well known that the forgetful functor from symmetric operads to nonsymmetric operads has a left adjoint Sym1 given by product with the symmetric group operad. It is also well known that this functor does not affect the category of algebras of the operad. From the point of view of the author's theory of higher operads, the nonsymmetric operads are 1-operads and Sym1 is the first term of the infinite series of left adjoint functors Symn, called symmetrisation functors, from n-operads to symmetric operads with the property that the category of one object, one arrow, …, one (n−1)-arrow algebras of an n-operad A is isomorphic to the category of algebras of Symn(A).In this paper we consider some geometrical and homotopical aspects of the symmetrisation of n-operads. We follow Getzler and Jones and consider their decomposition of the Fulton-Macpherson operad of compactified real configuration spaces. We construct an n-operadic counterpart of this compactification which we call the Getzler-Jones operad. We study the properties of Getzler-Jones operad and find that it is contractible and cofibrant in an appropriate model category. The symmetrisation of the Getzler-Jones operad turns out to be exactly the operad of Fulton and Macpherson. These results should be considered as an extension of Stasheff's theory of 1-fold loop spaces to n-fold loop spaces n?2. We also show that a space X with an action of a contractible n-operad has a natural structure of an algebra over an operad weakly equivalent to the little n-disks operad. A similar result holds for chain operads. These results generalise the classical Eckman-Hilton argument to arbitrary dimension.Finally, we apply the techniques to the Swiss-Cheese type operads introduced by Voronov and prove analogous results in this case. 相似文献
110.
We review the unusual structural, transport and magnetic properties of highly conducting polyaniline, doped with boron trifluoride.
Our studies establish the unique conducting state of this system, which is in distinct contrast with the conventional proton-doped
polyaniline samples. 相似文献