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61.
Adriana Tudose 《Tetrahedron letters》2006,47(48):8529-8533
Simple catalysts formed in situ from palladium acetate and a variety of imidazolium and imidazolinium carboxylates and dithiocarboxylates have been screened in the coupling of aryl halides with trans-2-phenylvinylboronic acid. Imidazol(in)ium carboxylates show an excellent activity, which compares to that displayed by the parent imidazol(in)ium chlorides, whereas imidazol(in)ium dithiocarboxylates are poorly efficient. Interestingly, the base employed exerts a profound influence on the trans/cis stereochemistry of the coupling product. 相似文献
62.
DIELECTRIC EFFECT ON THE RADIO-FREQUENCY CHARACTERISTICS OF A RECTANGULAR WAVEGUIDE GRATING TRAVELING WAVE TUBE 总被引:2,自引:0,他引:2
Zhigang Lu Yubin Gong Yanyu Wei Wenxiang Wang 《International Journal of Infrared and Millimeter Waves》2006,27(8):1095-1108
A new type of partial-dielectric-loaded rectangular waveguide grating slow-wave structure (SWS) for millimeter wave traveling
wave tube (TWT) is presented in this paper. The radio-frequency characteristics including the dispersion properties, the longitudinal
electric field distribution and the beam-wave coupling impedance of this structure are analyzed. The results show that the
dispersion of the rectangular waveguide grating circuit is weakened, the phase velocity is reduced and the position of the
maximum E
z
is basically invariant after partially filling the dielectric materials in the rectangular waveguide grating SWS. Although
the coupling impedance decreases a little, it still keeps above 40 Ω. 相似文献
63.
The steel ASTM A213 P22 is used for superheater outlet header in power plants. During duty cycles lasting over tens of years the temperature is of the order of 545°C and the pressure 125 atm. The microscopic changes in these steels are hard to analyze under working conditions, but they are believed to be responsible for the appearance of creeps in such devices. Investigation of the microscopic modifications will help to predict future failures due to creeps, increasing the reliability and saving a lot of money.We report the investigation of such changes in ASTM A213 P22 steel in use for 30 years as a Superheater header at Haifa power station. The analysis has been carried out using Mössbauer Spectroscopy, X-ray diffraction and optical microscopy. As a result it seems that the morphology and phase change of the carbide phases M3C/M7C3 and M23C6 are the most prominent changes leading to the material failures. 相似文献
64.
Hiroki Shigehisa 《Tetrahedron letters》2006,47(41):7301-7306
The first total synthesis of a spiro-isoquinoline alkaloid, (±)-annosqualine, was established by employing an enamide-phenol coupling of a 1-methylene-1,2,3,4-tetrahydroisoquinoline derivative with a hypervalent iodine reagent, where the formation of the phenoxide was recognized to be an essential step for the reaction of the phenolic hydroxyl group with the hypervalent iodine reagent leading to the formation of the desired product. 相似文献
65.
Surajit Some 《Tetrahedron letters》2006,47(7):1221-1224
A convenient synthetic approach to substituted benzene derivatives by modified Ullmann cross-coupling of 2-bromobenzaldehyde and bromovinylaldehydes followed by intramolecular McMurry coupling has been developed. 相似文献
66.
在常温常压下采用新型旋转电极等离子体反应器,对辉光等离子体作用下的甲烷偶联反应制C2烃进行了研究。结果表明,甲烷偶联反应的主要产物为C2H2,占C2烃的80%以上,能量效率在5.6%~11.2%之间;增加H2含量可以提高CH4转化率和C2烃收率;在500~2200kJ•mol−1的能量密度范围内,CH4转化率随能量密度的增大而线性增加,C2烃收率随着能量密度的增加呈峰形变化趋势。 相似文献
67.
H. Barentzen 《Annalen der Physik》2006,15(9):684-698
The eigenvalues of the weakly coupled T ? t Jahn‐Teller problem are known for several decades, and the same holds also true for the eigenstates. These, however, are only given in the traditional position representation, which proves inconvenient if one attempts to extend the weak‐coupling treatment into the region of stronger coupling. Here the solution of the T ? t eigenvalue problem at weak coupling is derived in terms of creation and annihilation operators. This reformulation of the problem is nontrivial, since the algebraic form of the oscillator eigenvectors, being simultaneous angular‐momentum eigenstates, has been worked out only recently and is probably still widely unknown. The electronic and oscillator eigenstates are then coupled to form eigenvectors of the total angular momentum. Finally, in preparation for an extension of the weak‐coupling treatment, the action of the boson creation and annihilation operators on the oscillator eigenvectors is calculated, thus completing the algebraic approach to the weakly coupled T ? t system. 相似文献
68.
Guantie Deng 《Bulletin des Sciences Mathématiques》2007,131(1):53
In this paper, using a modified Poisson kernel in an upper half-space, we prove that a harmonic function u(z) in a upper half space with its positive part u+(x)=max{u(x),0} satisfying a slowly growing condition can be represented by its integral in the boundary of the upper half space, the integral representation is unique up to the addition of a harmonic polynomial, vanishing in the boundary of the upper half space and that its negative part u−(x)=max{−u(x),0} can be dominated by a similar slowly growing condition, this improves some classical result about harmonic functions in the upper half space. 相似文献
69.
Crossed modules have longstanding uses in homotopy theory and the cohomology of groups. The corresponding notion in the setting of categorical groups, that is, categorical crosses modules, allowed the development of a low-dimensional categorical group cohomology. Now, its relevance is also shown here to homotopy types by associating, to any pointed CW-complex (X,∗), a categorical crossed module that algebraically represents the homotopy 3-type of X. 相似文献
70.
We report the temperature dependence of electrical resistance (R) and thermopower (S) of clathrate Cs8Sn44 under high pressure up to 1.2 GPa. We observe a reversible gap widening, prominent relaxation effect of R, irreversible increase of |S| under high pressure. We also find that the power factor S2σ (σ: electrical conductivity) reaches a maximum at pressure of 0.3 GPa. Comparison of the experimental results with band structure calculations suggests that the intrinsic vacancy in the clathrate structure of Cs8Sn44 plays an important role in transport properties under high pressure. Measurements on Cs8Zn4Sn42, a clathrate which has defects other than vacancies, are compared with Cs8Sn44. The results indicate that replacing Sn by Zn has similar effect as the intrinsic vacancy on S. 相似文献