无保护流体室温燐光法测定吲哚-3-丁酸的研究

在仅以碘化钾为重原子微扰剂、亚硫酸钠为除氧剂及无任何保护性介质存在的水溶液中 ,吲哚_3_丁酸 (IBA)能发射很强的室温光 (RTP) ;详细研究了分析测定条件及有机溶剂对RTP的影响 ;在最大光波长λex/λem =281/447nm处 ,光强度与IBA浓度在2.0×10 -7～1.0×10 -5mol/L范围内呈良好的线性关系 ,检出限4.3×10-8 mol/L ;方法直接用于强化水样和土壤中IBA的测定 ,回收率96 %～104 % ,相对标准偏差2.37 %～3.97 %。     

Alkylation of 6-(3-Indolyl)indolo[2,3-b]carbazole

The methylation and allylation of 6-(3-indolyl)indolo[2,3-b]carbazole were studied, and its trimethyl and mono-, di-, and triallyl derivatives were obtained.     

Total synthesis of 3,3′:4′,3″-ter-1,2,5-thiadiazole using a synthetic utility of S4N4·SbCl5 complex

3,3′:4′,3″-Ter-1,2,5-thiadiazole, an useful oligoheterocyclic compound, has been accomplished in seven steps from 1-(5-methyl-3-isoxazolyl)ethanone or diethyl acetylenedicarboxylate using a synthetic utility of tetrasulfur tetranitride antimony pentachloride (S₄N₄·SbCl₅) complex to make a 1,2,5-thiadiazole ring.     

Interaction of (1-phenylethyl)indole-2-carbonitrile with C-nucleophiles

Methods of obtaining ketones and enamino esters have been developed on the basis of reactions of 1-(1-phenylethyl)indole-2-carbonitrile with organomagnesium and organozinc compounds. Removal of a benzyl group from the indole nitrogen atom by the Grignard reagent has been discovered. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1179–1183, August, 2006.     

3,5-diBr-PADAP作锆(Ⅳ)显色剂的分光光度法研究与应用

本文研究了在非离子表面活性剂存在下,用3,5-diBr-PADAP作锆显色剂的胶束增溶分光光度法。在pH1.0～2.0的HCl介质中,配合物吸光度最大且稳定,最大吸收值在610nm处。Zr(Ⅳ)与试剂形成1:2的配合物,摩尔吸光系数为1.10×10~5L·mol~(-1)·cm~(-1),zr(Ⅳ)量在0～30μg/25mL范围内遵守比尔定律。采用钽试剂一苯苹取分离法,适合于钽铌矿中微量锆的测定。     

Investigation of the phosphinyl analog of α-ketoglutaric acid

It was shown by³¹P and¹³C NMR spectroscopy that methyl(3-carboxy-3-oxopropyl)phosphinic acid (4-methylhydroxyphosphinyl-2-oxobutyric acid) (1) and the amide (2) of the latter exist in keto forms in non-aqueous solutions. In aqueous solutions an equilibrium between the keto,gem-diol, and enol forms has been observed. The proportions of the diol and enol forms increase as the acidity of the media increases. Silylation of acid 1 with hexamethyldisilazane gives the tris(trimethylsilyl) derivative of enol form (3) (Z- andE-isomers).Translated fromIzyestiya Akadetnii Nauk. Seriya Khimicheskaya, No. 1, pp. 125–128, January, 1994.     

The Formation of C?C Bonds with the Aid of α-Halogeno Ethers,Sulfides, and Amines

α-Halogeno ethers, sulfides, and amines are reactive compounds which can be used for the formation of new C? C bonds, either as nucleophilic or as electrophilic reagents, or by α-elimination. The use of these compounds in the synthesis of many classes of organic compounds is reviewed.     

Solid Phase Synthesis of 4H-Pyrimido[2,1-b] Benzothiazol-4-ones from Resin-Bound Cyclic Malonic Ester

The solid phase synthesis of 4H-pyrimido[2,1-6] benzothizaol-4-ones has been reported.     

Substituted pyrazine-di-N-oxides as the mediators of catalytic oxidation of organic compounds

The mechanism of oxidation of 2,5-dimethyl-, 2,3,5,6-tetramethyl-, 2,3-dimethyl-5,6-cyclohexa, and 3-phenyl-5,6-cyclohexapyrazine-di-N-oxides is studied by cyclic voltammetry, quantum chemical simulations, and ESR electrolysis. The studies are carried out on electrodes of glassy carbon and Pt in 0.1 M LiClO₄ solutions in acetonitrile. ESR spectra of radical cations of substituted pyrazine-di-N-oxides are recorded. The effects of the temperature, oxygen, and the additions of water, pyridine, and acid on the shape of cyclic voltamograms and the intensity of ESR signals of pyrazine-di-N-oxides are studied. A quantum-chemical simulation of the reaction of pyrazine-di-N-oxide radical cations with acetonitrile is carried out. The oxidation of substituted pyrazine-di-N-oxides is described by the E₁C₁E₂C₂ mechanism, which includes the stage of the formation of a complex between the di-N-oxide radical cation and acetonitrile.     

Synthesis and reactivity of thieno[2,3-<Emphasis Type="Italic">b</Emphasis>]pyridine-2,3-diamines

It has been established that the interaction of N¹-(2-hydroxyphenylmethylthieno[2,3-b]pyrid-3-yl)arylamides with hydrazine hydrate leads to thieno[2,3-b]pyridine-2,3-diamines. It was shown that the reaction of the latter with acetylacetone and acetoacetic ester occurs regioselectively at the amino group in position 3 of the thiophene ring. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1400–1408, September, 2007.