植物病毒病化学防治剂的探寻 Ⅺ.三羧酸乙基DHT酯的合成及抗病毒活性

合成了１０个未见文献报道的三羧酸乙基ＤＨＴ的酯类化合物,新化合物的水溶性、脂溶性均较ＤＨＴ好,并有一定抗病毒活性,其中化合物２的活性最高,对ＴＭＶ的抑制百分率达到９０％,优于对比的ＤＨＴ     

象山港水交换能力研究

为深入研究象山港水交换现状,并为港区生态模型等后续研究提供数据,运用Delft3D软件运行了一个已校准的水动力模型,用模型输出的水位和流速数据分析象山港纳潮量和水流特征,并用模型输出的盐度和示踪剂数据求得基于箱式模型的水更新时间和基于Delft3D示踪剂模型的水更新时间.结果表明:港区平均纳潮量为1.32×109 m3,大潮纳潮量为1.82×109 m3,小潮纳潮量为0.82×109 m3.箱式模型得出滞留系数为0.9,水更新时间约13~21 d.Delft3D示踪剂对流-扩散模型得出水更新时间约4个月,置换35%的水体需5d,置换65%的水体需125d,置换90%的水体需305 d;示踪剂垂直混合充分,水平差异显著,口门区示踪剂平均滞留时间少于10 d,港中区约170d,港顶区超过250d.因此象山港是口门水交换强烈,但中顶部水交换很弱的港湾,其排污口应设在西泽码头以东,港顶应养殖大型海藻,并控制鱼虾养殖规模以减轻富营养化.     

在微通道反应器中合成2-乙基-2-苯基-3-溴-3-丁烯醛

在微通道反应器中进行了1-苯基-2-乙基-2,3-丁二烯醇和溴合成2-乙基-2-苯基-3-溴-3-丁烯醛的反应．测定了不同流速和反应时间对反应产率的影响．反应速度比常规的玻璃容器中有明显提高,并具有反应物的用量少,对环境的污染轻等优点．实验结果表明,微通道反应器在有机合成领域有广泛的应用前景．     

甲烷二氧化碳氧化重整制合成气反应中Al2O3对Ni-Al2O3/SiO2催化剂性能的影响

在流化床中评价了用于甲烷二氧化碳氧化重整制合成气反应的Ni-Al2O3/SiO2催化剂体系(NixAlSi,x代表Al的质量分数,Ni的质量分数为4%)的催化性能.利用XRD,CO2(O2)-TPD,积炭量测定等手段对催化剂进行了表征.结果表明,Al2O3的添加促进了Ni金属的分散;增强了对CO2和O2的吸附能力,使催化剂的抗积炭性能得到很大的提高,延缓了催化剂的失活.     

La掺杂对Bi4Ti3O12薄膜铁电性能的影响

利用Sol-Gel法在Pt/Ti/SiO₂/Si衬底上制备出Bi₄Ti₃O₁₂和Bi_3.25La_0.75Ti₃O₁₂薄膜，研究了La掺杂对Bi₄Ti₃O₁₂薄膜的晶体结构、铁电性能和疲劳特性的影响，发现La掺杂没有改变Bi₄Ti₃O₁₂薄膜的基本晶体结构，并且提高了Bi₄Ti₃O₁₂铁电薄膜的剩余极化值和抗疲劳性能，对La掺杂改善Bi₄Ti₃O₁₂铁电薄膜性能的机理进行了讨论. 关键词： 铁电性能 4Ti₃O₁₂薄膜')" href="#">Bi₄Ti₃O₁₂薄膜 3.25La_0.75Ti₃O₁₂薄膜')" href="#">Bi_3.25La_0.75Ti₃O₁₂薄膜 sol-gel法 La掺杂     

Acoustooptic extension of the frequency tunability of CW CO2 lasers: New FIR lasers emissions from CH3OH and13CH3OH

We have increased the frequency tunability of our CW waveguide CO₂ lasers by means of an acoustooptic amplitude modulator, operating at the fixed frequency of 90 MHz. The up-shifted, or down-shifted, laser optical sideband can be generated independently by adjusting the orientation of the modulator. The efficiency is larger than 50%. The frequency tunability of the CO₂ laser around each laser line is thus increased by 180 MHz. To demonstrate the possibilities of this method, a source composed of the above modulator and of a CW, 300 MHz tunable waveguide CO₂ laser has been used for the search of new large offset FIR laser lines from optically pumped CH₃OH and¹³CH₃OH molecules. As a result 15 and 10 new large offset laser lines were discovered respectively. New assignments of some laser lines are also proposed. We have also measured the Stark effect, the offset, and the polarization of other already known lines. In particular a Stark effect frequency tuning of about 1 GHz is demonstrated for a laser line at 208.399 m.     

Optimizing in the class of Fuller modified limited information maximum likelihood estimators

A general class of Fuller modified maximum likelihood estimators are considered. It is shown that this class possesses finite moments. Asymptotic bias and asymptotic mean squared error are derived using small-σ expansions. A simulation study is carried out to compare different estimators in this class with standard estimators.     

隐式曲面与参数曲面的G3过渡

通过几何过渡方法，结合重新标度连续概念，利用隐式曲面与参数曲面的各自等距曲面的交线，构成隐式曲面与参数曲面问的过渡面．用曲面的隐式与隐式、参数与参数形式，证明了所作的过渡面与给出的隐式曲面与参数曲面在连接线处是G^3连接的。     

Iterated monoidal categories

We develop a notion of an n-fold monoidal category and show that it corresponds in a precise way to the notion of an n-fold loop space. Specifically, the group completion of the nerve of such a category is an n-fold loop space, and free n-fold monoidal categories give rise to a finite simplicial operad of the same homotopy type as the classical little cubes operad used to parametrize the higher H-space structure of an n-fold loop space. We also show directly that this operad has the same homotopy type as the n-th Smith filtration of the Barratt-Eccles operad and the n-th filtration of Berger's complete graph operad. Moreover, this operad contains an equivalent preoperad which gives rise to Milgram's small model for when n=2 and is very closely related to Milgram's model of for n>2.