5 μm thick 3C-SiC layers grown on Ge-modified Si(100) substrates

The effect of the germanium coverage prior to the epitaxial growth of 5 μm thick 3C-SiC on Si(100) substrates were evaluated with Atomic Force Microscopy and μ-Raman spectroscopy. The 3C-SiC layers were grown by atmospheric pressure chemical vapor deposition via a special procedure leading to layers with compressive instead of tensile stress. The Ge amount was varied from 0 up to 2 ML. The obtained results showed that the residual stress inside the layers is shifted in the compressive direction; the crystalline quality is improved with the Ge introduction but on the account of the surface roughness. These results open the route for the use of Ge-modified Si(100) as a potential substrate in order to improve the heteroepitaxial growth of 3C-SiC on silicon substrates.     

Ground state rotational spectrum of nitrogen trifluoride: The K = 3 splittings of NF3 and NF3

The ground state rotational spectrum of the ¹⁴NF₃ and ¹⁵NF₃ isotopic species of nitrogen fluoride has been observed in the ∼450-810 GHz frequency range. This investigation allowed us to improve the rotational parameters for both isotopologues. In particular, for the first time the K = 3 line splitting parameter and the sextic centrifugal distortion constants have been determined for ¹⁵NF₃.     

Relation between Hall-magnetohydrodynamics and the kinetic Alfvén wave

Effects of a finite ion temperature on the Hall magnetohydrodynamics (MHD), which breaks down for a finite ion temperature, are clarified in terms of a rigorous three-field kinetic dispersion relation. The MHD mode equation becomes anisotropic with respect to the ion pressure because of the double adiabaticity in ion dynamics.     

三价镧系离子掺杂的Cd3Al2 Ge3O12的长余辉发光

系统地研究了三价镧系离子在Cd3Al2Ge3O12基质中的长余辉发光。总结了余辉性能与激活离子电负性的关系。研究发现该体系中易失电子的激活离子产生的余辉效果较好。在254nm紫外光激发下,基质和所有镧系离子(Pm除外)掺杂的样品都有发光和余辉。按照发光和余辉性质的不同可以将激活离子分为三类：Pr^3 、Tb^3 和Dy^3 等是有特征余辉发光的离子;Eu^3 和Sm^3 等是有特征发射,但没有特征余辉发光的离子;Ce^4 、La^3 、Nd^3 以及其他是没有特征发光的镧系离子。长余辉的产生是由缺陷引起的。由于Cd^2 离子在高温下容易挥发,基质中存在大量的Cd^2 离子空位,这种空位可以作为俘获电子的陷阱。同时为了补偿Cd^2 所产生的正电荷,在Cd^2 离子空位周围会有相应的负离子空位产生,比如氧离子空位。这种补偿作用的存在使得基质本身的缺陷种类和数量十分丰富,使得该体系的余辉性能比较优越。     

Dy3+/Tm3+共掺杂钒磷酸钇的共沉淀法合成及光谱性质

以Y2O3、Dy2O3、Tm2O3、V2O5、(NH4)2GPO4为原料,采用共沉淀化学法合成了体色纯白的Dy^3 、Tm^3 共掺杂YP1-xVxO4荧光粉。对合成荧光粉的V^5 ／p^5 、Dy^3 ／Tm^3 摩尔比等条件进行了研究。利用SEM、变温紫外激光激发下的发射光谱及紫外激发下的发射光谱,对所合成的粉体的表面形貌及发光性能进行了表征。YP1-xVxO4：Dy^3 ,Tm^3 荧光粉在325nm紫外激光激发下,低温时存在基质VO4^3-的蓝色宽带发射,随着温度升高,VO4^3 吸收的激发能量更有效地传递给Dy^3 、Tm^3 ,使其发光逐渐增强;在254nm的紫外光激发下,YP1-xVxO4：Dy^3 ,Tm^3 荧光粉发白光,是一种潜在的二基色高压汞灯用荧光粉。     

Shape‐ and Trap‐Controlled Nanocrystals for Giant‐Performance Improvement of All‐Inorganic Perovskite Photodetectors

In the last few years, all‐inorganic perovskite CsPbBr₃ nanocrystals (NCs) have attracted tremendous attention for its high carrier mobility, long carrier diffusion length, excellent visible light absorption, and more importantly superior air stability. In fact, photodetectors (PDs) are designed and fabricated using the CsPbBr₃ NCs with very high performance. Herein, by optimizing the NC shape, size, and surface passivation, the CsPbBr₃ PDs are developed with an even higher performance. It is found that the PDs based on CsPbBr₃ nanoribbons show the best photoresponse among all common NC structures synthesized. Moreover, it is found that 6,6‐phenyl‐C61‐butyric acid ethyl ester can be used to passivate defects on the CsPbBr₃ nanoribbon surface and shows the charge transfer. As a result, the device displays superior photoresponsivity (R = 18.4 A W⁻¹), excellent signal‐to‐noise ratio, as high as 10⁴, and a very sharp rise/decay time (8.7/3.5 ms). The method demonstrated may offer an attractive strategy to improve sensitivity for all‐inorganic perovskite PDs in general.     

小鼠卵母细胞染色体三维双光子荧光图像的轴向衰减

双光子荧光显微镜作为一种高分辨光学仪器,已经被广泛应用于生物样品的非侵入式三维光学成像中。相比共聚焦显微镜,双光子荧光显微镜拥有更深的探测深度。然而,即便如此,在对较厚的生物样品进行非侵入式光学三维成像时,样品的成像质量也往往会随着探测深度的增加而下降。在临床和生物学领域对研究母性遗传起重要作用的小鼠卵母细胞拥有较大的直径(80～100 μm),吸收和散射效应较为明显。本文研究小鼠卵母细胞染色体的三维双光子荧光图像随探测深度增加图像质量的衰减程度。通过对所得图像进行轴向衰减矫正,利用体积作为参数,将矫正前后小鼠卵母细胞内染色体三维双光子荧光图像进行对比。结果表明,由于吸收和散射效应,卵母细胞存在较严重的光学轴向衰减问题,因此,对用双光子荧光三维成像手段获得的小鼠卵母细胞图像进行衰减矫正是有必要的。这为进一步精确定量的研究卵母细胞内染色体的三维构像打下良好的基础。     

A One-Pot Entry to a Novel 3-H-benzo[d]pyrazolo[1,5-b]isothiazole Ring System

Summary The phosphorus ylide obtained from the reaction between 2-aminobenzo[d]isothiazol-3-one and dimethyl acetylenedicarboxylate in the presence of triphenylphosphine undergoes a smooth intramolecular Wittig-type reaction to produce, in a one-pot reaction, 3-H-benzo[d]pyrazolo[1,5-b]isothiazole-2,3a-dicarboxylic acid dimethyl ester, a novel functionalized heterocyclic compound.     

荧光光谱法辨别丙二醇和二甘醇

以齐药二厂的假药事件为背景,对1,2-丙二醇、1,3-丙二醇和二甘醇的吸收光谱和荧光光谱进行了测量,实验结果证明光谱法不失为一种快捷有效的区分手段.在紫外吸收光谱中,可以通过最大吸光度的差异区分二甘醇和丙二醇;在一定紫外波长激励下,三种醇的荧光光谱特性均存在差异,以此可以对三种醇作出有效区分;在230nm激发下,将二甘醇和两种丙二醇分别混合,混合溶液的相对荧光强度均与两种丙二醇体积比呈线性反比关系,这在一定程度上证明了二甘醇的荧光量子效率大于两种丙二醇.