首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   152380篇
  免费   10716篇
  国内免费   22141篇
化学   125426篇
晶体学   3074篇
力学   3176篇
综合类   1353篇
数学   17800篇
物理学   34408篇
  2024年   292篇
  2023年   1704篇
  2022年   3754篇
  2021年   3637篇
  2020年   4141篇
  2019年   4878篇
  2018年   3542篇
  2017年   5404篇
  2016年   5006篇
  2015年   4428篇
  2014年   5968篇
  2013年   11866篇
  2012年   9831篇
  2011年   9064篇
  2010年   7643篇
  2009年   9618篇
  2008年   9902篇
  2007年   10234篇
  2006年   9257篇
  2005年   8022篇
  2004年   7518篇
  2003年   6206篇
  2002年   7125篇
  2001年   4593篇
  2000年   4859篇
  1999年   4143篇
  1998年   3733篇
  1997年   2675篇
  1996年   2279篇
  1995年   2118篇
  1994年   1851篇
  1993年   1542篇
  1992年   1432篇
  1991年   1029篇
  1990年   791篇
  1989年   749篇
  1988年   584篇
  1987年   438篇
  1986年   378篇
  1985年   376篇
  1984年   350篇
  1983年   204篇
  1982年   287篇
  1981年   294篇
  1980年   279篇
  1979年   276篇
  1978年   234篇
  1977年   182篇
  1976年   146篇
  1973年   107篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
The object of the paper is to study the absolute matrix summability problem of Fourier series, conjugate series and some associated series under a new set of conditions on matrix methods, generalising many known results in the literature.  相似文献   
992.
Spin-flip (paramagnetic) scattering and neutron depolarization studies were performed on Ce2Fe17 in its paramagnetic phase on the Dhruva neutron polarization analysis spectrometer. The absence of normalQ dependence of the scattered spin flip intensity shows that Ce2Fe17 is not a normal paramagnetic and there exist superparamagnetic clusters of sufficiently large dimensions (~100Å). The observed neutron depolarization gives an indication of the dynamics of these Ce2Fe17 superparamagnetic clusters.  相似文献   
993.
New concepts for the study of incompressible plane or axisymmetric flows are analysed by the stream tube method. Flows without eddies and pure vortex flows are considered in a transformed domain where the mapped streamlines are rectilinear or circular. The transformation between the physical domain and the computational domain is an unknown of the problem. In order to solve the non-linear set of relevant equations, we present a new algorithm based on a trust region technique which is effective for non-convex optimization problems. Experimental results show that the new algorithm is more robust compared to the Newton-Raphson method.  相似文献   
994.
本文用ab initio计算方法,采用STO-3G基组,对二硝基卤代甲烷CH_2(NO_2)_3(1),CF_2(NO_2)_2(2);CCl_2(NO_2)_2(3)等分子作了单点计算,研究其旋转势能.全构型优化研究了五个具有对称性构型的结构和稳定性,并作了理论分析和探讨.  相似文献   
995.
In this paper we deal with the following particular case of a weaker conjecture by B. Y. Chen: Are there 2-type Willmore surfaces in E 3? In particular we prove that the above question has a negative answer when the surface is the image under stereographic projection of a minimal surface in S 3.  相似文献   
996.
Matrix-Investigations on Monomeric Copper(I) Chloride and its Complexes with N2 and PN Ligands. IR Spectroscopic Results and ab-initio Calculation In solid argon the reaction of monomeric CuCl with N2 yields ClCuN2. On the basis of two absorptions in the ir-spectrum and their corresponding isotopic shifts (14/15N) and with the help of a normal coordinate analysis, linearity of the molecule has been deduced. These results are confirmed by large scale ab-initio Calculations (CPF, MP2). Reaction of monomeric CuCl with molecular PN under matrix condition is shown to give rise to new absorptions in the IR spectrum which arev assigned to a linear molecule ClCuNP.  相似文献   
997.
The utility of fluoride salts as potential base in a va-riety of synthetic reactions has been recognized in re-cent years.1 However, low solubility of fluoride salts in ordinary solvents hampers their wide applications in organic synthesis. On the other hand, there has been increasing use of inorganic solid supports as catalysts for many years2 resulting in higher selectivity, milder reaction conditions and easier work-up. Especially po-tassium fluoride-coated alumina (KF-alumina) has been a …  相似文献   
998.
X-ray photoelectron spectroscopy (XPS) was adopted for the analytical characterization of composite titanium dioxide–poly(vinylidenefluoride) (TiO2–PVDF) films developed for applications in the photocatalytic degradation of pollutants.

The composites were deposited on glass substrates by casting or spin coating from TiO2–PVDF suspensions in dimethylformamide (DMF). XPS data on the TiO2–PVDF surface composition were used to optimize preparation conditions (composition of the TiO2/PVDF suspension, deposition technique) in terms of titanium dioxide surface amount and film stability.

The use of spin-coating deposition and the increase of TiO2 amount in the DMF suspensions were found to improve the titanium surface content, although high TiO2/PVDF ratios led to film instability. PVDF–TiO2 films were also used in preliminary photocatalytic degradation tests on isoproturon, a phenylurea herbicide, under solar UV irradiation; the results were compared to direct photolysis to evaluate the catalytic efficiency of immobilized TiO2 and the role played by the PVDF film during the degradation process.  相似文献   

999.
Synthesis of ZnAl2O4/α-Al2O3 complex substrates and growth of GaN films   总被引:1,自引:0,他引:1  
With the solid phase reaction between pulsed-laser-deposited (PLD) ZnOfilm and α-Al2O3 substrate, ZnAl2O4/α-Al2O3 complex substrates were synthesized. X-ray diffraction (XRD) spectra show that as the reaction proceeds, ZnAl2O4 changes from the initial (111)-oriented single crystal to poly-crystal, and then to inadequate (111) orientation. Corresponding scanning electron microscope (SEM)images indicate that the surface morphology of ZnAl2O4 transforms from uniform islands to stick structures, and then to bulgy-line structures. In addition, XRDspectra present that ZnAl2O4 prepared at low temperature is unstable at the environment of higher temperature. On the as-obtained ZnAl2O4/α-Al2O3 substrates, GaN films were grown without any nitride buffer using light-radiation heating low-pressure MOCVD (LRH-LP-MOCVD). XRD spectra indicate that GaN film on this kind of complex substrate changes from c-axis single crystal to poly-crystal as ZnAl2O4 layer is thickened. For the single crystal GaN, its full width at half maximum (FWHM) of X-ray rocking curve is 0.4°. Results indicate that islands on thin ZnAl2O4 layer can promote nucleation at initial stage of GaN growth, which leadsto the (0001)-oriented GaN film.  相似文献   
1000.
Golub et al. (2001, BIT, 41, 71–85) gave a generalizedsuccessive over-relaxation method for the augmented systems.In this paper, the connection between the SOR-like method andthe preconditioned conjugate gradient (PCG) method for the augmentedsystems is investigated. It is shown that the PCG method isat least as accurate (fast) as the SOR-like method. Numericalexamples demonstrate that the PCG method is much faster thanthe SOR-like method.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号