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121.
122.
光学仪器胶粘剂应用现状及进展 总被引:4,自引:0,他引:4
本文是在对国内光学零件加工及光学仪器产品胶粘剂的应用现状与研究动态的调研基础上,结合作者的工作,综合介绍了光学零件加工过程中工艺用粘接材料与工艺材料用树脂结合剂;光学零件、光学分划元件、光学偏振元件、光学塑料元件等的胶合用光学胶;光学仪器产品结构用结构胶及非结构胶;光学仪器产品及部件用密封胶等的应用现状及其进展概况 相似文献
123.
M. El-borai M. F. Abdel-megeed 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2):165-173
Abstract The mass spectral fragmentation of thiophenotropone, thiophenotropilidene derivatives and their iron and chromium tricarbonyl complexes are fully reported and discussed. The fragmentation patterns of the complexes are characterised by successive loss of three carbonyl groups. In general, the resulting ions after elimination of the metal behave in the same manner as the organic ligand. The iron complexes behave differently from their corresponding chromium complexes. The thiopheno[b]tropilidene iron tricarbonyl complex and its isomer thiopheno[c]tropilidene iron tricarbonyl complex could not be differentiated by mass spectrometry, such differentiation was achieved by proton magnetic resonance. 相似文献
124.
A new infrared-spectroscopic method to characterize acid sites of zeolites using small and weakly basic molecules such as diatomic and monoatomic molecules is reviewed. It has been revealed that N2 is an effective probe molecule to characterize both Brønsted acidity and Lewis acidity of H-form zeolites. The characteristics of the N 2 probe are discussed in detail in comparison with the CO probe. O2 and rare gases have also been applied to monitor the strong acid sites in the H-form zeolites. Further, the studies of the adsorption of water on H-form zeolites are shortly reviewed: a recent IR study of the H2
18O adsorption on H-ZSM-5 has given direct experimental evidence that the main feature of the observed IR bands is due to the hydrogen-bonded adsorption of water on the Brønsted acid sites. 相似文献
125.
以2-氰基-3-(4-(2-氯-3-甲基-1-丁酰氧基)-苯基丙烯酸(A)为质子给体,N-(4-吡啶基亚甲基)-4-烷氧基苯胺(nSSZ)为质子受体,合成了一系列新的氢键复和物,经红外光谱证实了分子间氢键的存在,通过DSC,偏光方法及X射线衍射方法对其液晶行为进行研究,结果表明复合物呈现近晶相行为。 相似文献
126.
采用水热方法,用2种联苯四羧酸配体(2,4-H4bpta和3,5-H4bpta)和4,4''-联吡啶(4,4''-bipy)或2,2''-联吡啶(2,2''-bipy)分别与MnCl2·4H2O和CuCl2·H2O反应,合成了一个具有一维双螺旋链结构的配位聚合物[Mn(μ3-2,4-H2bpta)(4,4''-bipy)2]n(1)和一个二维层状配位聚合物{[Cu(μ4-3,5-bpta)0.5(2,2''-bipy)(H2O)]·H2O}n(2),并对其结构和磁性质进行了研究。结构分析结果表明2个配合物分别属于单斜晶系,P21/c和C2/c空间群。配合物1具有一维双螺旋链结构,而且这些一维链通过O-H…N氢键作用进一步形成了二维超分子网络。而配合物2具有二维层状结构。研究表明,配合物1中相邻锰离子间存在铁磁相互作用。 相似文献
127.
The first isolation of a phosphonium amide, (Ph3PEt)+(NPh2)−, obtained via the deprotonation of a secondary amine (diphenylamine) with a phosphorus ylide (triphenylphosphonium ethylide), is described. An X-ray crystal structure provides the first observation of an essentially ion-separated Ph2N− anion in the solid state, though weak association with Ph3PEt+ cations take plac through C---H…N hydrogen bonding. Cryoscopic and NMR spectroscopic data suggest that this association is not maintained in benzene solution. 相似文献
128.
High Performance Nonvolatile Transistor Memories Utilizing Functional Polyimide‐Based Supramolecular Electrets 下载免费PDF全文
Wei‐Yao Tung Meng‐Hsien Li Dr. Hung‐Chin Wu Hsin‐Yu Liu Yun‐Ting Hsieh Prof. Wen‐Chang Chen 《化学:亚洲杂志》2016,11(10):1631-1640
We report pentacene‐based organic field‐effect transistor memory devices utilizing supramolecular electrets, consisting of a polyimide, PI(6FOH‐ODPA), containing hydroxyl groups for hydrogen bonding with amine functionalized aromatic rings (AM) of 1‐aniline (AM1), 2‐naphthylamine (AM2), 2‐aminoanthracene (AM3), and 1‐aminopyrene (AM4). The effect of the phenyl ring size and composition of AM1–AM4 on the hole‐trapping capability of the fabricated devices was investigated systematically. Under an operating voltage under ±40 V, the prepared devices using the electrets of 100 % AM1–AM4/PI ratios exhibited a memory window of 0, 8.59, 25.97, and 29.95 V, respectively, suggesting that the hole‐trapping capability increased with enhancing phenyl ring size. The memory window was enhanced as the amount of AM in PI increased. Furthermore, the devices showed a long charge‐retention time of 104 s with an ON/OFF current ratio of around 103–104 and multiple switching stability over 100 cycles. This study demonstrated that the electrical characteristics of the OFET memory devices could be manipulated through the chemical compositions of the supramolecular electrets. 相似文献
129.
N. Lee D. Thirumalai 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,12(4):599-605
The effect of electrostatic interactions on the stretching of DNA is investigated using a simple worm like chain model. In
the limit of small force there are large conformational fluctuations which are treated using a self-consistent variational
approach. For small values of the external force f, we find the extension scales as where is the Debye screening length. In the limit of large force the electrostatic effects can be accounted for within the semiflexible
chain model of DNA by assuming that only small excursions from rod-like conformations are possible. In this regime the extension
approaches the contour length as where f is the magnitude of the external force. The theory is used to analyze experiments that have measured the extension of double-stranded
DNA subject to tension at various salt concentrations. The theory reproduces nearly quantitatively the elastic response of
DNA at small and large values of f and for all concentration of the monovalent counterions. The limitations of the theory are also pointed out.
Received 13 October 1998 and Received in final form 9 June 1999 相似文献
130.
在溶剂热条件下,合成了3个基于V型配体的Zn(Ⅱ)金属有机骨架:{[Zn2(BIDPS)2(OBA)2]·DMA}n(1)、{[Zn (BIDPT)(PA)]·DMF}n(2)和{[Zn (BIDPS)(PA)(H2O)2]·2H2O}n(3)(BIDPS=4,4''-二(1-咪唑基)苯砜,H2OBA=4,4''-二苯醚二甲酸,H2PA=帕莫酸,BIDPT=4,4''-二(1-咪唑基)苯硫醚)。利用X射线单晶衍射、红外光谱、元素分析、热重分析、X射线粉末衍射对其结构进行了表征。配合物1具有二重穿插的三维cds拓扑网络结构。配合物2为二维(4,4)层状结构,层与层之间通过互锁形成2D→3D的三维金属有机骨架。配合物3具有一维链状结构,一维链通过分子内和分子间氢键连接,形成三维超分子结构。荧光研究表明,配合物1~3可以在pH=4~10的水溶液中稳定存在,且在水中具有较强的发光性能,可作为检测2,4,6-三硝基苯酚和Fe3+的发光传感器,具有较高的灵敏度和选择性。 相似文献