静态顶空/气相色谱-质谱法同时测定化妆品中22种有毒挥发性有机溶剂残留

以2015版《化妆品安全技术规范》中规定的常见禁用及限用有毒挥发性有机溶剂为研究对象,建立了静态顶空/气相色谱-质谱法(SHS/GC-MS)同时测定化妆品中22种有毒挥发性有机溶剂(VOC)(二氯甲烷、顺式-1,2-二氯乙烯、反式-1,2-二氯乙烯、2-氯-1,3-丁二烯、三氯甲烷、1,2-二氯乙烷、苯、四氯化碳、三氯乙烯、甲苯、四氯乙烯、氯苯、乙苯、三溴甲烷、间二甲苯、对二甲苯、苯乙烯、邻二甲苯、异丙苯、1,4-二氯苯、1,2-二氯苯、六氯丁二烯)残留的检测方法。试样在80℃下30 min静态顶空,经DB-1柱分离后,采用选择离子监测模式(SIM)进行定性定量分析。优化了顶空、色谱和质谱参数,结果表明:22种VOC在0.5~50 ng/m L浓度范围内均呈良好的线性关系,相关系数均大于0.99,在1.0,2.0,5.0 ng/m L 3个浓度加标水平下的平均回收率为80.3%~102.7%,相对标准偏差(RSD,n=6)为6.4%~9.9%,检出限为0.2~5.0 ng/g。结果表明,该方法简便、灵敏、准确,具有良好的重现性和稳定性,适合于化妆品中22种VOC残留的筛查和确证检测。     

圆偏振光在手性聚合物合成与结构调控中的应用

手性是自然界中普遍存在的有趣现象之一,在生命体中手性大分子特有的不对称结构在维持生命过程、新陈代谢和进化等面均起着决定性作用.受此启发,合成具有新型结构的光学活性聚合物,研究其独特的物理化学性质和功能已成为当今高分子领域研究的热点.左旋和右旋的圆偏振光已被广泛应用于氨基酸衍生物的不对称光合成、光分解和去消旋化反应,以及诱导含有偶氮苯或三苯胺等特定功能基团的超分子组装体或无机纳米粒子形成稳定螺旋结构.本文详细地介绍了圆偏振光辐照在手性聚合物合成与螺旋结构调控中的应用,初步揭示了圆偏振光的作用机制以及优势,归纳总结了已取得的研究进展,并对圆偏振光在手性聚合物合成与结构调控中的应用及发展进行了简单的评述和展望.     

光纤陀螺随机游走系数的分析研究

分析了产生随机游走误差的机理,分别采用有关标准和Allan方差进行了随机游走系数的分析和计算。结果表明:随机游走系数是衡量光纤陀螺噪声水平的重要指标,其值的大小体现了陀螺的极限精度。采用Allan方法表述光纤陀螺的静态指标,物理概念清晰,方法简便。     

四元数旋转算子和螺旋算子

1.引言由于四元数具有其它定位参数和变换算法的综合优点和综合功能,因而在刚体和多刚体力学中的应用越来越广。本文正是利用了四元数表达的多样性和算法的多功能性,首先利用两个单位矢量的四元数乘积导出了四元数旋转算子,并通过其矩阵形式串通了其它参数形式的各种变换算子。     

添加剂与铝合金的相互作用研究 Ⅰ.静态反应膜及油润滑下的摩擦学性能

静态下分别于２５℃，９０℃及１８０℃下进行硫化异丁烯（ＳＯ）、亚磷酸二正丁酯（ＤＢＰ）、ＳＯ＋ＤＢＰ的混合物（质量比２０∶１）、二烷基二硫代磷酸锌（ＺＤＤＰ）及十二酸（ＬＡ）５种添加剂均以质量分数为２％的比例添加到液体石蜡（ＬＰ）中与铝合金进行油浸试验．用动－静摩擦系数精密测定仪评价了在铝合金表面上所形成的静态反应膜的摩擦磨损行为，并考察了上述添加剂在ＬＰ中对铝合金－钢摩擦副的润滑作用．结果表明：静态反应膜的摩擦磨损行为与添加剂的化学活性密切相关，其中ＤＢＰ最易与铝合金发生反应，故其反应膜具有最低的摩擦系数和最长的耐磨寿命；ＺＤＤＰ在１８０℃下的静态反应膜具有较低的摩擦系数和较长的耐磨寿命；ＳＯ、ＳＯ与ＤＢＰ的混合物及ＬＡ的静态反应膜则不具有减摩抗磨性能，预示这些添加剂在ＬＰ中不与铝合金发生较强的化学作用．含上述添加剂的ＬＰ润滑下的摩擦磨损试验显示，ＤＢＰ与ＺＤＤＰ具有较好的摩擦学性能．这表明添加剂在铝合金表面静态反应膜的摩擦磨损试验结果与其在常规润滑下的具有较好的相关性．     

Interaction between a screw dislocation and an elastic elliptical inhomogeneity with interfacial cracks

The elastic interaction between a screw dislocation and an elliptical inhomogeneity with interfacial cracks is studied. The screw dislocation may be located outside or inside the inhomogeneity. An efficient complex variable method for the complex multiply connected region is developed, and the general solutions to the problem are derived. As illustrative examples, solutions in explicit series form for complex potentials are presented in the case of one or two interfacial cracks. Image forces on the dislocation are calculated by using the Peach-Koehler formula. The influence of crack geometries and material properties on the image forces is evaluated and discussed. It is shown that the interfacial crack has a significant effect on the equilibrium position of the dislocation near an elliptical-arc interface. The main results indicate, when the length of the crack goes up to a critical value, the presence of the interfacial crack can change the interaction mechanism between a screw dislocation and an elliptical inclusion. The present solutions can include a number of previously known results as special cases.The project supported by the National Natural Science Foundation of China(10272009 and 10472030) and the Natural Science Foundation of Hunan Province(02JJY2014)     

静态分岔点的数值计算

本文讨论了古典分岔理论与分岔的奇异性理论的联系与区别，并针对分岔点的计算方法与所依赖的理论体系的关系进行了简单综述。     

螺旋槽干气密封微尺度流动场的近似计算及其参数优化

应用PH线性化方法、迭代法,近似求解了螺旋槽内稳态微尺度流动场的非线性雷诺方程,求得了气体动压和速度分布的解析解。继而利用多目标优化方法构建了气膜刚度与泄漏量之比的协调函数,并对该目标函数进行了近似求解,获得了最佳的螺旋槽几何参数值。     

CAE技术在井架设计中的应用

应用GAE技术，针对ZJ30／1700CZ钻机井架分别进行了静态分析及在自然状态和有钩载情况下的模态分析，为合理设计钻机井架结构提供了理论依据。通过分析计算，可以看出：所设计的井架的静态强度满足要求；经动力再设计后的井架固有频率与钻机的设计工作转速相差较大，达到工程要求，表明修改后的井架设计方案合理。     

VISCOPLASTIC SOLUTION TO FIELD AT STEADILY PROPAGATING CRACK TIP IN LINEAR- HARDENING MATERIALS

An elastic-viscoplastic constitutive model was adopted to analyze asymptotically the tip-field of moving crack in linear-hardening materials under plane strain condition. Under the assumption that the artificial viscosity coefficient was in inverse proportion to power law of the rate of effective plastic strain, it is obtained that stress and strain both possess power law singularity and the singularity exponent is uniquely determined by the power law exponent of the rate of effective plastic strain. Variations of zoning structure according to each material parameter were discussed by means of numerical computation for the tip-field of mode Ⅱ dynamic propagating crack, which show that the structure of crack tip field is dominated by hardening coefficient rather than viscosity coefficient. The secondary plastic zone can be ignored for weak hardening materials while the secondary plastic zone and the secondary elastic zone both have important influence on crack tip field for strong hardening materials. The dynamic solution approaches to the corresponding quasi-static solution when the crack moving speed goes to zero, and further approaches to the HR (Hui-Riedel) solution when the hardening coefficient is equal to zero.