甲基百里(香)酚蓝新负载树脂的特 性及应用

本文以金属指示剂甲基百里(香)酚蓝作为鳌合剂制得具有相应鳌合基团的负载树脂.研究了该树脂的某些分析特性及其在富集天然水中微量铜、钻、镍、锌中的应用.     

Fabrication and Characterization of Ni Thin Films Using Direct-Current Magnetron Sputtering

Ni films are deposited by using ultra high vacuum dc magnetron sputtering onto silicon substrates at room temperature, and the high-quality and high-density films are prepared. The parameters, such as thickness, density and surface roughness, are obtained by using small-angle x-ray diffraction (XRD) analyses with the Marquardt gradient-expansion algorithm. The deposition rate is calculated and the Ni single layer can be fabricated precisely. Based on the fitting results, we can find that the surface roughness of the Ni films is about 0.7nm, the densities of Ni films are around 97% and the deposition rate is 0.26nm/s. The roughness of the surface is also characterized by using an atomic force microscope (AFM). The changing trend of the surface roughness in the simulation of XRD is in good agreement with the AFM measurement.     

等温平台石墨炉原子吸收光谱法测定高纯镍中痕量杂质锑

利用石墨炉原子吸收法，在等温平台条件下直接测定高纯镍中的痕量杂质锑，对石墨炉加热程序中的干燥时间、灰化温度及原子化温度进行了优化，同时考察了介质酸度的影响。试验表明，基体镍对锑的测定有显著的影响，为此进行了标准系列基体匹配。该法的特征质量为6．6pg；相对标准偏差为6．5％；加标回收率为100％-103％。     

非晶态镍钨合金电镀工艺

非晶态镍钨合金由于具有长程无序，短程有序，无晶界、无位错，而具有极为优异的化学、物理和机械性能。非晶态镍钨合金镀层的结构致密，硬度高，耐热性好，尤其在高温下耐磨损、抗氧化，更能显示出其优良的自润滑和耐蚀性能。     

A Novel and Efficient Catalytic System for Aerobic Oxidative Coupling of 2-Naphthol Derivatives

The paper reported a novel and efficient aerobic oxidative coupling reaction of 2-naphthol derivatives catalyzed by CuCu (Ⅰ or Ⅱ)N-alkylimidazole complexes in excellent yields. The crystal structure of CuCu(Ⅱ)N-methylimidazole complex to be determined by X-Ray.     

Triterpenoid Constituents of Huperzia miyoshiana

Thirteen triterpenoids, including three new ones, miyoshianois A (1), B (2) and C (3), were isolated from Huperzia miyoshiana. The structures of these new compounds were established as 3-O-dihydroferuloyltohogenol (1), 16-oxo-3β,21β-dihydrox-y-serrat-14-en-24-ferulate (2) and 16-oxo-3a, 21β-dihydroxy-serrat-14-en-24-ferulate (3), respectively, on the basis of their spectroscopic analysis.     

Defect Structures in 4H-SiC Irradiated with Highly-energetic ^20Ne^4＋ and ^120Xe^26＋ Ions

The study of damage evolution in silicon carbide bombarded with energetic helium ions is important for the use of this material in future fusion reactors. Heavier inert gas atoms like Ne and Xe have similar behavior of diffusion and clustering with helium, and the comparison of damage accumulation behavior between energetic helium and heavier inert gas ions can reveal important aspects of underlying mechanisms. As an extension of our     

Time-Resolved Femtosecond Degenerate Four-Wave Mixing in LiNbO3：Fe,Mg Crystal

Forward degenerate four-wave mixing （DFWM） processes are investigated with a femtosecond pulsed laser in lithium niobate crystal doubly-doped with magnesium and iron （LiNbO3：Fe, Mg）. The pulse energy dependence reveals a pure third-order nonlinear response, and the third-order nonlinear susceptibility x^（3） in the material is evaluated to be 4.96 × 10^-13 esu. The time-resolved DFWM process shows a response time of x^（3） shorter than 100fs, which is due to the nonresonant electronic nonlinearities. Our results indicate that LiNbO3 crystals have potentials for ultrafast real-time optical processing systems, which require a large and fast x^（3） optical nonlinearity.     

反铁磁铜氧化合物中的磁致形状记忆

La2-xSrxCuO4(以下称LSCO)是最早发现的高温超导体之一.当x≈0.15时,它具有最高的超导转变温度,Tc=33K.对于x<0.02的轻度掺杂,材料的低温相是反铁磁绝缘体.在室温以上时,层状化合物LSCO晶格具有四方对称性;当冷却样品通过特征温度To,将发生从四方到正交的结构相变.此时,晶体发展出一种被称为孪晶的畴结构,被畴壁分开的相邻区域具有不同的晶轴取向.正交结构的晶格常数a=05339nm,b=0.5422nm,两者相差约1%.为了探求高温超导机理,LSCO曾被广泛深入地研究.由于在超导LSCO中根本不存在41meV反铁磁自…