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951.
WANG Li-min CHU De-qing ZHANG Jing-ping WANG Rong-shun 《高等学校化学研究》2006,22(5):631-634
IntroductionDesigns and syntheses of organic molecules withvery high-spin ground states have been a topic of greatinterest[1—8].One of the rational approaches to desig-ning high-spin molecules,which has been proposedand studied by several groups[9,10],in… 相似文献
952.
953.
Qing Qing Meng He Xiang Bai Feng Li Quan Rui Wang Feng Gang Tao 《中国化学快报》2007,18(7):785-787
A convenient synthetic pathway to 2-aryl-5,6-dihydro-4H-benzo[f][1,2,4]triazolo[1,5-α]azepine derivatives 7 was developed. The synthesis was based on the cycloaddition of the 1,2,3,4-tetrahydronaphthalene a-acetoxy azo compounds 3 with Ar-CN in the presence of AlCl3 and the consecutive ring enlargement. 相似文献
954.
大戟属植物在全世界分布有2000多种,对于本属植物二萜类成分及生物活性的综述报道较多,但是还未见关于三萜类化学成分及生物活性的综述报道。本文综述了该属植物各种类型三萜化合物(羊毛脂烷型、环阿尔廷烷型、大戟烷型、甘遂烷型、齐敦果烷型、乌苏烷型及羽扇豆烷型等)的化学性能以及抗肿瘤、抗炎抗菌、抗病毒等主要生物活性的研究。 相似文献
955.
956.
Syntheses,Structures, Luminescent Properties and Photocatalytic Activities of Two Lead(II) Compounds
CONG Yao MA Cai-Lian CHE Guang-Bo BAI Hong-Ye SUN He-Yi REN Ao LIU Chun-Bo 《结构化学》2013,(11):1673-1679
Two lead(ll) compounds, [Pb(qlc)(phen)2(NO3)]e-H20 (1) and [Pb(qlc)z(phen)]-3H20 (2) (Hqlc = quinoline-3-carboxylic acid, phen = 1,10-phenanthroline), were synthesized and charac- terized by elemental analysis, single-crystal X-ray diffraction, IR and thermogravimetric analysis. Crystal 1 is of monoclinic, space group C2/c with a = 25.246(5), b = 12.543(3), c = 18.917(4) A, β = 105.77(3)°, V= 5765(2) A3, Z = 4, C68H46N12OllPb2, Mr = 1621.53, Dc = 1.886 g.cm-3,/.t(MoKa) = 5.912 mm-1, F(000) = 3152, GOOF = 1.080, the final R = 0.022 and wR = 0.0571 for 4822 observed reflections (1 〉 2a(/)). Crystal 2 is oftriclinic, space group Pi with a = 8.7883(10), b = 11.7031 (13), c = 15.9320(17) A, a = 69.9400(10), fl = 78.9780(10), 7 = 79.1650(10)°, V = 1497.4(3) A3, Z = 2, C32H26NaO7Pb, Mr. = 785.71, Dc = 1.729 g.cm-s, p(MoKa) = 5.688 mm-1, F(000) = 756, GOOF = 1.106, the final R = 0.0313 and wR = 0.088 for 59i5 observed reflections (1 〉 2σ(I)). Single-crystal X-ray diffraction analysis reveals that 1 exhibits a two-dimensional (2D) layer based on π-π stacking interactions between phen. Simultaneously, the adjacent 2D layers are assembled via π-π stacking interactions between phen and quinoline tings into a 3D supramolecular structure. The zero- dimensional structure of 2 is also further extended by π-π interactions to form a 2D supramolecular layer. Furthermore, these two compounds exhibit photoluminescence at room temperature in the solid state and their photocatalytic activities have been studied by degradation methylene blue. 相似文献
957.
AN Yue MU Ping-Ping GUO Zhi-Ping ZHOU Guang-Hua 《结构化学》2009,(5):607-611
Two novel cobalt(Ⅱ) compounds were obtained and characterized by X-ray sing- le-crystal diffraction, IR, 1H NMR and elemental analysis. Compound 1 crystallizes in monoclinic, space group P21/n, with a = 18.046(4), b = 11.335(3), c = 19.157(5)A, β = 92.707(3)°, Z = 4, V = 3914.4(16) A3, Mr = 968.56, Dc = 1.644 g/cm3, μ = 1.378 mm^-1, F(000) = 1960, the final R = 0.0367 and wR = 0.0895. The crystal of compound 2 is of monoclinic, space group P211c with a = 8.7253(10), b = 10.9031(13), c = 18.235(2)A,β = 93.2210(10)°, Z = 4, V = 1732.0(3)A3, Mr = 464.21, Dc = 1.780 g/cm3,μ = 1.560 mm-1, F(000) = 932, the final R = 0.0322 and wR = 0.0743. 相似文献
958.
A novel super molecule [Na(C60H80O12)]+[Au(SCN)4]- was obtained by extraction of calix[4] arene (L) for an aqueous solution containing [AuCl4]-, and NaCl into CH2Cl2. The crystal structure and properties of the title super molecule were characterized by single-crystal X-ray diffraction, IR and 1H NMR spectra. The X-ray single crystal structure analysis shows that the crystal was Tetragonal system with space group P4/n and the unit cell parameters were as follows: a=2.880 8(18) nm, b=2.880 8(18) nm, c=2.292 4(5) nm, and final R indices [I>2σ(I)]: R1=0.048 5, wR2=0.106 1. CCDC: 243229. 相似文献
959.
全固态钠离子电池具有资源丰富、安全性高等优势,作为未来大规模储能的重要选择而成为近年来先进二次电池前沿研究热点。钠离子硫系化合物电解质室温离子电导率高、弹性模量高、容易冷压成型,能增强电极/电解质界面接触、减小界面阻抗、缓冲电极材料在充放电过程中的应力/应变,是全固态钠离子电池的研究重点。本文对钠离子硫系化合物固态电解质的结构及性质进行了总结,讨论了硫系化合物电解质的本征特性、与电极的界面稳定性,并介绍了硫系化合物全固态钠离子电池的研究现状,最后分析了硫系化合物电解质面临的挑战及今后的发展方向。 相似文献
960.
在不同含N辅助配体的存在下,将5-甲基-3-吡唑甲酸(H_2MPCA)与相应的铅(Ⅱ)盐反应制得了2个新的配合物:[Pb(HMPCA)_2(H_2O)_2]·H_2O (1)和[Pb(HMPCA)_2(phen)]·H_2O (2)(phen=菲咯啉)。双核配合物1中双核[Pb(μ_2-HMPCA)]_2单元在一对Pb…O次级键的作用下形成了一维链状结构,这些一维链在氢键的作用下进一步自组装成2D超分子结构。而单核化合物2在Pb…O次级键的作用下形成了Pb_2O_2平面,它们在π…π和氢键作用下堆积形成3D超分子结构。考察了配合物1和2的热稳定性、荧光性能。 相似文献