二阶导数光谱-峰面积积分法同时测定芦荟中痕量铁(Ⅱ)和钴(Ⅱ)

在 1,10 -邻菲罗啉显色体系中 ,引入二阶导数光谱 -峰面积积分技术 ,建立了同时测定痕量铁 ( )和钴 ( )的新方法。该法可有效消除共存离子的干扰 ,提高了准确度和灵敏度。对铁和钴的表观摩尔吸光系数分别为 εFe5 .4 5× 10 6 L·mol-1·cm-1,εCo 1.1× 10 4 L· mol-1· cm-1;铁含量在 0 .0— 8.5 μg·m L-1,钴含量在 0 .0— 7.3μg· m L-1范围内遵守比耳定律。可用于芦荟中铁和钴的同时测定 ,结果令人满意     

Indriect Determination of CTMAB with Sodium Chloride and Ammonium Thiocyanate by Floatation and Separation of Zine

A new method for indirect determination of cetyl-trimethyl ammonium bromide (CTMAB) with NaCl and NH4SCH by floatation and separation of zinc has been studied.The study shows that Zn(Ⅱ） can associate with NH4SCN and CTMAB to form insoluble ternary ion-association complex,and the precipitate can float on the surface of the liquid phase.A good linear relationship is observed between the floatation yield(E%) of Zn(Ⅱ） and the amount of CTMAB.On the ground,CTMAB Can be indirectly determined by determining E% of Zn(Ⅱ）.The results were satisfactory.     

Effects of Pre-exposure Mouse Pituitary with Low-dose ^60Co γ-ray on Growth Hormone （GH） and Body Mass Induced by Subsequent High-dose Irradiation

The pituitary of the B6C3F1 hybrid strain mice were irradiated with 0.05 Gy of ^60Co γ-ray as the pre-exposure dose (D1), and were then irradiated with 2 Gy of ^60Co γ-ray as challenging irradiation dose (D2) at 4h after per-exposure. Body weight and serum growth hormone (GH) were measured at 35th day after irradiation. The results showed that irradiation of mouse testes with 2 Gy of ^60Co γ-ray significantly diminished mousebody weight and level of serum GH (Table). Pre-exposure with a low-dose (0.05 Gy) of ^60Co γ-ray significantly alleviated reductions of mouse body weight and level of serum GH induced by subsequent a high-dose (2 Gy) irradiation (Table). The data suggested that low-dose ionizing irradiation can induce adaptive responses to the harmful effects of pituitary by subsequent high-dose exposure.     

用改进嵌入原子法计算Cu晶体的表面能

用改进嵌入原子法(MEAM)计算了Cu晶体12个晶面的表面能.结果表明，密排面(111)的表面能最小.其他晶面的表面能随其晶面与(111)晶面夹角的增加而增加，据此可以粗略地估计各晶面表面能的相对大小.给出的几何结构因子的确定方法及结果可以直接用于计算其他面心立方晶体的表面能及其他特性.在Cu,Ag等面心立方薄膜中出现(111)择优取向或织构的机理是表面能的最小化. 关键词： 改进嵌入原子法 铜 表面能 计算     

某些类氖离子和类镍离子等离子体状态对应关系的研究

利用一维拉格朗日流体动力学程序Med103详细研究了产生类镍Ag,Cd,In,Sn, Sb离子和类氖Fe,Co,Ni,Cu,Zn离子的等离子体状态.通过对电子温度、离子丰度、离子数密度等状态参量的分析比较，得到了这两类等离子体状态之间的对应关系.即类镍银的等离子体状态与类氖铁 的相近，类镍镉的与类氖钴的相近，依次类推.利用这一对应关系可以方便地由类氖机理x射线激光的等离子体状态来对相应元素的类镍x射线激光的等离子体状态进行判断. 关键词： 类氖 类镍 等离子体状态 x射线激光     

ICP-AES测定钛基复合材料中镍、钕和铁的研究

采用ICP－AES法对钛基复合材料中的合金元素镍、钕、铁的测定进行了研究，着重进行了基体元素及待测元素镍、钕、铁之间干扰试验及各元素在测定浓度范围内的线性相关性试验，进行了酸度试验，测定了钛基复合材料中3种元素的含量，得到了较好的精密度和准确度。方法简便、可靠，获得满意的分析结果。     

Structural Evolution of Nanostructured γ—Ni—28Fe Alloy Investigated by Using the Internal Friction Technique

The structural evolution of nanostructured γ-Ni-28Fe alloy(n-Ni-Fe)(grain size d-30nm),synthesized by the mechno-chemical method,was investigated by using the internal friction technique combined with differential scanning calorimetry(DSC) in the temperature range from 300K to 670K.An internal friction peak with typical characteristics of the first-order phase transition was observed in the vicinity of 620K,which corresponds to a broad exothermic process revealed by using DSC.Theses results can be explained as the structural changes from the disordering to the ordering transition in the n-Ni-Fe sample.     

Crystal Structure of Adduct 2-Phenyl-imidazo [ 4,5-f ] 1,10-phenanthroline Methanol

The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials.     

ICP-AES同时测定混合矿物素中的磷、钙、铁、铜、锌、锰、镁、钴

采用ICP－AES法测定混合矿物素中的磷、钙、铁、铜、锌、锰、镁、钴元素含量，并对样品的溶解酸和酸用量、元素分析线的选择以及共存元素间的干扰进行了研究。该法简便、快速，精密度和准确度较好。     

苯并18-冠-6配合物[K(B18-C-6)]SCN的合成与结构分析

苯并 18 -冠 - 6 (B18- C- 6 )与 K2 [Cd(SCN) 4 ]反应 ,得到了 [K(B18- C- 6 ) ]SCN配合物。通过元素分析、红外光谱、单晶 X射线衍射进行了结构分析。该配合物为单斜晶系 ,空间群 P2 (1) / c,晶体学数据 :a=0 .996 0(3) nm,b=2 .5 0 97(7) nm,c=0 .8374 (2 ) nm,β=10 6 .5 19(5 )°,V=2 .0 0 6 7(10 ) nm3 ,Z=4 ,F(0 0 0 ) =86 4,R1=0 .0 4 2 9,w R2 =0 .0 5 75。结构分析表明 ,该配合物由一个 [K(B18- C- 6 ) ]配阳离子和一个 SCN阴离子组成 ,配合物的两个分子通过 K+ - π相互作用形成一维链状结构