Static and dynamic properties of grafted ring polymer: Molecular dynamics simulation

The static and dynamic properties of a system of end-grafted flexible ring polymer chains grafted to a flat substrate and exposed to a good solvent are studied by using a molecular dynamics method. The monomers are described by a coarse-grained bead-spring model. Varying the grafting density ρ and the degree of polymerization or chain length N, we obtain the density profiles of monomers, study the structural properties of the chain (radius of gyration, bond orientational parameters, etc.), and also present the dynamic characteristics such as chain energy and bond force. Compared with a linear polymer brush, the ring polymer brush exhibits different static and dynamic properties for moderate or short chain length, while it behaves like linear polymer brush in the regime of long chain length.     

二氢杨梅素-钴配合物的合成及其清除羟基自由基

用分光光度法测定了二氢杨梅素与Co(Ⅱ)反应的配比和条件稳定常数,结果表明,pH=7.4的NaH2PO4-Na2HPO4缓冲溶液中,二氢杨梅素与Co(Ⅱ)配位,采用等摩尔连续变化法测得二氢杨梅素-Co(Ⅱ)配合物的配位比为2∶1,计算得到该配合物的条件稳定常数为6.47×1013L2·mol-2;清除自由基试验结果表明,二氢杨梅素-钴(Ⅱ)配合物清除羟基自由基的能力强于配体二氢杨梅素.     

SiO2包覆共轭聚合物CN-PPV纳米探针的制备与荧光性质

采用纳米沉淀法制备了半导体聚合物CN-PPV纳米粒子,并用改进的Stber方法对纳米粒子进行包覆,获得了发光稳定的SiO2/CN-PPV纳米粒子。用动态光散射(DLS)及透射电镜(TEM)方法对粒子尺寸进行了表征,结果表明包覆前的CN-PPV纳米粒子平均粒径约为30 nm,包覆获得SiO2/CN-PPV纳米粒子的平均粒径约为60 nm。通过紫外-可见吸收光谱及荧光光谱对包覆前后纳米粒子的发光性质进行了比较,发现共轭聚合物CN-PPV包覆后的发射光谱与包覆前相比发生了小的蓝移,表明共轭聚合物的分子构型可能发生了微小变化。SiO2包覆可以提高聚合物发光分子的光稳定性,并且提供用于生物分子耦联的表面,这类材料有望在生物医学成像中获得应用。     

Mg2+-ENRX体系的荧光特性及恩诺沙星含量的测定

基于镁(Ⅱ)对恩诺沙星的荧光强度有显著的增敏作用,建立了镁(Ⅱ)增敏,荧光光度法快速测定恩诺沙星的新方法.在pH5.5的酒石酸-酒石酸钠缓冲溶液中,恩诺沙星在1.00×10-8-1.00×10-6mol/L范围内符合比耳定律,方法检出限为7.5×10-10mol/L.已用于片剂中恩诺沙星的测定,样品平均回收率为93.91％,RSD=0.55％.实验表明,该方法简单、快速、灵敏、准确.     

链间耦合对极化子非弹性散射性质的影响

基于一维紧束缚的Su-Schreiffer-Heeger模型, 采用非绝热动力学方法, 研究了链间耦合对聚合物中极化子对非弹性散射性质的影响: 激子的产生依赖于链间耦合, 随着耦合强度的增加, 正负极化子对的电子波函数交叠增强, 利于提高激子的产率; 当耦合区域是极化子的宽度时, 正负极化子对波函数的耦合最充分、耦合最强, 电荷跃迁更容易, 激子产率最大. 关键词： 聚合物 极化子 激子     

Epoxy Resin-Photopolymer Composite with None-Shrinkage for Volume Holography

A novel photopolymer storage medium for holographic storage is presented. In particular, the refractive in-dex of the monomer methyl methacrylate is much lower than that of the binder epoxy resin solidified by m-xylylenediamine, and the material can be developed into samples with dimension stability and high optical quality and thickness of several millimetres or more. Some none-polymeric macromolecule impurity is uniformly mixed into the medium to aid the monomer diffusing and to enhance the diffraction efficiency. A holographic recording medium of 0.8 mm thickness has been fabricated, and relative theoretical analysis and experiments are presented.     

Giant Positive Magnetoresistance in Grain-Oriented CxCo1-x Alloys

The grain-oriented CxGo1-z (x = 0.9, 0.5) samples were fabricated by the hot.pressing method. The microstruc-ture was observed by an x-ray diffractometer and a scanning electron microscope. The resistance against the applied magnetic field was measured by a standard four-polnt probe method at different temperatures. The magnetoresistance and the magnetization ratio were studied as a function of magnetic field in the range of -1800 kA/m-1800 kA /m at different temperatures from 50 K to 300 K. The magnetoresistance of grain-oriented GxGo1-x is positive. The maximum positive MR of 98% at 50 K and 34% at 300 K was obtained under 1800 kA/m magnetic field in the C0.9Go0.1 sample.     

“神光”Ⅱ黑腔物理分解实验

本项目主要关注金腔靶内辐射烧蚀等离子体运动对辐射场特性及其诊断产生的影响和抑制方法。黑腔诊断口附近金等离子体喷射容易造成堵口现象，对X光发射能谱特性和角分布测量产生不利影响。腔内金等离子体向心运动还会使入射激光光路偏折，从而改变着靶点位置和能量沉积区域，影响腔内辐射场分布。为便于实验诊断分析，采用半腔靶和静态充气腔靶两种分解靶型进行研究，分别对应以下研究内容：了解金腔靶诊断口附近等离子体喷射对X光诊断的影响和抑制方法；利用填充气体抑制腔壁金等离子体喷射，证实静态充气黑腔靶实验的技术可行性。     

“神光”Ⅱ内爆动力学研究

2003年“神光”Ⅱ内爆实验中，获得了靶丸燃料区空间分辨的Ar线谱—由此得到Heα等谱线发射区的尺寸，分别由线强比和谱线Stark宽推出了燃料区的电子温度和密度。     

快速响应“智能型”水凝胶

链接聚合物可以形成在生物医学上有应用前景的水凝胶,而水凝胶的性能似乎与聚合物组成分子的排列密切相关.水凝胶是一种三维聚合物链形成的网状物.它在水中能膨胀,但不溶解.水凝胶的形成是一种有趣的现象.它有一天可能成为新的生物物质或药品递送系统设计、合成和自组装的补充工具.Wichterle和Lim 在1960年合成了第一个有乙烯-二甲基丙烯酸盐的2-羌乙基-异丁烯酸盐,它是一种在医学上有应用前景的生物共聚物.这种水凝胶是最初的软性隐型眼镜的材料.它们的生物兼容性在临床上已得到证明.软性隐型眼镜的成功激起了对水凝胶的巨大兴趣,并引起“…