铁及稀土元素在DOWEX 1-X8阴离子交换树脂上分配系数的测定及其应用于原子发射光谱法测定钢中稀土元素含量

对铁和稀土元素在DOWEX 1-X8阴离子交换树脂上于不同浓度的盐酸和硝酸介质中的分配系数(K_d)进行了研究,试验结果表明:在6～9 mol·L~(-1)盐酸介质中Fe~(3+)的K_d10~3,即强吸附于DOWEX 1-X8阴离子交换树脂,而稀土元素在DOWEX 1-X8阴离子交换树脂的K_d≤10,即不吸附于树脂;而在浓度低于2 mol·L~(-1)的硝酸介质中,Fe~(3+)的K_d6.4,即不吸附于树脂上,故选用1.6 mol·L~(-1)硝酸溶液将吸附于柱上的Fe~(3+)洗脱下来。在此基础上提出了一种阴离子交换树脂分离电感耦合等离子体原子发射光谱法测定洁净钢中微量稀土元素含量的方法。该方法用于测定产于日本及韩国的洁净钢样品,测得回收率在87.7%～118.3%之间,相对标准偏差(n=6)小于23%。     

Performance and characterization of iron-nickel catalysts for light olefin production

A series of x (Fe, Ni)/Al2O3 catalysts (x = 2--12 wt%) were prepared using incipient wetness method and studied for the conversion of synthesis gas to light olefins. 6 wt%(Fe, Ni)/Al2O3 catalyst was found to be the optimal catalyst for the production of C2--C4 olefins. The effects of calcination behaviors and operational conditions on the catalytic performance of the optimal catalyst were investigated. The best operational conditions were molar feed ratio H2/CO = 2/1, T = 260 ℃, gas hourly space velocity (GHSV) = 2600 h-1 and the pressure of 3 bar. Characterizations of both precursors and catalysts were carried out using X-ray diffraction (XRD), temperature-programmed reduction (TPR), scanning electron microscopy (SEM), N2-adsorption-desorption measurement, thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC).     

多元轻稀土硝酸盐水溶液的等压实验研究

采用改进的等压法研究了影响多元轻稀土硝酸盐水溶液体系等压平衡的因素,确定了在低水活度区以氯化钙水溶液、高水活度以氯化钠水溶液为等压平衡参考物;等压平衡实验时间按水溶液浓度由高到低的顺序依次从4d到7d不等;确定了硝酸镧、硝酸镨及硝酸钕水溶液的等当点.结果表明,在实验误差允许范围内,所考察的系统符合偏理想溶液模型.     

Mixed Quark-Gluon Condensate Beyond Chiral Limit

Using the Dyson-Schwinger equation and perturbation theory, we calculate the mixed quark-gluon condensates in the chiral limit and in the case of nonzero quark current mass for the light quark u/d and strange quark s. The results show that the mixed quark-gluon condensate will decrease when the quark mass increases. For the quark with zero mass, we obtain mo2 = g（qσuvGuvq）/（qq） 0.68 GeV2, which is in good agreement with the QCD sum rules estimate mo2=（0.8± 0.2） GeV2.     

Lepton Flavor Violating Z →lIlJ in SO（3） Gauge Extension of SM

The SO（3） gauge extension of SM, which is proposed to present a successful explanation for the observed small masses of neutrino and the nearly tri-bimaximal neutrino mixing, predicted the vector-like SO（3） triplet Majorana neutrinos and SUL（2） double Higgs bosons. In this work we calculate branching ratios of the charged lepton flavor violating decays lIlJV （V = γ, Z） induced by these Majorana neutrinos and Higgs bosons. We find that under the model parameters constrained by experimental bounds on the decays Z →lIlJ, the branching ratio of decays lI→lJγ can be up to 10^-10, which may be accessible at the future experiments.     

Perturbation Effects of Ion Screening to Leptons in Type-II Supernova

Based on the new progenitor stars model, the influence of ion screening is investigated. The simulation results show that ion screening has weak perturbation effects to the leptons in type-II supernova explosion. Ion screening decreases slightly the fraction of leptons and prolongs slightly the shock propagation time. Moreover, simulation results are shown that ion screening increases the total energy loss and reduces the shock energy, eventually decreasing of explosion energy and becomes a negative factor to supernova explosion. In addition, comparison of slight perturbated variation of ion screening to leptons, but simulation results＂ show that ion screening affects obviously explosion energy of type-II supernova, hence, it can also confirm that the variation of leptons is very sensitive to energy in supernova explosion.     

Isospin violation,light quark masses,and all that

Isospin violation is driven through the light quark mass difference and electromagnetic effects.I review recent progress in extracting the light quark mass difference and tests of the chiral dynamics of Quantum Chromodynamics in various reactions involving light as well as heavy quarks.     

Search for new physics in the B→K^（＊）l^＋l^- decays at BABAR

Based on a data sample of 384 million BB pairs collected with the BABAR detector at the PEP-Ⅱ asymmetric e ＋ e ￣ storage ring,we measure branching fractions,direct CP,isospin and lepton-flavor asymmetries for the rare decays B → K （＊） l ＋ l￣ in two di-lepton mass bins above and below the J/ψ resonance.For the B → K＊ l ＋ l￣ decay,we also measure the K＊ longitudinal polarization fraction and the di-lepton forwardbackward asymmetry.     

Theoretical Analysis of Neutron Double-Differential Cross Sections of n ＋^9Be Reactions

By using the nuclear reaction model for light nuclei, the calculations of the double-differential cross sections of outgoing neutrons from n ＋^9Be reactions are performed. The total outgoing neutrons are only come from the （n, 2n）2a reaction channel. The （n, 2n）2a reaction channel is achieved through six different reaction approach, which are illustrated in this paper. The calculated results agree very well with the measured data at En = 7.1, 8.09, 8.17, 9.09, 9.97 and 10.26 MeV, because the updated level schemes related to the n ＋ ^9Be reactions have been employed in this calculations.     

《稀土元素及其分析化学》

该书详述了稀土元素的基本性质、稀土化合物的性质与合成、稀土化学反应的基本原理与应用以及稀土分析化学的基本知识。全书内容包括稀土元素的电子结构和镧系收缩,磁学和光学性质,各价态化合物的性质、制备、分析及分析方