超声波提取-等离子体原子发射光谱测定何首乌中的磷脂

采用超声波提取法提取中药何首乌中磷脂类化合物,探讨了提取溶剂用量、提取时间及超声功率等因素对磷脂提取率的影响,结合ICP-AES分析法对提取的磷脂类化合物进行了测定.结果表明,对于1.5 g何首乌,用20 mL Folch试剂,超声提取35 min,超声功率为24 kHz的条件下磷脂提取率较高.     

兆巴高压下c向蓝宝石的冲击辐射研究

采用三层夹心靶结构,利用铜箔与抛光蓝宝石之间良好的接触条件,使用辐射式高温计在1.30～1.72兆巴压力范围内观测到c向蓝宝石的强冲击辐射。在1.30和1.72兆巴的冲击压力下,得到蓝宝石在0.633μm波长处的不透明系数为1.7 cm-1和5.0 cm-1。实验显示蓝宝石的冲击辐射随着冲击压力的增加而急剧增强。     

Decomposition Reaction of Zn-MPA（3-Mercaptopropionic Acid） Complex Under Microwave Irradiation

The thermal decomposition of Zn-MPA complex was investigated under microwave irradiation. ZnO and ZnS nanocrystals could be obtained by decomposing Zn-MPA（3-mercaptopropionic acid） complex under different reaction conditions. It was found that both the pH value of the solution and the molar ratio of Zn2＋ and MPA can play an important role in the formation of ZnO and ZnS nanocrystals. MPA mainly acts as an S source or as a complexing agent. This study provides a new route for the controllable preparation of semiconductor nanocrystals.     

CHAOTIC MOTIONS AND LIMIT CYCLE FLUTTER OF TWO-DIMENSIONAL WING IN SUPERSONIC FLOW

Based on the piston theory of supersonic flow and the energy method, the flutter motion equations of a two-dimensional wing with cubic stiffness in the pitching direction are established. The aeroelastic system contains both structural and aerodynamic nonlinearities. Hopf bifurcation theory is used to analyze the flutter speed of the system. The effects of system parameters on the flutter speed are studied. The 4th order Runge-Kutta method is used to calculate the stable limit cycle responses and chaotic motions of the aeroelastic system. Results show that the number and the stability of equilibrium points of the system vary with the increase of flow speed. Besides the simple limit cycle response of period 1, there are also period-doubling responses and chaotic motions in the flutter system. The route leading to chaos in the aeroelastic model used here is the period-doubling bifurcation. The chaotic motions in the system occur only when the flow speed is higher than the linear divergent speed and the initial condition is very small. Moreover, the flow speed regions in which the system behaves chaos axe very narrow.     

多目标多光谱辐射高速高温计的研制

固体火箭羽焰是一种特殊的火焰,固体火箭发动机喷管羽流沿径向和轴向的温度是研究固体推进剂燃烧状况和发动机燃烧流场的基本参数。针对固体火箭发动机尾喷焰温度及其空间分布测量的需要,继1999年采用多光谱辐射测温方法和技术实现航天某型号固体火箭发动机测量后,研制了新型的多目标多光谱辐射高速高温计用于固体火箭发动机地面搭载试验。仪器使用组合棱镜和光电二极管阵列实现目标0.4~1.1μm光谱的热辐射测量,在主光路设计中首次使用光纤技术,实现一台仪器同时测量空间分布6个目标点的温度和发射率,每个点的空间位置由光阑上的通光孔精确确定,且每个目标测点均有8个工作光谱,研制的同步高速数据采集系统完成48个测量通道的数据同步时间小于10 ns。     

《Wuhan University Journal of Natural Sciences》Vol．9 No.6 2004摘要选登

四核苯甲酸锌配合物的合成和晶体结构；杯芳烃[6]修饰碳糊电极同时测定痕量铅和镉的研究；新型双卟啉的合成及结构表征；含二个硫脲基的荧光化学传感器的合成及其对二羧酸阴离子的识别行为     

流动注射分光光度法测定脱氧核糖核酸

基于DNA对三苯甲烷类阳离子染料甲基紫的褪色反应建立了流动注射分光光度法测定DNA的新方法。探讨了最佳的褪色条件,工作波长为580nm,线性范围为0－30μg/mL。本法流路简单、操作方便。进样频率为60次／h。     

医用超声治疗机换能器表面辐射声动率的声光法测量

声光法测量声功率,是利用平面波超声在透明液体中对光波产生的衍射效应来测量的一种方法.它能测量紧贴换能器表面的辐射功率,并且对声场没有影响.适宜于测量医用超声治疗机换能器的表面辐射功率.此文叙述了实验方法,给出了实验结果,并把结果列成表,以便查阅.结论表明,此法测量简便,精度较高.     

Polarization and Angular Distribution of Ll X-Ray Following Inner-Shell 2p3/2 Photoionization of Magnesium-Like Ions

The inner-shell 2pa/2 photoionization and the subsequent decay of Mg-like Fe^14＋, Cd^36＋, W^62＋ and U^80＋ ions are studied theoretically within the multiconfiguration Dirac-Fock method and the density matrix theory. Special attention is paid to exploring the influence of the non-dipole terms which arise from the multipole expansion of the electron-photon interaction in the photoionization process. The results show that the non-dipole contribution to the total cross section, the magnetic sublevels cross section of the photoionization process, the degree of linear polarization and angular distribution of the subsequent characteristic x-ray radiation become more important with the increase of photons energy and atomic nuclear Z. Especially for the cross section and the degree of linear polarization, the non-dipole contribution arrives at 50% for U^80＋ at four time energy threshold units. However, for the angular distribution, the maximum contribution does not exceed 4%, even for U^80＋ ions.