Ba2SiO4荧光粉中Ce3+和Eu2+的光谱性质和能量传递

采用高温固相法合成了绿色荧光粉Ba2SiO4:Ce3 ,Eu2 .测量了它们的吸收光谱、激发光谱和发射光谱,观察到了Ba2SiO4中Ce3 对Eu2 发光的敏化现象,发光的敏化作用缘于Ce3 和Eu2 之间的高效无辐射能量传递.     

对正负一级能量之比测量光栅参量方法的改进

提出利用同一波长的入射光在双面入射时两个能量之比的比值对光栅的参量进行测量,进一步提高准确度。首先从理论上比较正弦面形光栅在单一面入射及双面入射时各种衍射效率对光栅表面粗糙度的敏感程度;然后模拟测量出该正弦面型光栅在双面入射情况下的光栅参量;最后成功反演出体积相位全息光栅的三个参量,其测量结果为0.080μm,1.452μm,20.5μm准确度比单一入射面情况(0.080μm,1.451μm,20.1μm)时要高。同时该法继承了原来方法的无损伤、操作简便、可重复、易推广、成本低等优点。     

从窗棂图案到金刚石结构规律探究

笔者研读了一些书籍,体味到了些许科学文化之美,在此与大家分享。最让我心动的还是蜂巢和中国传统的窗棂、漏窗图案之秀美。图1小小的蜜蜂,不愧为是大自然的小精灵,只用正六边形构筑它的巢室,这种构造所用材料最少,构筑成的巢穴空间却最大。花费最少材料,却能获得最大的空间,自然的美妙与数学的简炼和谐之美,紧密地联系在一起。六边形不仅仅在蜂房和艺术的殿堂里找到,在雪花、分子(如苯、已糖及其衍生物)、晶体(如石墨)、海洋生物中都能找到它的倩影。我一边赏析着窗棂图案之美,一边从这些迷人线条组成的复杂背景中梳理着规律性知识。其一,…     

Crystal Structure and Activity against Acetaminophen-induced Hepatotoxicity of a Potassium Complex with Taurine-5-bromosalicylaldehyde Schiff Bases

A novel potassium complex KC9H9NO4SBr has been synthesized and characterized by IR spectra and single-crystal X-ray diffraction method. The crystal belongs to orthorhombic, space group Pbca with a = 0.74040（15）, b = 0.74960（15）, c = 4.2620（9） nm, V = 2.3654（8） nm^3, Mr = 346.24, Dc = 1.945 g/cm^3, Z = 8, F（000） = 1376, μ（MoKa） = 4.005mm^-1, GOOF = 1.021, R = 0.0471 and wR = 0.0872. In the crystal, the potassium ion is typically eight-coordinated, surrounded by eight O atoms from six （E）-2-（5-bromo-2-hydroxy-benzyli-deneamino）ethanesulfonate anions. The neighboring potassium ions are bridged by sulfonate groups into a two-dimensional layer structure, above and below which the 5-bromo-2-hydroxy-benzene rings are protruded. The activity against acetaminophen-induced hepatotoxicity of this complex was also studied, and found it can protect liver from hepatotoxicity induced by acetaminophen （AAP） to some extent.     

沥青基球状活性炭气相吸脱附行为研究

本文利用热重法研究了一系列沥青基球状活性炭对蒸汽及正已烷蒸汽的动态吸脱附曲线。结果表明,PSAC对苯蒸汽的吸附及再生性能优良。随吸附温度的降低、比表面积的增大、总孔容及微孔容的增大,PSAC对苯蒸汽的吸附容量增大。PSAC对正已烷的吸附速度大于对苯蒸汽的吸附速度,但其对正已烷的平衡吸附容量小于对苯蒸汽的平衡吸附容量。     

一类带有无穷时滞的Lotka-Volterra食饵捕食系统的正周期解

首先给出了一类带有无穷时滞的Lotka-Volterra食饵捕食系统,接着使用Krasnoselskii’s不动点定理研究了其正周期解的存在性;然后证明了正周期解的全局吸引性;最后,给出了一个例子.     

污染数据半参数回归模型估计的渐近正态性

考虑半参数回归模型：yi=xiβ g(ti) e1,i=1,2,…,n,其中Ee1=0,Ee^2/1=δ2/1>0．假定y1,y2,…,y0受到另一独立同分布随机变量序列μ1,μ2,…,μn的污染,{μi}与{y1}独立,且仅能观察到污染数据.[ι]对由污染数据作出的参数β的估计βn,证明了它的强相合性．而本则证明了它的渐近正态性．     

具无限时滞的周期系统的持久性与正周期解

本文利用比较定理,控制收敛定理和积分平均的方法,讨论一类具有无限时滞的非自治,非卷积的捕食者-食饵系统的一致持久性和正周期解。     

非线性自回归序列L1估计的渐近分布

由于时间序列数据中经常出现的厚尾特征使得通常的估计方法不再具有渐近的正态分布,在误差项二阶矩有限的条件下考虑了非线性自回归序列的L_1估计.采用局部线性近似的方法得到了具有凸样本路径的随机过程,在此基础上利用凸样本路径随机过程弱收敛的性质证明了非线性自回归序列L_1估计的渐近正态性及无偏性.     

Controlled quantum state sharing of arbitrary two-qubit states with five-qubit cluster states

In this paper, we propose a controlled quantum state sharing scheme to share an arbitrary two-qubit state using a five-qubit cluster state and the Bell state measurement. In this scheme, the five-qubit cluster state is shared by a sender (Alice), a controller (Charlie), and a receiver (Bob), and the sender only needs to perform the Bell-state measurements on her particles during the quantum state sharing process, the controller performs a single-qubit projective measurement on his particles, then the receiver can reconstruct the arbitrary two-qubit state by performing some appropriate unitary transformations on his particles after he has known the measured results of the sender and the controller.