稀土甘氨酸咪唑配合物[RE(Gly)4(Im)(H2O)](ClO4)3的热化学研究

采用溶解-反应量热法在具有恒温环境的溶解-反应热量计内,测定了[Gd(Gly)4(Im)(H2O)](ClO4)3和[Y(Gly)4(Im)(H2O)](ClO4)3两种稀土甘氨酸咪唑配合物的标准生成焓分别为(-3 461.46 ±0.22) kJ·mol-1 和(-3 926.6±0.90) kJ·mol-1.     

A Facile Synthesis of Silver-Coated Composite Particles by Swelling Surface Method

We report a facile and rapid method for fabrication of composite particles consisting of a polystyrene (PS) core and a uniform silver shell. The process involves the PS colloid surface swelling, the anchoring of silver ions and nanoparticles onto the surfaces, and the subsequent growth of metal seeds in a short period. The present approach has the advantages of simplicity and high efficiency. The TEM images show the morphology of the obtained PS core-silver shell particles, and their chemical composition and crystallinity are analysed by x-ray diffraction. To our knowledge, this is the first study based on swelling PS surface for synthesis of silver-coated PS particles and may be implemented for preparing other metal-coated PS particles.     

Singlet-Triplet Transition in Quantum Dots Confined by Triangular and Bowl-Like Potentials： the Effect of Electric Fields

We theoretically investigate the energy spectra of two-electron two-dimensional （2e 2D） quantum dots （QDs） confined by triangular potentials and bowl-like potentials in a magnetic field by exact diagonalization in the framework of effective mass theory. An in-plane electric field is found to contribute to the singlet-triplet transition of the ground state of the 2e 2D QDs confined by triangular or bowl-like potentials in a perpendicular magnetic field. The stronger the in-plane electric field, the smaller the magnetic field for the total spin of the ground states in the dot systems to change from S = 0 to S = 1. However, the influence of an in-plane electric field on the singlettriplet transition of the ground state of two electrons in a triangular QD modulated by a perpendicular magnetic field is quite small because the triangular potential just deviates from the harmonic potential well slightly. We find that the strength of the perpendicular magnetic field needed for the spin singlet-triplet transition of the ground state of the QD confined by a bowl-like potential is reduced drastically by applying an in-plane electric field.     

一个线性约束优化问题的广义梯度投影法

本文对线性约束优化问题提出了一个新的广义梯度投影法，该算法采用了非精确线性搜索，并在每次迭代运算中结合了广义投影矩阵和变尺度方法的思想确定其搜索方向．在通常的假设条件下，证明了该算法的整体收敛性和超线性收敛速度．     

Luminescent Properties and Mechanism of Gd1-x-yAlO3Eux,REy

GAP:Eu,Re(Gd1-x-yAlO3Eux,REy?A，RE=Pr or Ce) powders were prepared by a nitrate-citrate process. It is found that luminescent intensity decreases when GAP:Eu is co-doped with Pr or Ce. The phenomena of spectra prove that there is a resonant energy transfer between Eu and Pr, by the absorption and emission of lower-energy phonon, and also Ce sensitizer decreases the activator energy level from host→Eu. The two factors are considered to be the main reasons for decrease of the luminescent intensity for the co-doped GAP:Eu,Re.     

珠心算排积法论

传统的关于合并同位项的求排积方法都是通过计算求出来的，因为其层次过多，进位链条过长，出现了一种曲线思维，如果算法停在这个水平上，不可能使计算加快，尤其在幼儿中推广困难更大，其大量的抽象概念，孩子很难接受。在这个历史条件下，方应运产生了认字排积法。     

脉冲中子探测系统的中子灵敏度能量响应

为了获得脉冲中子探测系统的中子灵敏度能量响应，编制了适合裂变中子测量探测系统灵敏度能响的一系列专用程序，研究了相应的实验标定技术，采用理论计算和实验验证相结合的方法，对几套探测系统中子灵敏度能量响应进行了研究，初步解决了标定需要的“单能、脉冲、高强度、多个不同能量的中子源”问题，使不确定度大大提高，满足了测量的要求。     

Δ—scaling and Information Entropy in Ultra—Relativistic Nucleus—Nucleus Collisions

The Δ-scaling method has been applied to ultra-relativistic p p,C C and Pb Pb collision data simulated using a high-energy Monte Carlo package,LUCIAE 3.0.The Δ-scaling is found to be valid for some physical variables,such as charged particle multiplicity,strange particle multiplicity and number of binary nucleon-nucleon-nucleon collisions from these simulated nucleus-nucleus collisions over an extended energy ranging from E1ab=20 to 200A GeV.In addition we derive the information entropy from the multiplicity distribution as a function of beam energy for these collisions.