One-dimensional Coordination Polymers of rctt-1,3-Diphenyl-2,4-bis [2-（5-phenyl）- oxazolyl]cyclobutane with CuCI2 and COCl2

The Cu（Ⅱ） and Co（Ⅱ） supramolecular coordination polymers, [CuCl2（DPO）- （CH3CN）0.5（CH2Cl2）0.5]n （CuDPO, DPO = rctt-1,3-diphenyl-2,4-bis[2-（5-phenyl）oxazolyl]cyclo- butane） and [CoCl2（DPO）]n （CoDPO）, were synthesized and characterized by single-crystal X-ray diffraction method. CuDPO crystallizes in monoclinic, space group P21/n, with a = 11.243（5）, b = 16.070（8）, c = 19.872（9） A, β = 95.678（10）°, Z = 4, V= 3573（3） A3, C35.50H28.50Cl3CuN2.50O2, Mr = 692.00, Dc = 1.287 g/cm3, p = 0.868 mm^-1, F（000） = 1420, S = 1.089, （△/σ）max = 0.069, the final R = 0.0682 and wR = 0.1749. CoDPO is of monoclinie, space group P21/n, with a = 11.396（4）, b = 15.151（5）, c = 17.673（6） A, β = 90.528（6）°, Z = 4, V = 3051.4（17） A3, C34H26Cl2CoN2O2, Mr = 624.40, Dc = 1.359 g/cm3, μ = 0.770 mm^-1, F（000） = 1284, S = 0.981, （△/σ）max = 0.001, the final R = 0.0471 and wR = 0.0961. In each case, the metal cation is coordinated by two C1 anions and two N atoms from oxazole ring of the ligands, which leads to the formation of a one-dimensional polymeric structure. It is found that the cyclobutane ring of coordinated DPO adopts a distorted conformation in the crystal, which is attributed to the increased steric effect between adjacent aryl substituents for the coordination of oxazole ring to metal cation. Thermal gravimetric analysis of the two complexes was also observed.     

光电倍增管脉冲性能研究

采用外腔式电光开关，调制主动照明探测光源，使光电倍增管处于脉冲工作状态下，以提高光电倍增管的输出幅度和动态范围，改善信号的信噪比，同时避免样品和探测器长时间受强激光照射。对滨松H6780光电倍增管进行了调试，使其线性输出电流由静态的0．1mA提升到脉冲状态的4．4mA，信噪比提高到6．6倍。     

模型外载与自重并存变动外载的光弹性分析法

提出一个变动模型外载，分析大模型在外载与自重共同作用时的尤弹性法。它与用离心力模拟自重试验的传统方法完全不同，只要在大模型上变动外载，就可以获得上述两种载荷共同作用下的应力分析结果。此法避免了用离心模型自重受模型尺寸限制等诸多因素影响的缺点，为自重不可的大型复杂空间工程结构模型试验应力分析提出了一条新的途径。文中给出了本方法的基本原理及其简要的实验验证和工程应用结果。     

磷脂改性聚合物膜

综述了膦脂改性聚合物膜的制备方法，其中饭知光引发接枝、电晕放电、化学接枝、原位聚合、共混改性、物理吸附等方法，并对磷脂改性聚合物膜的部分性质和应用前景作了简单介绍。     

Synthesis and characterization of novel poly（aryl ether sulfone ketone）s containing phthalazinone and biphenyl moieties

A novel series of poly（aryl ether sulfone ketone）s （PPESKs） containing phthalazinone and biphenyl moieties were prepared by two-step nucleophilic polycondensation reaction. The ^-Mw values of these copolymers were between 38,330 and 67,900. The glass transition temperatures （Tg） and 5% decomposition temperatures were ranged in 253-269 ℃ and 488-500 ℃, respectively, The structures of these copolymers were confirmed by FT-IR and ^1H NMR. Moreover, all the resultant copolymers were amorphous determined by wide angle X-ray diffraction （WAXD）.     

外代数上复杂度为2的Koszul模

本文对外代数上复杂度为2的不可分解循环Koszul模M的极小投射分解进行了分析，构造出了基映射对应的矩阵的一种标准形式，进而刻划出了其合冲ΩM的滤链结构．