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31.
32.
The polyacrylic acid functionalized polystyrene nanospheres were synthesized and self-assembled into irregular, densely packed monolayers in non-aqueous media. The polymer nanoparticles were chemically adhered to substrates. The morphologies of the resulting films were investigated. The impact of the volume fraction of alcohol in the mixed solvents on the particle adsorption and fabrication of nanosphere assembled films was examined. 相似文献
33.
The adsorption of asymmetrical triblock copolymers from a non-selective solvent on solid surface has been studied by using Scheutjens-Fleer mean-field theory and Monte Carlo simulation method on lattice model. The main aim of this paper is to provide detailed computer simulation data, taking A8-kB20Ak as a key example, to study the influence of the structure of copolymer on adsorption behavior and make a comparison between MC and SF results. The simulated results show that the size distribution of various configurations and density-profile are dependent on molecular structure and adsorption energy. The molecular structure will lead to diversity of adsorption behavior. This discrepancy between different structures would be enlarged for the surface coverage and adsorption amount with increasing of the adsorption energy. The surface coverage and the adsorption amount as well as the bound fraction will become larger as symmetry of the molecular structure becomes gradually worse. The adsorption layer becomes thicker with increasing of symmetry of the molecule when adsorption energy is smaller but it becomes thinner when adsorption energy is higher. It is shown that SF theory can reproduce the adsorption behavior of asymmetrical triblock copolymers. However, systematic discrepancy between the theory and simulation still exists.The approximations inherited in the mean-filed theory such as random mixing and the allowance of direct back folding may be responsible for those deviations. 相似文献
34.
在硝酸介质中,痕量铬(Ⅵ)能灵敏的催化氧化DBC褪色。研究了反应的最佳条件,建立了测定痕量铬(Ⅵ)的新方法。检出限可达10^-9g/ml,测定范围为0.12--0.7μgCrC(Ⅵ)/10ml,方法简便、灵敏、快速、准确。用于测定水中的痕量铬(Ⅵ),获得了满意的结果。 相似文献
35.
本文通过制备吸附树脂D3520负载的钴,锰双金属氧化物催化剂(Co-Mn-O/D3520),考察了在强碱性醇溶液中氧化对甲酚制对羟基苯甲醛的催化性能。利用XRD,XPS,IR等方法研究了催化剂的表面结构及其与催化性能的关系。 相似文献
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从第一性原理出发利用密度泛函理论研究了 4 ,4′ 二巯基联苯分子和金表面的相互作用 ,并利用了前线轨道理论和微扰理论定量地确定了该相互作用能常数. By using density functional theory, we have investigated the interaction between a thiol-phenyl molecule (4-4′-dimercaptodibenzene) and a gold surface. The frontier orbit theory and the perturbation theory are also employed to determine quantitatively the constant of interaction energy. The results show that the bonding between the sulfur atom and the gold atoms corresponds mainly to the covalent bond and some molecular orbits are extended over the molecule and gold cluster which certainly give channels... 相似文献
38.
皮道华 《数学物理学报(A辑)》1991,11(1):61-69
本文用无穷小变换群使作用量不变的思想,直接导出线性微极弹性动力学的一类守恒律,对线性均匀微极弹性固体证明了在纯量变换下不可能有守恒律,对线性微极弹性动力学而言,可看出守恒律(4.7)式是新的和独特的。 相似文献
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40.
We take the viewpoint that X(1576) is the tetraquark state which consists of a scalar diquark and an antiscalar-diquark in relative P-wave, and calculate its mass in the framework of the QCD sum rule approach. The numerical value of the mass mx= (1.66 =k 0.14) GeV is consistent with the experimental data. There might be some tetraquark components in the vector meson X(1576). 相似文献