连续搅拌槽式反应器中自催化化学反应的延迟同步

讨论了由两个连续搅拌槽式反应器组成的化学反应系统的延迟同步问题.基于Lyapunov稳定性理论,通过选择适当的输出和同步信号得到了使反应实现延迟同步的控制函数,并用数值模拟验证了方法的有效性.最后指出延迟同步误差系统存在着两种不同的时间尺度. 关键词： 延迟同步 化学反应 连续搅拌槽式反应器 时间尺度     

CO分子的A1Π(v=1)对d3∆(v=5)态的微扰研究

CO谱带的微扰给谱线的标识和分析带来挑战.这里针对CO A1Π(v=1)对d3∆(v=5)态的微扰,首先采用有效哈密顿矩阵的方法重新分析了d3∆—a3Π(5,0)带高精度的涉及d3∆2和d3∆3的振转光谱数据,发现A1Π的微扰可忽略不计.进一步理论计算了由A1Π的微扰产生的d3∆的∆1,∆2和∆3的转动能级移动和d3∆—a3Π(5,0)光谱强度的变化.发现∆1的能级移动最大,最大可达4 cm-1,这个能级移动随J值的增大而减小;对∆2和∆3的影响在J小时可忽略不计.光谱强度的改变有类似的变化趋势,涉及到∆1的d3∆1—a3Π光谱强度减小量最大可达20%,随J的增大,此减小量变小;对涉及∆2和∆3的光谱强度此微扰可忽略不计,从而给出了上面实验数据分析中不考虑微扰的原因.     

纳米晶锐钛矿相TiO2的非简谐效应和声子局域

对晶粒尺寸为19.4,8.6和5.6 nm的纳米晶锐钛矿相TiO2,进行了从83到723 K的变温拉曼散射测量,并对Eg(1)模式进行了详细研究.根据非简谐效应和声子局域模型,对Eg(1)拉曼峰进行了拟合与计算.结果表明,以上三种纳米晶粒的晶格振动机理,在本质上是相同的.三声子过程对频率蓝移起主要作用.为了得到很好的拟合,需要同时考虑三声子和四声子过程.随着温度的升高,四声子过程增强,并对三声子过程起抵消作用.与非简谐衰减相关的声子寿命随着晶粒尺寸的减小而增加,晶粒尺寸越小衰减越慢.在低温区,声子局域是导致5.6 nm晶粒的声子寿命非常短的原因.声子局域引起Eg(1)模式在高波数段非对称展宽和频率蓝移,其对Eg(1)峰展宽的影响要大于对峰位移动的影响.     

171Ta高自旋态能级寿命测量

在中国原子能科学研究院的HI 13串列加速器上通过157Gd(19F,5n)171Ta重离子熔合蒸发反应布居了171Ta的高自旋态,以多普勒移动衰减法的峰形分析法分析了171Tah9/2质子1/2[541]转动带的6条能级的寿命,得到了这6条能级的平均寿命值. The high spin states of~(171)Ta have been populated via heavy ion fusion evaporation reaction~(157)Gd(~(19)F, 5n)~(171)Ta at the HI-13 tandem accelerator in China Institute of Atomic Energy. The lifetimes of the high spin states in~(171)Ta have been measured by using the Doppler Shift Attenuation Method (DSAM). Six levels of its h_(9/2) proton 1/2\ band have been analyzed and their lifetimes have been deduced from the experimental data.     

Thin－Film Enhanced Goos－Haenchen Shift in Total Internal Reflection

It is reported that the Goos-Haenchen (GH) shift of both TE and TM light beams totally reflected from a dielectric interface can be greatly enhanced by a dielectric thin film without changing the property of total internal reflection.Numerical simulations confirm the theoretical analysis and show that the enhanced GH shift can be as large as the width of the beam for beam‘s width up to 820 times of the wavelength. This may stimulate investigations in other areas of physics and may lead to interesting applications in optical devices. The enhancement of the GH shift is accompanied by the enhancement of the intensity of the decaying field in the optically thin medium and of the propagating field inside the film.     

Pseudo-Spin Model for the Cytoskeletal Microtubule Surface

Due to the inherent symmetry structures and the electric properties in the microtubule (MT), we treat the MT as a one-dimensional ferroelectric system and describe the nonlinear dynamics of dimer electric dipoles in one protofilament of the MT by virtue of the double-well potential. Consequently, the physical problem has been mapped onto the pseudo-spin system, and the mean-field approximation has been taken to obtain some physical results, including the expression for the phase transition temperature Tc and the estimated value of Tc (=312 K).     

Compensation for Self-Focusing of Picosecond Pulses in Nd：Glass by Using Cascaded Quadratic Nonlinearity

One of the obstacles in obtaining high power/energy laser sources is self-focusing, which stems from the nonlinear phase shift (B-integral) accumulated during beam propagation in Kerr media. Phase-mismatched secondharmonic generation may impose a nonlinear phase shift on the fundamental with controllable sign and magnitude,which can be used to compensate for self-focusing with a single-pass configuration. We have demonstrated such a possibility for picosecond pulses theoretically and experimentally, and both configurations of pre- and postcompensation by a β-barium borate crystal have been studied in detail. Cascaded second-order nonlinearity-based compensation for self-focusing may provide an auxiliary means to the conventional B-integral control techniques.     

InxGa1-xN薄膜的弯曲因子及斯托克斯移动研究

采用常压金属有机化学汽相沉积(MOCVD)技术以Al2O3为衬底在GaN膜上生长了InxGa1-xN薄膜。以卢瑟福背散射／沟道技术、光透射谱、光致发光光谱对InxGa1-xN／GaN／AI2O3样品进行了测试。研究了InxGa1-xN薄膜的弯曲因子及斯托克斯移动。结果表明，采用光透射谱、光致发光光谱得到的InxGa1-xN薄膜的禁带宽度一致，InxGa1-xN薄膜并不存在斯托克斯移动。InxGa1-xN薄膜的In组分分别为0．04，0．06，0．24，0．26时，其弯曲因子分别为3．40,2．36，1．82，3．70。随In组分变化。InxGa1-xN薄膜的弯曲因子的变化并没有一定的规律，表明InxGa1-xN薄膜的禁带宽度随In组分的变化关系复杂。     

地球磁场的物理问题

地磁学的发展经历了两千多年的历史，文章回顾了这一漫长历史的四个主要阶段，对每一阶段研究的基本物理问题和主要进展做了简要概述．地磁场的空间分布、地磁场起源、地磁场长期变化和西向漂移、磁极移动和极性倒转、地磁场与人类生存环境等，是地磁学的基本物理问题．文章还从物理概念、研究现状和地磁学以及相关学科当前存在的问题等几个方面对地磁学未来的发展趋势做了简要的说明．     

三维无网格法中权函数影响半径的优化

从函数逼近的角度建立三维无网格法中权函数影响半径的优化计算模型,针对一次基、二次基情形求解该模型.分析不同影响半径下函数的逼近误差,以及计算量、条件数等因素对无网格法计算性能的影响,结合数值试验,确认给出的权函数影响半径是有效、可靠、综合最优的.