α,α''-二氧代烯酮环二硫代缩酮类化合物的谱学研究

研究了5种含有苯环取代基的α, α'-二氧代烯酮环二硫代缩酮类化合物的红外光谱的特征吸收规律, 指出了这类化合物分子结构对红外吸收谱带的影响; 对1H NMR, 13C NMR共振谱带做了全面的归属, 并且讨论了分子结构对1H NMR, 13C NMR共振谱带化学位移的影响, 其变化规律与红外光谱一致, 为这类化合物的结构及谱学研究提供了启发性的模式.     

静磁场中的互作用能

讨论了在激发磁场的电流保持不变时和束缚磁荷作为磁场的不变时，两种情况下磁场的相互作用能。结果与静电场类似，两种情况的互作用能中都含有相互磁化，致使物体磁化状态改变作的功。     

论恒力作用下质点的相对论运动

在相对论情况下，讨论了受恒力作用的质点的运动规律。     

对于“功”定义中的一点看法

垂直射人匀强磁场中的带电粒子，在洛伦兹力F=qvB的作用下，将会偏离原来的运动方向．那么，粒子的运动轨迹是怎样的呢？     

质量起源——量子色动力学与质量起源

 ……有读者可能会问：我们是不是离题了？既然量子色动力学中的胶子是无质量的，而夸克虽然有质量，但其质量是不可约化的。那么，量子色动力学与质量起源这一主题又能有什么关系呢？应该说，这是一个很合理的疑问。但量子色动力学的奇妙之处就在于，它形式上异常简洁，内涵却惊人地丰富。它宛如一坛绝世的佳酿，越品就越是回味无穷。在谈论质量起源问题的时侯，人们往往把注意力放在包含希格斯机制的电弱统一理论上，因为希格斯机制在登场伊始就打出了质量产生机制的响亮广告。但事实上我们将会看到，看似与质量起源问题无关的量子色动力学对这一问题有着非常独特而精彩的回答，从某种意义上讲，这一回答才是标准模型范围内的最佳回答。……     

Raman and X-Ray Investigation of Pyrope Garnet （Mg0.76Fe0.14Ca0.10）3Al2Si3O12 under High Pressure

The compressional behavlour of natural pyrope garnet is investigated by using angle-dlspersive synchrotron radiation x-ray diffraction and Raman spectroscopy in a diamond anvil cell at room temperature. The pressureinduced phase transition does not occur under given pressure. The equation of state of pyrope garnet is determined under pressure up to 25.3 GPa. The bulk modulus KTO is 199 GPa, with its first pressure derivative K′TO fixed to 4. The Raman spectra of pyrope garnet are studied. A new Raman peak nearly at 743 cm^-1 is observed in a bending vibration of the SiO4 tetrahedra frequency range at pressure of about 28 GPa. We suggest that the new Raman peak results from the lattice distortion of the SiO4 tetrahedra. All the Raman frequencies continuously increase with the increasing pressure. The average pressure derivative of the high frequency modes （650-1000 cm^-1） is larger than that of the low frequency （smaller than 650 cm^-1）. Based on these data, the mode Grǖneisen parameters for pyrope are obtained.     

Remarks on Exactly Solvable Noncommutative Quantum Field

We study exactly the solvable noncommutative scalar quantum field models of （2n） or （2n ＋ 1） dimensions. By writing out an equivalent action of the noncommutative field, it is shown that the special condition B. 0 = 4-1 in field theoretic context means the full restoration of the maximal U（∞） gauge symmetries broken due to kinetic term. It is further shown that the model can be obtained by dimensional reduction of a 2n-dimensional exactly solvable noncommutative φ4 quantum field model closely related to the 1＋1-dimensional Moyal/matrix-valued nonlinear Schr6dinger （MNLS） equation. The corresponding quantum fundamental commutation relation of the MNLS model is also given explicitly.     

Stable Electron Field Emission from CeO2 Nanowires by Hydrothermal Method

CeO2 nanowires are successful synthesized by hydrothermal method and their field emission （FE） properties are investigated. The turn-on electric field is 5.8 V/μm at an emitter-anode spacing of 700μm. The FE current is stable and the current fluctuations are less than 3% over 5 h. All the plotted Fowler-Nordheim curves yield straight lines, which are in agreement with the Fowler-Nordheim theory. The relationship between the field enhancement factor β and the emitter-anode spacing d follows a universal equation. Our results imply that the CeO2 nanowires are promising materials for fabricating FE cathodes.     

ReSi1.75电子结构的第一性原理研究

基于第一性原理全势线性缀加平面波方法和局域密度近似(LDA),对ReSi1.75的基态晶格属性进行了研究.结构优化的结果表明,ReSi1.75的基态平衡晶格常数比实验值小约0.6%.在LDA计算基础上,考虑局域的Re的d电子库仑作用,用LDA+U方法计算了ReSi1.75的电子结构,发现当Ueff=U-J=4.4 eV时,能带结构呈半导体性质.具有0.12 ev的间接能隙和0.36 ev的直接能隙.有效质量计算结果表明,ReSi1.75晶体具有强烈的各向异性.Resi1.75的态密度在费米能级附近变化剧烈,通过掺杂改变材料的费米能级位置,有望提高材料的热电性能.     

Rapid Fabrication of Three-Dimensional Woodpile Photonic Crystals by Means of Two-Photon Photopolymerization

Two-photon photopolymerization （TPP） of femtosecond laser is a promising method to fabricate three-dimensional woodpile photonic crystals （PCs）. We build micro-fabricatlon system based on the principle of TPP. Three- dimensional woodpile PCs consisting of in-plane rod distances ranging from 1000nm to 2000nm are fabricated by focusing femtosecond laser in photosensitive liquid resin ORMOCER. The properties of the PCs are also discussed, and fundamental photonic band gaps in middle-infrared range are measured, whose in-plane rod distances are 1500nm and 2000 nm. Three-dimenslonal woodpile PC devices with desired defects, such as cross-waveguide and micro-laser structures, are introduced easily by TPP. We fabricate the three-dimensional woodpile PCs in the liquid resin at the fast scanning speed of 120μm/s.