N_(235)萃取HCl体系中TBP消除第三相的作用机理

通过测定萃取有机相的电导率变化研究叔胺N235(三烷基胺)萃取盐酸体系中第三相的形成及改性剂消除第三相的作用机理。实验结果表明,无改性剂时萃取体系在各种条件下均出现第三相。第三相组成为R3NH (H2O)3·Cl-,具有导电性。加改性剂TBP(磷酸三丁酯)后,第三相消失。本文认为改性剂TBP消除第三相的作用机理是TBP能够将萃合物R3NH (H2O)3·Cl-拆分为可溶于惰性稀释剂的R3NH (H2O)3·O=P(OC4H9)3大阳离子,Cl-离子则以抗衡离子分散于稀释剂中。     

Simulation of Electroosmotic and Pressure-Driven Mixed Flow of Viscoelastic Fluids in Converging-Diverging Tubes北大核心CSCD

The electroosmotic and pressure⁃driven mixed flow was widely used in various biochemical microflu⁃ idic fields, where the elastic instability of the viscoelastic fluid cannot be ignored. A viscoelastic fluid was used to numerically simulate electroosmotic and pressure⁃driven mixed flow in a 10 ∶ 1 ∶ 10 microchannel converging⁃ diverging tube. The effects of different pressures and different polymer concentrations on the fluid flow were studied, and the superposition principle for the velocity distributions of Newtonian fluids and viscoelastic fluids in converging⁃diverging tubes was analyzed. The results show that, the reverse pressure brings the viscoelastic fluid into higher instability, which makes the inlet vortex larger by 25 μm for every 1 Pa pressure increase. The positive pressure makes the eddy current smaller. For a relatively small reverse pressure, the inlet vortex in⁃ creases with the polymer concentration and tends to be stable gradually. For a relatively large reverse pressure, the vortex size first increases and then decreases with the polymer concentration. © 2023 Editorial Office of Applied Mathematics and Mechanics. All rights reserved.