基于LIBS及时间分辨特征峰的激光除漆机理研究

激光除漆是一种高效、清洁的新型清洗技术,对激光除漆物理过程和机理的研究是该技术发展的关键。基于LIBS技术,测量得到油漆去除过程中等离子体的发光光谱,计算出油漆样品去除前后等离子体的电子密度和温度,研究了油漆中特征元素对应的光谱特征峰强度随时间的变化情况。结果表明,随着激光作用脉冲数量的增加,油漆去除深度逐渐增加,等离子体电子密度和温度在将漆去除干净的最后几个脉冲作用时呈下降趋势。油漆中Ti元素的所对应的特征峰信号持续时间为2个μs,油漆去除前后信号强度呈现跳跃减少,该现象可用于快速、准确、实时的判断油漆去除情况。     

环戊烯分子内价轨道1a′的电子动量谱学研究

报道了环戊烯（C₅H₈）分子1a′轨道的电子动量谱，并且给出了价 轨道的电离能谱信息 .实验在非共面对称几何条件下用能量多道型电子动量谱仪完成，入射电子的能量为1200 eV 加结合能.通过Hartree-Fock 和密度泛函方法计算得到了C₅H₈分子 1a′轨道的动量谱. 对1a′轨道的电子动量谱的实验值和理论计算进行了比较，得到了该轨道的极强度（pole s trength）的信息.     

Heat Transport of Electron-Doped Cobaltates

Within the t-J model, the heat transport of electron-doped cobaltates is studied based on the fermionspin theory. It is shown that the temperature-dependent thermal conductivity is characterized by the low-temperature peak located at a finite temperature. The thermal conductivity increases monotonously with increasing temperature at low-temperatures T 〈 0.1 J, and then decreases with increasing temperature for higher temperatures T 〉 0.1 J, in qualitative agreement with experimental result observed from NaxCoO2.     

两种铽配合物与PVK混合体系的发光机理研究

研究了稀土配合物Tb(p-MBA)₃phen(样品Ⅰ)和Tb(p-ClBA)₃phen(样品Ⅱ)与导电聚合物材料PVK掺杂体系的光致发光和电致发光特性。发现在样品Ⅰ与PVK混合薄膜的光致发光中,除了三价铽离子的发光外,还能看到明显的PVK的发光;而在电致发光中,PVK的发光完全被抑制,只能看到Tb3+的绿光发射。对样品Ⅱ与PVK的混合发光层,无论其光致发光谱还是电致发光谱,都没有看到410 nm处PVK的发射。进一步测量两种材料的激发光谱,初步探讨了器件的发光机理。样品Ⅰ的发光可能来源于两个方面,一是PVK到稀土配合物的不完全的能量传递,二是由于载流子俘获机理;样品Ⅱ的发光则是由于PVK到稀土配合物的完全的能量传递。     

Raman spectrum study of graphite irradiated by swift heavy ions

Highly oriented pyrolytic graphites are irradiated with 40.5-Me V and 67.7-Me V ^112Sn-ions in a wide range of fluences： 1×10^11 ions/cm^2–1×10^14ions/cm^2. Raman spectra in the region between 1200 cm^-1 and 3500cm^-1 show that the disorder induced by Sn-ions increases with ion fluence increasing. However, for the same fluence, the amount of disorder is greater for 40.5-Me V Sn-ions than that observed for 67.7-Me V Sn-ions, even though the latter has a slightly higher value for electronic energy loss. This is explained by the ion velocity effect. Importantly, ～ 3-cm^-1frequency shift toward lower wavenumber for the D band and ～ 6-cm^-1 shift toward lower wavenumber for the 2D band are observed at a fluence of 1×10^14 ions/cm^2, which is consistent with the scenario of radiation-induced strain. The strain formation is interpreted in the context of inelastic thermal spike model, and the change of the 2D band shape at high ion fluence is explained by the accumulation of stacking faults of the graphene layers activated by radiation-induced strain around ion tracks. Moreover,the hexagonal structure around the ion tracks is observed by scanning tunneling microscopy, which confirms that the strains near the ion tracks locally cause electronic decoupling of neighboring graphene layers.     

二氧化钒强关联固体的三相点

<正>在强关联材料中,电子—电子,电子—晶格的相互作用可导致各种电子相、磁相以及结构相之间的竞争。研究在这些竞争相之间的相变,往往可以揭示出用其他方法难以获得的有关基础量子态的信息。最近,来自美国华盛顿大学的Park等在Nature周刊上撰文,报道了他们使用微机械设备和纳米单晶束所完成的实验:在二氧化钒     

用"删除法则"求3个同科电子的光谱项

提出了3个同科电子体系在L-S耦合中确定光谱项的“删除法则”,并加以证明．利用“删除法则”可以很方便地求出3个同科电子所形成的光谱项．     

对“微波共振跃迁法测量电子偶素2~3S_1-2~3P_1精细结构”实验拟合公式的探讨

本文对Michigan大学S.Hatamian等人在“微波共振跃迁法测量电子偶素2~3S_1-2~3P_J精细结构”实验中所用拟合公式进行了审慎的分析和推证,修正了该公式的功率增宽项,并就Mainz大学R.Ley等人对该公式的批评作了评价。最后,采用新、旧拟合公式对Michigan组实验数据进行拟合并讨论其结果。     

HL—1装置汤姆逊散射测量空间两点电子温度

本文叙述用激光汤姆逊散射方法测量HL-1装置在不同放电条件下空间两点的电子温度。简要介绍了测量条件,空间两点测量的实验安排及数据获取系统等。对实验结果进行了初步分析。在适当改变等离子体边缘径向电场分布时,电子温度有明显增加。