微型流化床-快速过程红外热分析仪对CaCO_3热分解的动力学研究

本文使用程序升温热重分析仪和自主开发的微型流化床(MFB)一快速过程红外(IR)热分析仪进行CaCO_3热分解动力学的实验研究。通过MFB-IR系统实验获得的碳酸钙分解活化能为107.7 kJ/mol,处于文献报道的范围之内;反应动力学模型符合形核与成长(n=2/3)模型。当转化率小于30%时,通过MFB-IR系统获得的CaCO_3分解活化能与热重较一致,但在转化率大于30%情况下,MFB-IR中获得的分解活化能随转化率的变化比热重分析所得活化能变化明显。同时,其活化能数值小于通过热重分析仪实验获得的数值。     

超临界水流化床内煤气化过程建模与仿真(2):气化反应动力学模型及气化规律

本文成功建立了煤超临界水气化动力学模型,其中包括煤在超临界水中热解、液化、固相残碳及液化产物的蒸汽重整等均相和非相反应。该动力学模型能准确反应煤在超临界水中气化特征。在前述第一部分工作的基础上,耦合该气化动力学模型,对煤在超临界水流化床中气化过程进行了建模。通过该模型研究了宽温度参数范围下反应器内典型反应速率、反应组分分布演变规律,揭示了反应器内部化学反应特征与气化规律。研究加深了对超临界水流化床内煤气化过程的认识,对超临界水流化床反应器的优化、放大以及实际运行具有指导意义。     

Double Diffractive Process Factorization from ηc and γ Associated Production at Tevatron and LHC

We present a study of associated ηc and γ double diffractive production in pp^- collision based on Ingelman-Schlein model, and the framework of non-relativistic QOD factorization formalism for quarkonia production. The prediction of ηc and γ is more reliable than J/ψ production, because the associated ηc and γ production is a pure color-octet process, and the dominant contribution comes from color octet ^1S0^(8) subprocess, which is related to the color octet matrix element of ^1S0(8) of J/ψ by the heavy quark spin symmetry and the large PT J/ψ production data. We find that the ratio of diffractive to inclusive cross sections is independent of the values of color octet matrix elements, but is sensitive to the gluon factor of the Pomeron and renormalized Pomeron flux factors. So experimental measurement of this ratio can give us more information of the nature of Pomeron and test the assumption of hard diffractive factorization in hadron-hadron collisions.     

Asymmetric Superradiant Scattering Patterns from Bose--Einstein Condensates

The asymmetric patterns of superradiance from Bose-Einstein condensates are studied for the spatially inhomogeneous pump pulse with the semiclassical Maxwell-Schrodinger equations. The coupling dynamics between the optical field and condensate in the strong pulse and a faded wing in the weak coupling regime are discussed, which not only explain the spatial effects in the process of superradiance, but also supply a new method to control its patterns.     

Difference of Directions Between External Driving Force and Movement Direction of Center of Mass

Driven dynamics of a two-dimensional Frenkel-Kontorova model is studied in the paper. In our numerical simulations, it is found that the movement direction of the center of mass is not consistent with that of the external driving force except for some special symmetric directions at the lower driving force. Our results also indicate that the movement direction of the center of mass strongly depends on both the magnitude and the direction of the external driving force as well as the misfit angle between two layers.     

Electronic,Vibrational, and Superconducting Properties of High-Pressure Metallic SiH4： ab initio Calculations

We extensively explore the experimentally proposed metallic structure of hcp P63 for the hydrogen rich compound, SiH4. It is found that the lattice dynamic of this structure is severely unstable. By freezing the soften mode, an orthorhombic Pbcn structure is discovered to be dynamically stable up to 226GPa. Within the conventional BCS theory, the calculated critical temperature Tc within the proposed Pbcn structure is 16.5K at 188GPa, in good agreement with the experimental result （17.5K）. Thus, we propose that the current predicted orthorhombic phase is a better candidate for the metallic phase of SiH4.     

夸克物质中的色超导性理论简介(英文)

夸克-夸克通过单胶子交换的相互作用在其反对称态上是相互吸引的,在致密夸克物质里,这种吸引相互作用会导致费米面上的双夸克凝聚,这就是所谓的夸克配对或色超导现象。本文介绍了夸克配对或色超导现象的基本知识和一些新进展。色超导是一个对称性自发破坏现象,有非常丰富的破缺方式,我们介绍了色超导对称性及其自发破坏模式的分析方法,介绍了怎样计算色超导体两个最基本的变量:能隙和迈斯纳质量。然后我们介绍了描述色超导现象的有效理论。最后是这些理论的一个应用,即计算色超导体里的中微子发射率以及其它输运性质。本文可以作为研究夸克物质理论的入门参考资料。     

Differential Representations of SO（4） Dynamical Group

In this paper we present systematic differential representations for the dynamical group SO（4）. These representations include the left and the right differential representations and the left and the right adjoint differential representations in both the group parameter space and its coset spaces. They are the generalization of the differential representations of the SO（3） rotation group in the Euler angles. These representations may find their applications in the study of the physical systems with SO（4） dynamical symmetry.     

Rate Constants for Reaction Between Hydroxyl Radical and Dimethyl Sulfide Under Real Atmospheric Condition

用相对速率方法分别考察了OH自由基与DMS在氮气、空气和氧气体系的反应速率常数. 发现使用HONO和CH3ONO作为OH自由基发生剂时,基态氧原子O(3P)对动力学的测定有很大的影响. H2O2为OH自由基的发生剂,室温下在氮气、空气及氧气体系下的速率常数分别为4.50×10-12,8.56×10-12和11.31×10-12 cm3/(molecule?s).在287～338 K,测得氮气和空气体系下的阿累尼乌斯表达式分别为:kair=(7.24±0.28)×10-13exp[(770.7±97.2)/T],kN2=(3.40±0.15)×10-11exp[-(590.3±165.9)/T     

应用具有手征流关联函数的光锥求和规则计算B(Bc)→Dlν过程的形状因子

在QCD光锥求和规则(LCSR)框架内应用具有手征流关联函数计算B(B_c)→Dlν衰变过程的弱形状因子. 所获得的形状因子的表达式仅依赖于D介子的主导级分布振幅(DA). 应用了三类D介子的分布振幅计算了形状因子F_B→D(0)和F_Bc→D(0). 在速度迁移1.142=0附近算符乘积展开(OPE)得以有效的情况下所计算的形状因子行为在误差范围内与B(B_c)→Dlν过程实验数据相一致. 在大反冲区域1.35B→D(0)是与微扰QCD(pQCD)结果相一致的. 所以本文的计算在联接格点QCD, 重夸克对称性和pQCD之间起桥梁作用，有助于进一步对B(B_c)→Dlν跃迁过程的理解. 计算 使用了在端点具有指数压低的分布振幅行为, 对F_Bc→D(0)的预言与其他方法获得的结果是可比的, 有利于具有库仑修正的三点求和规则(3PSR)方法所得的结果.