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281.
利用差示扫描量热仪研究了5种高浓度丙三醇水溶液(60%、70%、80%、90%、100%)的玻璃化转变行为,以考察水分含量和升降温速率对其玻璃化转变行为和结构松弛参数的影响.采用4种线性升降温速率(10、15、20、25K/min)获得玻璃化转变的相关参数.利用GordonTaylor方程对玻璃化转变温度的分析结果表明,水对丙三醇增塑常数的计算结果与升降温速率和玻璃化转变温度的读取方法有很大关系.玻璃化转变过程的比热容变化不仅随水分含量的增加而增加,而且与升降温速率也有一定的依赖关系.结构松弛活化能的计算结果表明,随体系水分含量的增加,体系的结构松弛活化能和动力学脆度都逐渐降低.随水分含量的变化,热力学脆度和动力学脆度表现出相反的变化趋势. 相似文献
282.
The ferrimagnetism and quantum phase transition of a bipartite lozenge periodic Anderson-like organic polymer, in which the localized f electrons hybridize with the odd site conduction orbitals, are investigated by means of Green's function theory. The ground state turns out to be gapless ferrimagnetism. At a finite temperature, the ferrimagnetic-to- paramagnetic phase transition takes place. The Kondo screenings and Ruderman-Kittel-Kasuya-Yosida (RKKY) inter- action can reduce and increase the transition temperature, respectively. Two Kondo screenings compete with each other, giving rise to the localized f electron spin screened antiferromagnetically. Accordingly, in a magnetic field, all spins are aligned along the chain easily, which is associated with metal-insulator transition. Furthermore, in a temperature-field plane, we reveal the gapless and spin polarized phases, which are characterized by susceptibility and specific heat, and whose behaviours are determined by the competition between the up-spin and down-spin hole excitations. 相似文献
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284.
Double perovskite manganite Y2MnCrO6 ceramic Novel multiferroic properties are displayed with respect is synthesized and its multiferroic properties are investigated. to other multiferroics, such as high ferroelectric phase transi- tion temperature, and the coexistence of ferrimagnetism and ferroelectricity. Moreover, the ferroelectric polarization of Y2MnCrO6 below the magnetic phase temperature can be effectively tuned by an external magnetic field, showing a re- markable magnetoelectric effect. These results open an effective avenue to explore magnetic multiferroics with spontaneous magnetization and ferroelectricity, as well as a high ferroelectric transition temperature. 相似文献
285.
Investigation of the free volume and ionic conducting mechanism of poly(ethylene oxide)-LiClO_4 polymeric electrolyte by positron annihilating lifetime spectroscopy 下载免费PDF全文
The positron annihilation lifetime and ionic conductivity are each measured as a function of organophilic rectorite(OREC) content and temperature in a range from 160 K to 300 K.According to the variation of ortho-positronium(o-Ps) lifetime with temperature,the glassy transition temperature is determined.The continuous maximum entropy lifetime(MELT) analysis clearly shows that the OREC and temperature have important effects on o-Ps lifetime and free volume distribution.The experimental results show that the temperature dependence of ionic conductivity obeys the Vogel-Tammann-Fulcher(VTF) and Williams-Landel-Ferry(WLF) equations,implying a free-volume transport mechanism.A linear least-squares procedure is used to evaluate the apparent activation energy related to the ionic transport in the VTF equation and several important parameters in the WLF equation.It is worthwhile to notice that a direct linear relationship between the ionic conductivity and free volume fraction is established using the WLF equation based on the free volume theory for nanocomposite electrolyte,which indicates that the segmental chain migration and ionic migration and diffusion could be explained by the free volume theory. 相似文献
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287.
在研究BiSrCaCuO超导单晶的过程中,我们发现材料的实际化学组分与理想的2212相配比组分有着一定的差别,正是这种成分偏析造成了样品的Tc与结构的不同。本文研究了在压力下不同Tc的样品随压力改变Tc的变化关系,发现偏析越大、Tc越低的样品的dTc/dp也越大,而越接近理想组分,则dTc/dp越趋于最小值,还可以从此推断出BiSrCaCuO理想单晶材料的Tc最佳值。压力对超导电性的这种影响可能与耦合链长的变化有关。 相似文献
288.
Magnetic properties and magnetocaloric effects in NaZn13-type La(Fe, Al)13-based compounds 下载免费PDF全文
In this article,our recent progress concerning the effects of atomic substitution,magnetic field,and temperature on the magnetic and magnetocaloric properties of the LaFe13-xAlx compounds are reviewed.With an increase of the aluminum content,the compounds exhibit successively an antiferromagnetic(AFM) state,a ferromagnetic(FM) state,and a mictomagnetic state.Furthermore,the AFM coupling of LaFe 13-xAlx can be converted to an FM one by substituting Si for Al,Co for Fe,and magnetic rare-earth R for La,or introducing interstitial C or H atoms.However,low doping levels lead to FM clusters embedded in an AFM matrix,and the resultant compounds can undergo,under appropriate applied fields,first an AFM-FM and then an FM-AFM phase transition while heated,with significant magnetic relaxation in the vicinity of the transition temperature.The Curie temperature of LaFe13-xAlx can be shifted to room temperature by choosing appropriate contents of Co,C,or H,and a strong magnetocaloric effect can be obtained around the transition temperature.For example,for the LaFe 11.5Al1.5C0.2H1.0 compound,the maximal entropy change reaches 13.8 J·kg-1 ·K-1 for a field change of 0-5 T,occurring around room temperature.It is 42% higher than that of Gd,and therefore,this compound is a promising room-temperature magnetic refrigerant. 相似文献
289.
为了解玻璃化过程氢键结构特性,采用分子模拟的手段计算了三种压力下的水玻璃化过程氢键的角度、距离、生命期和数量.计算结果显示:(i)氢键角度呈现泊松分布的特征,随着温度降低分布氢键角度分布范围变窄,峰值变高,在0~13°范围,随温度降低,分布数值变大;而在大于13°,随温度降低,分布数值变小;(ii)氢键距离也呈现泊松分... 相似文献
290.