电化学电容器中二氧化锰电极材料研究进展

本文在简介MnO2电极材料的性质和特点基础上,重点介绍近5年来国内外有关MnO2电极材料在合成及电化学电容器应用领域中的最新进展,及未来可能的发展方向。     

超级电容器用聚吡咯纳米粒子的比容量衰减机理研究

基于化学氧化聚合法制备了粒径约为40nm的掺杂对甲苯磺酸(TSA)的聚吡咯(PPy)复合纳米粒子.采用XRD、EDS、SEM和TEM研究了产物的结构和形貌特征,并用循环伏安、恒流充放电等方法测试了纳米粒子的电化学性能.结果表明PPy/TSA具有良好的快速充放电能力,在10 mA/cm2时比容量达到268Fg-1,但在1000次循环后发现其比容量下降了25.5%.用CV测试了PPy/TSA电极在第一次循环和第1000次循环的伏安曲线图,发现经过1000次循环后PPy/TSA电极的氧化峰逐渐消失,并且非法拉第电流减小.交流阻抗测试表明,PPy/TSA纳米粒子在反复充放电循环后,其界面电荷传递电阻增加,高频段双层电容值降低,但低频段的赝电容值却有所增加.通过比表面积测量发现,聚合物链的反复氧化-还原过程还可导致平均孔径减小、比表面积下降.红外和拉曼光谱也证实PPy纳米粒子在充放电过程中会发生降解,生成一种含氧的醌式结构,这表明聚合物电极材料比容量的下降可能与PPy主链的不可逆氧化和结构碎片化有关.     

一种新型有机硅离子液体电解液在超级电容中的应用

设计合成了一种新型有机硅室温离子液体(SiN1IL), 并对其化学结构和电化学窗口进行表征, 通过与具有高介电常数的丙烯碳酸酯(PC)/低粘度的乙腈(AN)匹配组成电解液, 其离子电导率达到商业实际应用的要求(19.6 mS·cm^-1). 对以活性炭(AC)为对称电极的超级电容器的电化学性能测试表明, SiN1IL 基电解液与活性炭有很好的界面相容性, 其高倍率充放电、阻抗性能优于商用四乙基四氟硼酸铵(Et₄NBF₄)/PC 电解液, 在电流密度为1000 mA·g^-1的条件下, 工作电压为2.7 V, 其比电容为108 F·g^-1.     

电弧放电法制备石墨烯的硝酸改性及其电化学性能增强

采用电弧放电法大规模制备了层数少, 导电率高, 结晶性好的石墨烯纳米片(GNSs). 通过扫描电镜(SEM)和透射电镜(TEM)表征发现制得的石墨烯形貌良好. 然而电化学测试表明GNSs作为电极材料的电容性能不好. 为了增加材料表面电化学反应活性点, 促进GNSs在水系电解液中的润湿性, 我们对所制备的GNSs表面进行了硝酸改性处理. 结果显示硝酸处理后的石墨烯纳米片(H-GNSs)表面新增了较多的含氧氮官能团,其亲水性得到了显著提高. 对H-GNSs的电化学研究表明: 硝酸改性处理后的GNSs在2 mol·L^-1 KOH溶液中电流密度为0.5 A·g^-1时, 比电容可达65.5 F·g^-1, 约为改性前的30 倍; 此外, H-GNSs作为电极材料连续进行2000次充放电测试后还展示出了良好的循环稳定性, 是一种潜在的超级电容器电极材料.     

股价遵循分数跳扩散的混合型双标的两值期权定价

应用风险中性定价原理,研究标的股价服从分数跳扩散过程的混合型双标的两值期权的定价问题,并得出定价公式,并与股价服从标准布朗运动的定价公式做出比较分析.     

Generalized Frankl-Rassias Mixed Type Equations in an Problem for a Class of Infinite Domain

In this paper, we study the boundary-value problem for mixed type equation with singular coefficient. We prove the unique solvability of the mentioned problem with the help of the extremum principle. The proof of the existence is based on the theory of singular integral equations, Wiener-Hopf equations and Fredholm integral equations.     

热-机载荷下不规则夹杂的奇异性应力场分析

基于有限元特征分析法得到的夹杂角部场数值特征解开发了一种超级奇异单元模型,并将其与普通四节点单元紧密结合,用于热-机载荷下夹杂角端部的应力场分析。在数值计算中,考察了热-机载荷下不同弹性比和不同夹杂尺寸的应力强度因子,并将所得结果与文献解和传统有限元方法解比对。结果表明,本文方法对热-机耦合条件下的不规则夹杂角端部的热弹性应力分析极为有效,可避免局部网格的高度加密,并提高计算效率。模型在复合材料夹杂的局部强度问题分析方面具有很好的实用性。     

Microwave-hydrothermal preparation of a graphene/hierarchy structure MnO2 composite for a supercapacitor

Graphene/hierarchy structure manganese dioxide （GN/MnO2） composites were synthesized using a simple microwave-hydrothermal method. The properties of the prepared composites were analyzed using field emission scanning electron microscopy （FE-SEM）, X-ray diffraction （XRD）, transmission electron microscopy （TEM）, and X-ray photoelectron spectroscopy （XPS） measurements. The electrochemical performances of the composites were analyzed using cyclic voltammetry, electrochemical impedance spectrometry （EIS）, and chronopotentiometry. The results showed that GN/MnO2 （10 wt% graphene） displayed a specific capacitance of 244 F/g at a current density of 100 mA/g. An excellent cyclic stability was obtained with a capacity retention of approximately 94.3% after 500 cycles in a 1 mol/L Li2SO4 solution. The improved electrochemical performance is attributed to the hierarchy structure of the manganese dioxide, which can enlarge the interface between the active materials and the electrolyte. The prepa- ration route provides a new approach for hierarchy structure graphene composites; this work could be readily extended to the preparation of other graphene-based composites with different structures for use in energy storage devices.     

Super cyclically edge-connected vertex-transitive graphs of girth at least 5

A cyclic edge-cut of a graph G is an edge set, the removal of which separates two cycles. If G has a cyclic edge-cut, then it is called cyclically separable. We call a cyclically separable graph super cyclically edge-connected, in short, super-λc, if the removal of any minimum cyclic edge-cut results in a component which is a shortest cycle. In [Zhang, Z., Wang, B.: Super cyclically edge-connected transitive graphs. J. Combin. Optim., 22, 549-562 (2011)], it is proved that a connected vertex-transitive graph is super-λc if G has minimum degree at least 4 and girth at least 6, and the authors also presented a class of nonsuper-λc graphs which have degree 4 and girth 5. In this paper, a characterization of k (k≥4)-regular vertex-transitive nonsuper-λc graphs of girth 5 is given. Using this, we classify all k (k≥4)-regular nonsuper-λc Cayley graphs of girth 5, and construct the first infinite family of nonsuper-λc vertex-transitive non-Cayley graphs.