Synthesis of new 2-aryl-6-styryl-2,3-dihydropyridin-4(1H)-one derivatives from curcuminoids

Series of new 2-aryl-6-styryl-2,3-dihydropyridin-4(1H)-one derivatives were synthesized in acceptable to good yields by treatment of the curcuminoids with aqueous ammonia,the mechanism was proposed.By modification of the primary products,total 13 new compounds were obtained.The structures of all products were elucidated by spectroscopy analysis including HR-MS,~1H NMR and ~(13)C NMR.     

不对称(口片)呐醇偶联反应新进展

综述了近年来不同催化体系的不对称合成呐醇的方法,并总结了不同的催化效率和对映选择性的差异.     

高效液相色谱-大气压化学电离质谱联用分析天然(口山)酮甙类化合物

利用高效液相色谱大气压化学电离质谱联用技术,探讨了酮单糖甙和酮双糖甙在负离子模式下的质谱断裂特点,比较相同条件下不同酮甙的质谱图,借助[Y0-1]-.和Y0-离子的相对丰度关系探讨了糖基的性质对断裂规律的影响。同时借助[Y0-1]-.、Y1-及Z1-离子的丰度实现对双糖基为1→2与1→6连接的酮双糖甙的区分。     

一类新型环金属配体——(口恶)二唑衍生物的化学结构及其性能

合成了5个2,5-二芳基-1,3,4-(口恶)二唑衍生物环金属配合物配体,其化学结构经1H NMR、IR和元素分析得到确证. 利用紫外光谱、荧光光谱、差热分析(DSC)和循环伏安法测试技术分别研究了它们的光谱性能、热性能和电化学性能. 结果表明,该类衍生物在二氯甲烷溶液中的最大紫外吸收波长在268～327 nm范围,在二氯甲烷溶液和固体膜中的最大荧光发射波长分别在332～390 nm和359～439 nm范围;DSC分析结果表明,5个(口恶)二唑衍生物的起始吸热峰位于120～328 ℃之间,其中对称结构的(口恶)二唑衍生物显示了较高的熔融温度;由循环伏安图和相关计算结果表明,5个(口恶)二唑衍生物的还原电位位于-1.03～-0.98 V,其相应的最低非占有分子轨道能级(LUMO)在-3.71～-3.76 eV之间.     

含喹噁啉环的化合物改性聚己内酰胺

合成了14种由三种含喹(哑心)啉环的芳香化合物改性的聚己内酰胺(MC尼龙),并对其形态、抗冲击强度、吸水性及熔融行为等进行了表征。聚苯基单醚喹(哑心)啉(PPQ)单模型化合物对MC尼龙结晶部分几乎没有影响。少量(0.005—5.0％)吩嗪的引入使MC尼龙的颜色、形态及性能等发生巨大变化,改性体系被认为是氢键相互作用,PPQ双模型化合物的改性作用介于二者之间。     

由5-唑烷酮合成α-天冬氨酰肽类的简便方法(英文)

用一锅法制得了２－三溴甲基－３－甲酰基－５－氧－４－口恶唑烷乙酸，它与氨基酸酯反应形成题称化合物Ｎ－甲酰基－α－天冬氨酰肽类。     

Risk models for the Prize Collecting Steiner Tree problems with interval data

Given a connected graph G=(V,E)with a nonnegative cost on each edge in E,a nonnegative prize at each vertex in V,and a target set V′V,the Prize Collecting Steiner Tree(PCST)problem is to find a tree T in G interconnecting all vertices of V′such that the total cost on edges in T minus the total prize at vertices in T is minimized.The PCST problem appears frequently in practice of operations research.While the problem is NP-hard in general,it is polynomial-time solvable when graphs G are restricted to series-parallel graphs.In this paper,we study the PCST problem with interval costs and prizes,where edge e could be included in T by paying cost xe∈[c e,c+e]while taking risk(c+e xe)/(c+e c e)of malfunction at e,and vertex v could be asked for giving a prize yv∈[p v,p+v]for its inclusion in T while taking risk(yv p v)/(p+v p v)of refusal by v.We establish two risk models for the PCST problem with interval data.Under given budget upper bound on constructing tree T,one model aims at minimizing the maximum risk over edges and vertices in T and the other aims at minimizing the sum of risks over edges and vertices in T.We propose strongly polynomial-time algorithms solving these problems on series-parallel graphs to optimality.Our study shows that the risk models proposed have advantages over the existing robust optimization model,which often yields NP-hard problems even if the original optimization problems are polynomial-time solvable.     

仿紧集上的拟变分不等式

本文利用T－γ－对角凹函数和我们得到的一类极大极小不等式研究了仿紧集上的拟变分不等式．     

Consecutive-(r,f,k)out-of-n:F和Consecutive(f,g)-out-of-(r,n):F线性系统的可靠性

Consecutive-(r,f,k)-out-of-n:F系统由n个单元顺序连结而成,仅当在连续的r个单元中,至少有f个失效或者至少连续k个失效,整个系统才失效;而Consecutive-(f,g)-out-of-(r,n):F系统由n个单元顺序连结而成,仅当在整个系统中至少有f个失效或者在连续的r个单元中,至少有g个失效,整个系统才失效。本文运用马氏链嵌入方法,在单元之间相互独立以及单元之间马氏相关这两种情况下,给出线性系统的可靠性。     

On Polynomial Representations of Lie Algebras

We study polynomial representations of finite dimensional (R or C) Lie algebras. As a total classification, we show that there are altogether three types of such nontrivial representations and give their subtle structures.