p型导电掺In的SnO_2薄膜的制备及表征

采用溶胶 凝胶提拉法成功地制备了p型导电掺In的SnO2 薄膜 .x射线衍射测试结果表明 ,掺In的SnO2 薄膜保持SnO2 的金红石结构 .吸收谱测试结果表明 ,掺In的SnO2 禁带宽度为 3 8eV .霍尔测量结果表明 ,空穴浓度与热处理温度有很大的关系 ,5 2 5℃为最佳热处理的温度 .铟锡原子比在 0 0 5— 0 2 0范围内 ,空穴的浓度与In的含量有直接的关系 ,并随In含量的增加而增加     

具有非单调功能反应和脉冲扰动的捕食系统的研究

研究捕食者具有非单调功能反应和周期脉冲扰动的捕食者一食饵系统，利用脉冲微分方程的Floquet理论和比较定理，得到了系统灭绝和持续生存的充分条件．最后，通过数值模拟阐明系统在周期脉冲扰动下的复杂性．     

关于态射的Drazin逆

给出了态射的Drazin逆存在的条件及显式表达式，改进并推广了[1]、[2]与[3]中的一些主要定理。     

Energy Density in Quark-Gluon Plasma

We study the energy density in quark-gluon plasma. At the very high temperature, the quark matter is a hot and dense matter in the colour deconfinement condition, and quarks can coalescent diquarks. Energy density of this system is worked out and compared with the energy density in the other two kinds of situations. Possible energy density is about ε0≈2.4 GeV/fm^3 according to our estimation for quark matter including diquarks.     

高功率固体激光放大系统相位自校正方法研究

就光学元件间低频相位误差叠加提出用相关系数作为叠加相位结果的估计参量，并通过模拟计算和验证实验证明了相关系数能有效地对低频相位叠加结果进行比较估计，在此基础上就高功率固体激光放大系统中放大片的选取和安装提出了自校正方法并实现了自校正过程。     

Self-assembly behaviour of amphiphilic diblock copolymer in selective solvents studied by synchrotron small-angle x-ray scattering

The aggregation behaviour of styrene-vinyl benzoic acid (PSm-b-PVBAn) amphiphilic diblock copolymers in selective solvents with different m and n was investigated by synchrotron small-angle x-ray scattering (SAXS). We have carried out a detailed analysis of scattering intensity, dimension, shape and microstructure of the diblock copolymers of narrow distribution in water, methanol, ethanol and isopropanol selective solvents, respectively. We have found that the aggregation behaviour of the copolymer depends on the nature of the solvent and the micelle forms fiat disc objects with the ratio of radius ω=0.4. The average radius gyration Rg of the copolymer decreases as solvents change from isopropanol to ethanol and to methanol, and increases with increasing pH in aqueous solution, but decreases with the addition of COCl2 in ethanol solvent. The scattering intensity of diblock copolymer micelle follows I(h) ∝ h^-α in different selective solutions, suggesting that the PSm-b-PVBAn coils have self-similar structure behaviour or a fractal structure in the selective solvents. All of these revealed that the aggregation behaviour of the diblock copolymer changes dramatically with experimental condition in the selective solvent. The increase of mass fractal dimension (Dm) from 2.12 to 2.47 indicates that the copolymer chain changes from a swollen coil to a rather compact disc in the course of changing solvents, decreasing surface fractal dimension (Ds) from 2.98 to 2.58 indicates that the copolymer micelle change from a rather rough surface to a smooth form in the course of increasing pH in aqueous solutions, and increasing Dm and Ds from 2.29 to 2.35 and 2.70 to 2.90, respectively, indicates the shrinkage of copolymer micelle to a rather compact and rough disc form by adding COCl2 in ethanol solvents.     

二氧化碳和丙烯直接合成甲基丙烯酸的NiPMo/TiO2催化剂的研究

用溶胶 凝胶法以磷钼酸 (MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2 催化剂 .使用ICP、XRD、TG DTA、IR、TPD MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能 .杂多钼酸盐与TiO2 通过O2 -在TiO2 表面发生了键合 .在 6 2 3K下 ,杂多阴离子仍保持原有的Keggin结构 .CO2 在Lewis酸位Ni(Ⅱ )和Lewis碱位Ni-O -Mo的桥氧协同作用下生成CO2 卧式吸附态Ni(Ⅱ )←O - (CO)← (O--Ni) .丙烯有多种吸附态在催化剂上吸附 .在 5 6 3K、1MPa和空速 15 0 0h-1的反应条件下 ,丙烯的摩尔转化率为 3.2 % ,产物MAA选择性为 95 % .     

二阶导数光谱-峰面积积分法同时测定芦荟中痕量铁(Ⅱ)和钴(Ⅱ)

在 1,10 -邻菲罗啉显色体系中 ,引入二阶导数光谱 -峰面积积分技术 ,建立了同时测定痕量铁 ( )和钴 ( )的新方法。该法可有效消除共存离子的干扰 ,提高了准确度和灵敏度。对铁和钴的表观摩尔吸光系数分别为 εFe5 .4 5× 10 6 L·mol-1·cm-1,εCo 1.1× 10 4 L· mol-1· cm-1;铁含量在 0 .0— 8.5 μg·m L-1,钴含量在 0 .0— 7.3μg· m L-1范围内遵守比耳定律。可用于芦荟中铁和钴的同时测定 ,结果令人满意     

可调谐液晶法-珀滤光片的研究

提出了一种可用于密集波分复用系统中的新型可调谐滤光片的设计方法,该设计利用了液晶的双折射现象,以及液晶盒内法-珀效应,从理论上分析了器件的光谱特性,计算了液晶分子的折射率调制和其分子转动角度的关系.并对器件进行了性能测试.实验结果与理论吻合较好.     

SO^-（^2B1）离子的结构与势能函数

用二次组态相互作用方法，在6-311G(d)基组水平上对SO2^-离子进行了理论计算，得到了它的结构、能量、谐振频率和力学性质，其结果与实验值符合得非常好．在此计算的基础上，应用多体展式理论方法推导出SO2^-离子的解析势能函数，该函数正确反映了SO2^-离子的结构特征和能量变化．