Effect of Alkali Treatment on the Structure and Catalytic Properties of ZSM-5 Zeolite

Catalytic properties of ZSM-5 zeolite samples pretreated with NaOH solution have been investigated. The samples are characterized by XRD, SEM, chemical analysis, and N2 adsorption.The results indicate that mesopores are created in ZSM-5 crystals under alkali treatment without change the microporous structure and acidic strength of the zeolite, but the crystallinity is greatly decreased under severe treatment. IR indicates that the concentration of silanol is greatly enriched by alkali treatment. The etherification activities of ZSM-5 zeolites are greatly increased byalkali-treatment. The noticeably improved catalytic activity of treated samples is ascribed to the formation of mesopores and greatly enriched silanol group.     

丙醛的等离子体聚合以及聚合物的结构与性质初探

应用外部电容耦合式等离子体聚合方法,制得了丙醛聚合物,研究了不同的等离子体条件对丙醛的聚合行为的影响。通过元素分析、红外光谱分析、色谱-质谱联合分析、X-射线衍射、润湿性测定等手段研完发现,聚合物为无定形交联结构,表面能为41—45达因/厘米。     

苯硫酚等离子体聚会及其结构与性能

应用外部电容耦合式等离子体聚合装置．研究了苯硫酚等离子体聚合规律，找到了最佳聚合条件，通过热失重、红外光谱、X－射线衍射、电子衍射、GC－MS和接触角测定等研究了聚合物结构与性能。电导率测定表明等离子体聚苯硫酚具有半导体性质。     

氧化锡表面的原子簇模型计算

Cluster models of SnO2(110) face and oxygen vacancies and oxygen adsorption on its surface have been calculated by EHMO method. The results show that a tin atom with a coordination number of four is the adsorption center, because the total energy of cluster model becomes lower when an oxygen atom adsorpts on the tin atom with a coordination number of four. The tin atom with this coordination number gains and loses electrons more easily than tin atoms with a coordination number of five. All tin atoms in the cluster of SnO2(110) face are Sn4+.     

Synthesis,Structure Analysis,and Antitumor Activity of （R）-2,4-Dioxo-5-fluoro-l-[1-（methoxycarbonyl） Ethylaminocarbonylmethyl]-1,2,3,4-tetrahydropyrimidine

A new dipeptide compound, （R）-2,4-dioxo-5-fluoro-1-[1-（methoxycarbonyl） ethylaminocarbonylmethyl]-1,2,3, 4-tetrahydropyrimidine （5-FUAPM）, has been synthesized and identified by means of elemental analysis, IR, ^1H NMR and ^13C NMR spectra. The single crystal of compound 5-FUAPMoDMF was also obtained and characterized by DSC-TGA techniques. The crystal belongs to orthorhombic space group P212121 with the cell parameters： a= 0.4740（7） nm, b= 1.923（3） nm, c= 1.9229 nm, a=β=y=90°, V= 1.753 nm^3, Z=4, Dc= 1.312 g/cm^3, Mr=346.32, F（000）=728 and u=0.111 mm^-1. The final R and wR are 0.1378 and 0.2862, respectively. The result of the biological test showed that the compound 5-FUAPM has certain antitumor activities.     

Synthesis and Structural Characterization of Gd（Ⅱ） Coordination Polymer [Gd2（μ-phth）3（b-pd）（H2O）5]n

1 INTRODUCTION The polymeric metal complexes with extended structures are of great interest because of their useful chemical or physical properties[1]. Due to the noti- ceable fact that the aromatic polycarboxylate can provide versatile coordination mode and the non- coplanar structure of carboxylate groups and benze- ne rings, a lot of efforts in this field have been parti- cularly directed to the preparation of aromatic poly- carboxylate (such as phthalate, terephthalate and isophthalat…     

Synthesis,X—Ray Structure and Characterization of a Triruthenium Cluster Complex Ru^Ⅲ3（μ3—O）（μ—CH3COO）6（py）2Cl with Four Steps One—electron Redox Processes

The synthesis and crystal structure of oxo-centered carboxylate-bridge trinuclear ruthenium complex,Ru3O(CH3OO)6(py)2Cl(py=pyridine)(1),are reported herein.The complex 1 has been characterized by IR,cyclic voltammetry (CV),UV-Vis and X-ray crystal analysis.The complex 1 in 0.1 mol/L (n-C4H9)4HPF6-CH2Cl2 solution at room temperature shows four oneelectron redox processes at E1/2=-1.38,1.20,-0.17 and 1.07V vs. Ag/AgCl.     

单氧代-二硒烷基-1, w-二氧取代杯[4]衍生物的合成,结构及萃取性能研究

Novel macrocyclic monooxa-diselkylene-1,ω-dioxy substituted calix[4]arene derivatives 1a-5a were synthesized by the reaction of calix[4]arene dibromides 1-5 with the disodium salt of bis（2-selenylethyl）ether in the yields between 28% and 64%. Their structures were characterized by proton and carbon NMR spectra. X-Ray structure analysis of la further confirmed the cone conformation of compounds 1a-5a. An interesting host-guest complex of la with dichloromethane via CH/π and C1/π interactions was elucidated. Extraction experiments showed that these novel monooxa-diselkylene-1,ω-dioxy substituted calix[4]arene derivatives 1a-5a had strong extraction ability towards mercury ion. The interaction of Hg^2＋with the calix ligand has also been investigated by 1^H NMR titration.     

基于双尺度渐近分析的有限元算法

1．引言正如文山所说，由于复合材料和周期结构的材料系数ail（x）在局部区域内间断且跳跃性很大，加上区域内含有周期性洞穴或裂缝，且周期长度很小．一般而言，直接采用有限元方法进行数值模拟，其计算量大得惊人，甚至难以实现．文山针对这种特征，提出了一种可计算的双尺度渐近分析模式，本文在此基础上给出了相应的有限元算法，它包括：1．周期解在一个基本构造上的有限元计算；2．边界层的有限元计算．同时，给出了相应的误差分析．2．周期解的有限元计算首先考虑下列形式的边值问题；其中把，代E尸（on叫，iii（0关于E—（EI，ZZ…     

黑米花色苷酰化修饰红外光谱分析

黑米花色苷易受外部环境影响发生降解致使局部分子结构破坏而使营养价值和保健功能有所下降。利用有机酸提供酰基对黑米花色苷进行修饰来提高花色苷结构的稳定性。利用红外光谱分析经咖啡酸酰化修饰黑米花色苷的结构变化。结果表明：黑米花色苷酰化修饰前后于官能团区3 650~3 200和1 680~1 620 cm-1处均有吸收峰，且其于指纹区1 282.68和1 277.51 cm-1处出现酚羟基吸收峰，于1 056.07和1 054.03 cm-1处出现醇羟基吸收峰，719.90和719.71 cm-1处出现苯环上C-H面外弯曲振动吸收峰。由此可见，黑米花色苷酰化修饰后主要结构框架仍为花色苷的芳环结构。此外，黑米花色苷酰化修饰前后于1 900~1 650 cm-1间1 714.28和1 728.13 cm-1处均出现共轭羰基的特征吸收峰，对应于可直接连接在苯环上的α-羰基结构，由此说明黑米花色苷结构中存在着酰基基团。黑米花色苷经酰化修饰后红外图谱于1 517.20 cm-1处出现新吸收峰，其正好处于1 800~900 cm-1双键(不含氢)伸缩振动区，指纹区876.65 cm-1处亦出现了苯环上的C-H面外弯曲振动吸收峰。与之相呼应在经二阶导数处理后红外光谱图中在2 500～2 000 cm-1间出现了新的波动，此波段为累积双键伸缩振动区，而官能团区3 650~3 200 cm-1间3 370.20 cm-1处的吸收峰正好处于多分子缔合区。由此可见，在咖啡酸作为酰基供体，酰化修饰黑米花色苷时由于分子间的重新缔合于结构中引入了新的酰基基团而呈现出一种双酰化的空间结构。黑米花色苷酰化结构中有机酸与糖链相连，将有机酸置于2-苯基苯并吡喃骨架的表面，这种堆积作用模式可以较好地抵抗水的亲核攻击和其他降解反应进而提高黑米花色苷结构的稳定性。