新型双光子吸收化合物的合成、光物理及其在固态分散体系中的性质

通过多步反应制备了三个新型的双光子吸收化合物,测试了它们的光物理性质,发现该系列化合物具有较大的双光子吸收截面,并且随温度降低其双光子吸收截面增大.尤其是化合物TMVDB,其量子效率为0.83,常温时的双光子吸收截面达到1164GM,其双光子吸收截面除以分子量为2.08,表现出了优良的双光子吸收发光性能.进一步将TMVDB掺杂到固体材料中,得到强双光子诱导发光的固体材料.     

Chemical composition of the lunar surface from neutron leakage fluxes

The neutron leakage fluxes from the lunar surface are calculated by Monte Carlo transport code based on Geant4. The integral fluxes of fast neutrons, epi-thermal neutrons and thermal neutrons are analyzed. Numerical results for 20 kinds of lunar soils and 7 minerals show that the fast neutron fluxes are linearly related to the average atomic mass numbers of the lunar materials used in simulations. Meanwhile, the average atomic mass numbers are strongly modulated by the abundances of iron (Fe) and titanium (Ti), and a linear relationship between the average atomic mass numbers and the abundances of Fe and Ti is found. Furthermore, the results show that the ratios of epi-thermal to thermal fluxes for lunar soils are linearly related to the macroscopic absorption cross sections of lunar materials, and that the macroscopic absorption cross sections monotonically increase with the abundances of Fe and Ti by a simple function. Then we reach the conclusion that the neutron fluxes can provide the information about the Fe and Ti contents.     

3.4μm处NO2吸收光谱特性及在差分吸收激光雷达中的应用

为使中红外差分吸收激光雷达能够精确测量NO_2气体浓度,对NO_2在中红外波段的吸收光谱特性进行测量分析.采用光参量放大激光器的λon和光参量振荡激光器λoff两路激光分别进行吸收谱线测量实验.用谱线宽小于0.05nm的λon激光测量了NO_2气体在3 410～3 433nm的吸收光谱,计算得到其吸收截面,采集分析了NO_2在291K、308K、363K三个温度下的光谱特性,用谱线宽约为10nm的λoff激光采集了3 400～3 435nm的吸收谱线.测量结果表明,在3 410～3 433nm波段,温度和吸收截面值呈负相关,测量的谱线与HITRAN数据库相关系数达到0.92以上;针对λoff激光下的吸收谱线,采用了改进的卷积修正方法,测量结果和拟合结果相关系数为0.97.将实测的on和off波长处的吸收截面应用于使用该波长对的中红外差分吸收激光雷达仿真上,拟合差分吸收激光雷达系统浓度测量误差,验证了基于该波长对的差分吸收激光雷达方案的可行性.     

核内△吸收截面

在相对论BUU方程框架内给出计算核内△吸收截面的严格公式.研究了核内△N→NN散射截面的介质效应,发现阈能附近的△吸收截面在介质中被压低.数值结果与TAPS实验组的最新实验结果符合得很好.     

乙醛（CH3CHO）水溶液的荧光特性

通过实验研究了乙醛（ＣＨ３ＣＨＯ）水溶液的荧光特性，测定了室温下乙醛１０％水溶液的吸收谱、在λ＝３５５ｎｍ处的表观吸收截面σ以及该溶液在不同浓度和不同温度下的荧光谱。实验发现，当激光的激励强度大于１０２３光子数／ｃｍ２ｓ时，乙醛水溶液的相对荧光效率渐趋饱和。     

非对称双极性(D-π-A)吡啶Salophen席夫碱锌/镍配合物的合成、表征、线性及非线性光学性质研究

通过Still偶联反应合成了吡啶取代的香草醛(1a和1b)。以过渡金属离子(Zn²⁺和Ni²⁺)作为模板,以单亚胺席夫碱2和吡啶基香草醛为原料合成和表征了新的非对称双极性(D-π-A)Salophen金属配合物(3a、3b和3c)。测定了这些金属配合物的线性和三阶非线性光学(双光子吸收,TPA)性质。双极性的Salophen金属配合物的发射光谱在可见光范围内(486~516nm),荧光寿命4.51ns~5.18ns,荧光量子产率在4.3%~5.3%之间。衰减时间测试表明,荧光寿命是在纳秒级范围,这表明该发射来自单线态。对这些化合物进行了热重分析,结果表明3a、3b和3c都是热稳定的,起始分解温度(T_d)为333~374℃。使用开孔Z-扫描方法在800nm处用100fs脉冲的激光对这些双极性的Salophen金属配合物的TPA截面σ⁽²⁾进行了测试,最高可达1403GM,其值为目前已知席夫碱金属配合物较高值之一。测试表明,锌的Salophen金属配合物具有良好的荧光量子产率、巨大的TPA截面σ⁽²⁾、很高的热稳定性以及锌配合物公认的低毒性。因这些配合物可以被近红外或红外波长的光激发,这种光可以有效地穿透生物组织同时减轻细胞损伤,所以Salophen锌配合物作为双光子荧光发色团在生物体成像中有潜在的应用。     

泵浦-探测实验影响因素的研究

结合泵浦-探测技术在材料非线性光学特性测量中的应用,介绍了影响泵浦-探测实验结果的几个因素,如样品厚度、样品距泵浦光会聚透镜焦点的距离、泵浦光强度等。通过40ps脉冲条件下的C60-甲苯溶液的实验结果证实了在满足薄样品近似条件下,使用厚一点的样品获得的泵浦-探测信号较大;样品放置距离泵浦光会聚透镜焦点较近时,泵浦-探测信号较大;在一定的泵浦光强范围内,泵浦光强度增大,泵浦-探测信号会随之增强。同时,对这几个因素影响实验结果的原因给与了简单解释。这些结论对于应用泵浦-探测技术探索材料非线性光学特性的物理本质具有实际的指导意义。     

Static and Ultrafast Transient Photophysics of Mono- and Dual-Branched Triarylamines

Mono- and dual-branched molecules, { 4-[2-（4-benzothiazol-2-yl-phenyl）-vinyl]-phenyl}-（4-methoxy-phenyl）-phenyl- amine （BS1） and bis-{4-[2- （4-benzothiazol-2-yl-phenyl）-vinyI]-phenyl}-（4-methoxy-phenyI）-phenyl-amine （BS2）, are investigated with one- and two-photon static spectroscopy, and the femtosecond fluorescence up-conversion technique. The molecules show branch-based fluorescence emission at low quantum yield. U1trafast non-radiative decay on a picosecond time scale is found and is attributed to intramolecular charge-transfer bridged by the central triphenylamine. The two-photon absorption cross-sections of BS1 and BS2 are 19.1 and 19.4 GM, respectively.     

Absorption Cross Section of Static Einstein-Maxwell Dilation Axion Black Hole for Scalar Particles

The absorption cross section of the static Einstein-Maxwell dilaton axion （EMDA） black hole for scalar particles is investigated. It is shown that the ratio of the absorption cross section of the EMDA black hole to that of the Schwarzschild black hole decreases as the absolute value of the dilaton increases, and it becomes zero as the dilaton tends to its extremal value. It is also shown that the absorption cross section decreases as both the v and the absolute value of the dilaton increase, and it decreases as the mass of the particle decreases.