Synthesis and Photocytotoxicity of Mono-functionalised Porphyrin with Valine Moiety

A mono-funtionalised tetraphenylporphyrin (TPP) bearing valine moiety at the phenyl ring was synthesized for photocytotoxicity examination in four steps, starting from regiospecific mono-nitration of TPP at the phenyl ring. The in vitro photocytotoxicitic effect against SPC-Al adenocarcinona cell line was tested.     

Crystal Structures of Two Potential Tumor Imaging Agents and Therapeutic Agents Copper（Ⅱ） Ternary Complexes with Salicylidene-tyrosinato Schiff Base and Nitrogen-donor Chelating Lewis Base

The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents.     

一类对称三对角矩阵的合同对角化算法的实现

从一个对称三对角矩阵的合同变换出发 ,阐述了对称三对角矩阵对应的二次型标准化的一种方法 .     

Theoretical Calculation of Rotational Bands of ^179Pt in the Particle-Triaxial-Rotor Model

Theoretical calculations have been performed for nucleus ^179Pt in the particle-triaxial-rotor model with variable moment of inertia. The obtained energy spectrum agrees with the experimental data quite well. The calculated results indicate that the bands 1/2^- and 7/2^ are triaxial deformation bands and originate mainly from the v[521]1/2^- and v[633]7/2^ configurations respectively.     

Theoretical Study on the Rotational Bands and Shape Coexistence of^179，181，183Au in the Particle-Triaxial-Rotor Model

We perform a series of theoretical calculations and investigation for nuclei 179，181，183Au in the particle-triaxialrotor model with variable moment of inertia. The calculated energy spectra in^179,181,183Au agree well with the experimental data globally. The obtained results indicate that the nuclei^179,181,183Au have prolate deformation and involve shape coexistence with different deformation parameters in different bands. The main configuration of bands 1, 2, 3 and 5 in these nuclei are identified as [541]1/2^- (πh9/2, α = 1/2), [541]1/2- (πh9/2, α= -1/2),[530] 1/2- (πf7/2) and [660] 1/2^ (πi13/2), respectively.     

164Lu的三轴超形变核态的研究

利用TRS方法对双奇核¹⁶⁴Lu的位能面进行了计算,确认了¹⁶⁴Lu核的一条三轴超形变带,结果与实验较好地符合,同时指出了三轴超形变带的一个具体的组态     

多官能团分枝状化合物的合成研究 Ⅳ.三方向醚-酰胺键型分枝状大分子的合成

本文报道三方向醚-酰胺键型多官能团分枝状大分子(Cascade)的合成.目标化合物以甘油、硝基甲烷为三方向起始核心,以从季碳原子三倍对称分散的化合物1～3为分支侧链.通过醚键进行空间延伸,以酰胺键进行分枝连接,经过一代或两代,所合成的分枝状大分子的末端官能团数是原起始核心的三倍或九倍.本文可为进一步的分枝反应提供基本的设计合成方法.     

KDP晶体三倍频实验和分析

报道了ＫＤＰ晶体中的三倍频产生的实验研究，计算了比较了直接三倍频过程和级联过程对ＫＤＰ晶体三阶有效非线性系数的贡献，并探讨了ＫＤＰ作为非线性晶体材料三阶非线性系数测量基准的可行性。     

关于三商映射

三商映射是完备映射和开映射的共同推广。本文综述三商映射的理论，论术这三商映射，开映射，紧覆盖映射，诱导完备映之间的一些转换关系，提出了几个供进一步研究的问题。