Mg掺杂调制铜铁矿结构CuAlO2多晶的微结构和电热传导

采用固相反应法制备铜铁矿结构的CuAl_1-xMg_xO₂ (x=0、0.005、0.01、0.02、0.03、0.04)多晶,研究了Mg掺杂对CuAlO₂多晶结构和性能的影响。Mg掺杂量x从0增加到0.02,样品均为菱方R3m单相,密度依次提高;所有样品呈半导体的热激活电输运行为,x=0.02样品在室温下的电阻率是未掺杂样品的1/19,热激活能显著下降(x=0时,ρ_{300 K}~5.54 Ω·m,E_a~0.328 eV;x=0.02时,ρ_{300 K}~0.29 Ω·m,E_a~0.218 eV),载流子浓度增加1个量级,主要因为Mg²⁺取代Al³⁺,引入新的受主能级。x>0.02时,MgAl₂O₄尖晶石杂相出现,使其电导率和热导率降低。CuAl_1-xMg_xO₂多晶的晶格热导率在总热导率中占绝对优势,且随温度升高(300~500 K)而下降,晶格热导Callaway模型模拟表明,所有样品的热阻主要源于点缺陷-声子散射。与x=0相比,x=0.02样品的室温热导率增大1倍(κ~13.065 0 W/(m·K)),声速增大,点缺陷-声子散射减弱,分析认为掺Mg形成强的Mg—O键,提高了晶体的弹性模量和声子频率,减弱了本征点缺陷、Mg掺杂引起的质量波动和应变场波动对声子的散射,同时Mg掺杂样品的密度提高也有利于增加热导率。     

N,N′,N″—三(对—甲苯磺酰基)二亚乙基三胺的合成

二亚乙基三胺与对—甲苯磺酰氯在碳酸钾存在下,发生对甲苯磺酰化反应,生成N,N′,N″-三(对—甲苯磺酰基)二亚乙基三胺,产率96％。考察影响反应的几个因素。     

有机薄膜电致发光器件的光学微腔效应

制备了以铝掺杂氧化锌（ＡＺＯ）透明导电膜为阳极的有机薄膜电致发光微腔器件，研究了垂直的光学法布里－珀罗微共振腔对有机器件的自发发射的微腔效应，发出了光谱窄化、发光强度增加及发射的角度依赖关系等现象。具有微腔结构的器件发射谱将高宽只有１４display status     

Observation of a narrow hyperon state of mass 3.17 GeV

We present evidence for a narrow Y¹ with a mass of 3.17 GeV and a width ? 20 MeV decaying to ΣKK? + pions, ΛKK? + pions and ΞK + pions. The data come from two high statistics K^?p bubble chamber experiments with a sensitivity of ≈100 eV/μbat 8.25 GeV/c and ≈ 45 eV/μbat 6.5 GeV/c.     

Posterior Simulation with Priors Specified on Functionals

Abstract

Many Bayesian analyses use Markov chain Monte Carlo (MCMC) techniques. MCMC techniques work fastest (per iteration) when the prior distribution of the parameters is chosen conveniently, such as a conjugate prior. However, this is sometimes at odds with the prior desired by the investigator. We describe two motivating examples where nonconjugate priors are preferred. One is a Dirichlet process where it is difficult to implement alternative, nonconjugate priors. We develop a method that allows computation to be done with a convenient prior but adjusts the equilibrium distribution of the Markov chain to be the posterior distribution from the desired prior. In addition to allowing more freedom in choosing prior distributions, the method enables the investigator to perform quick sensitivity analyses, even in nonparametric settings.     

First Order Differential Operators Associated to the Cauchy—Riemann Operator in the Plane

The article deals with initial value problems of type δw/δt = Fw, w(0, ·) = φ where t is the time and F is a linear first order operator acting in the z = x ? iy-plane. In view of the classical Cauchy-Kovalevkaya Theorem, the initial value problem is solvable provided F has holomorphic coefficients and the initial function is holomorphic. On the other hand, the Lewy example [H. Lewy (1957). An example of a smooth linear partial differential equation without solution. Ann. of Math., 66, 155–158.] shows that there are equations of the above form with infinitely differentiable coefficients not having any solutions. The article in hand constructs, conversely, all linear operators F for which the initial value problem with an arbitrary holomorphic initial function is always solvable. In particular, we shall see that there are equations of that type whose coefficients are only continuous.     

Sound Velocity in Liquid Binary Alloys as Calculated via the Percus-Yevick Liquid Phonon Dispersion Relation

Abstract

In this note, we utilize the recently calculatd long wavelength limit of the “liquid virtual crystal” model of binary alloy liquid structure factor at the melting temperature, ST_M ^AB (0), to estimate the long-volume binary liquid alloys. We compare the calculate sound velocities to the available experimental sound velocities in these liquid binary alloys and find reasonable agreement.     

具有常数行重的一类d-析取矩阵的界

首先介绍了辛空间上子空间的一些包含性质,利用这些性质构作了一类具有常数行重的dλ-析取矩阵,然后给出了这类矩阵相关参数的界.     

钯催化下肟醚导向的sp~2 C—H键邻位酰氧化反应(英文)

使用醋酸钯作为催化剂,过硫酸钠和氧化银为氧化剂,使肟醚导向的底物与苯甲酰甲酸发生sp2C—H键的邻位酰氧化反应,从而得到芳香酮类化合物.该方法对带吸电子基和给电子基的反应物都有很好的适应性,最高产率可达98%.