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111.
E. García-Matres N. Stüßer M. Hofmann M. Reehuis 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,32(1):35-42
The magnetic structures of Mn1-xFexWO4 with x
= 0.0, 0.16, 0.21, 0.225, 0.232, 0.24, 0.27, 0.29, and 1.0 were refined from neutron powder diffraction data. The magnetic phase
diagram could be completed in the coexistence range of different magnetic structures up to x
= 0.29. For the magnetic state at 1.5 K a commensurate antiferromagnetic structure with a propagation vector
= (±1/4, 1/2, 1/2) was found for x
⩽ 0.22 while the magnetic spins order with
= (1/2, 0, 0) for x
≥ 0.22. In the latter phase, additionally, weak magnetic reflections indexed to an incommensurate ordering with
= (- 0.214, 1/2, 0.457) occur in the diffraction pattern up to x
= 0.29 indicating the occurence of a reentrant phase. For 0.12 ⩽
x
⩽ 0.29 the low temperature phases are separated from a magnetic high temperature phase showing only magnetic reflections indexed
to a spin arrangement with
= (1/2, 0, 0). The magnetic phase diagram is discussed qualitatively considering random superexchange between the statistically distributed
Mn2+- and Fe2+-ions in the coexistence range 0.12 ⩽
x
⩽ 0.29 of different magnetic structures related to those of pure MnWO4 and FeWO4.
Received 9 October 2002 Published online 14 March 2003 相似文献
112.
Photoinduced optical and second-order non-linear optical effects in the interfaces separating In2O3–SiON (O/N ratio equals 1) films doped with A1, Sn and glass substrates were investigated using the photoinduced optical second harmonic generation. The photoinduced effective second-order optical susceptibility deff (at λ=1.76 μm) shows a good correlation with the linear optical susceptibility, particularly with the shift of the absorption edge. The maximal response of the photoinduced optical response signal was observed for the pump–probe delaying time of 34 ps. The performed experimental measurements indicate that the observed effects are mainly caused by the interface potential gradients on the border glass–In2O3–SiON film and by additional polarization due to insertion of the Al and Sn atoms. The observed phenomenon may be proposed as a sensitive tool for investigation of thin semiconducting interfacial layers and simultaneously such films may be used as materials for non-linear optical devices. 相似文献
113.
Xuyuan GuScott Cowell Jinfa YingXuejun Tang Victor J. Hruby 《Tetrahedron letters》2003,44(31):5863-5866
(2S,3S)- and (2R,3R)-2-amino-3-phenyl-5-hexenoic acids have been synthesized in large scale by using Ni(II)-complexes as a template. The amino acids were used in the synthesis of [4,3,0]-bicyclic β-turn mimetics by a convergent methodology. The unique advantage of this strategy is the convenience of introducing side chain groups with predetermined chiralities on both the five- and six-membered heterocyclic rings. 相似文献
114.
Summary. We consider the spline collocation method for a class of parabolic pseudodifferential operators. We show optimal order convergence
results in a large scale of anisotropic Sobolev spaces. The results cover the classical boundary integral equations for the
heat equation in the general case where the spatial domain has a smooth boundary in the plane. Our proof is based on a localization
technique for which we use our recent results proved for parabolic pseudodifferential operators. For the localization we need
also some special spline approximation results in anisotropic Sobolev spaces.
Received May 17, 2001 / Revised version received February 19, 2002 / Published online April 17, 2002 相似文献
115.
116.
Yasufumi Hashimoto 《Journal of Number Theory》2007,122(2):324-335
In [P. Sarnak, Class numbers of indefinite binary quadratic forms, J. Number Theory 15 (1982) 229-247], it was proved that the Selberg zeta function for SL2(Z) is expressed in terms of the fundamental units and the class numbers of the primitive indefinite binary quadratic forms. The aim of this paper is to obtain similar arithmetic expressions of the logarithmic derivatives of the Selberg zeta functions for congruence subgroups of SL2(Z). As applications, we study the Brun-Titchmarsh type prime geodesic theorem and the asymptotic formula of the sum of the class number. 相似文献
117.
X.X. Guo 《Surface science》2004,549(3):211-216
We studied parallel conductivities of pure BaF2 films with thicknesses ranging from 35 to 300 nm, epitaxially grown on Al2O3(0 1 2) substrates by molecular beam epitaxy technique. The overall conductivities of the films are found to increase with decreasing thickness. The detailed investigation of the overall conductance as a function of the thickness permits the deconvolution of bulk and boundary effects, the latter being attributed to distinct space charge effects in the interface between BaF2 film and Al2O3 substrate. The (extrinsic) Debye length (λ) is estimated to be about 8 nm at T=593 K, which corresponds to an impurity content of 1018/cm3 (singly ionized dopant assumed). This is consistent with the fact that we observed a constant boundary contribution for all investigated films (film thickness >4λ). It is also consistent with the Debye length observed in a previous report on CaF2/BaF2 heterolayers fabricated by the same technique, in which the low temperature enhancement was also attributed to space charges in BaF2 [Nature 408 (2000) 946]. Only at low temperatures (below 370 °C), the conductance seems to be influenced by strain effect. 相似文献
118.
V. A. Petrosyan 《Russian Chemical Bulletin》1995,44(8):1353-1364
The results of studies on electrosynthesis involving carb- and heteroanions generated by cathodic deprotonation of acids (CDA), carried out in the laboratory headed by the author, are surveyed. These studies resulted in the elaboration of efficient electrochemical versions of the known Michaelis-Becker, Wittig-Horner, and Perkin reactions; electrochemical analogs of homolytic aromatic substitution, alkylation, heterocyclization,etc. were developed. Based on CDA, convenient and promising methods for preparing variousN-, O-, P-, S-, andC-alkylated and arylated substances have been developed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1411–1422, August, 1995.The author is grateful to Professor V. A. Dorokhov, Professor V. P. Litvinov, and researchers from the laboratories of N. D. Zelinsky Institute of Organic Chemistry headed by them, who participated in joint studies.The work was carried out with financial support from the International Science Foundation (Grant No. MHYOO). 相似文献
119.
The electronic states of the Cr overlayers on TiO2(0 0 1) surfaces have been investigated using angle-resolved and resonant photoemission spectroscopy with synchrotron radiation. At lower coverages, Cr deposition on TiO2(0 0 1) creates two well separated in-gap emissions due to the formation of surface Ti3+ (3d1) ions and Cr3+ (3d3) ions. At higher coverages, the in-gap emission is developed into the 2-peak-structure emission of Cr 3d character. The corresponding state is considered to be of metallic nature from the viewpoint of the high ability of oxygen adsorption, but has no Fermi edge, indicating a possibility of forming small Cr clusters on TiO2(0 0 1) at this stage. 相似文献
120.
Alexander G. Ramm Alexandra B. Smirnova Angelo Favini 《Annali di Matematica Pura ed Applicata》2003,182(1):37-52
A nonlinear operator equation F(x)=0, F:H→H, in a Hilbert space is considered. Continuous Newton’s-type procedures based on a construction of a dynamical system with
the trajectory starting at some initial point x
0 and becoming asymptotically close to a solution of F(x)=0 as t→+∞ are discussed. Well-posed and ill-posed problems are investigated.
Received: June 29, 2001; in final form: February 26, 2002?Published online: February 20, 2003
This paper was finished when AGR was visiting Institute for Theoretical Physics, University of Giessen. The author thanks
DAAD for support 相似文献