全文获取类型
收费全文 | 1943篇 |
免费 | 162篇 |
国内免费 | 157篇 |
专业分类
化学 | 1293篇 |
晶体学 | 1篇 |
力学 | 424篇 |
综合类 | 9篇 |
数学 | 85篇 |
物理学 | 450篇 |
出版年
2024年 | 1篇 |
2023年 | 13篇 |
2022年 | 45篇 |
2021年 | 49篇 |
2020年 | 60篇 |
2019年 | 46篇 |
2018年 | 34篇 |
2017年 | 40篇 |
2016年 | 82篇 |
2015年 | 56篇 |
2014年 | 64篇 |
2013年 | 119篇 |
2012年 | 107篇 |
2011年 | 119篇 |
2010年 | 101篇 |
2009年 | 105篇 |
2008年 | 87篇 |
2007年 | 119篇 |
2006年 | 118篇 |
2005年 | 118篇 |
2004年 | 106篇 |
2003年 | 77篇 |
2002年 | 74篇 |
2001年 | 55篇 |
2000年 | 56篇 |
1999年 | 31篇 |
1998年 | 57篇 |
1997年 | 44篇 |
1996年 | 39篇 |
1995年 | 28篇 |
1994年 | 45篇 |
1993年 | 22篇 |
1992年 | 32篇 |
1991年 | 20篇 |
1990年 | 23篇 |
1989年 | 14篇 |
1988年 | 9篇 |
1987年 | 10篇 |
1986年 | 5篇 |
1985年 | 9篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1982年 | 7篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1974年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有2262条查询结果,搜索用时 140 毫秒
1.
Dominik Vítek Prof. Aleš Růžička Lise Vermeersch Dr. Libor Dostál Dr. Jan Turek Prof. Roman Jambor 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(70):e202202639
Reactivity studies of the GeII→B complex L(Cl)Ge⋅BH3 ( 1 ; L=2-Et2NCH2-4,6-tBu2-C6H2) were performed to determine the effect on the GeII→B donation. N-coordinated compounds L(OtBu)Ge⋅BH3 ( 2 ) and [LGe⋅BH3]2 ( 3 ) were prepared. The possible tuning of the GeII→B interaction was proved experimentally, yielding compounds 1-PPh2-8-(LGe)-C10H6 ( 4 ) and L(Cl)Ge⋅GaCl3 ( 5 ) without a GeII→B interaction. In 5 , an unprecedented GeII→Ga coordination was revealed. The experimental results were complemented by a theoretical study focusing on the bonding in 1 − 5 . The different strength of the GeII→E (E=B, Ga) donation was evaluated by using energy decomposition analysis. The basicity of different L(X)Ge groups through proton affinity is also assessed. 相似文献
2.
An M/G/1 retrial queueing system with additional phase of service and possible preemptive resume service discipline is considered. For an arbitrarily distributed retrial time distribution, the necessary and sufficient condition for the system stability is obtained, assuming that only the customer at the head of the orbit has priority access to the server. The steady-state distributions of the server state and the number of customers in the orbit are obtained along with other performance measures. The effects of various parameters on the system performance are analysed numerically. A general decomposition law for this retrial queueing system is established. 相似文献
3.
4.
5.
6.
7.
The steady-state two-phase flow non-linear equation is considered in the case when one of phases has low effective permeability in some periodic set, while on the complementary set it is high; the second phase has no contrast of permeabilities in different zones. A homogenization procedure gives the homogenized model with macroscopic effective permeability of the second phase depending on the gradient and on the second order derivatives of the macroscopic pressure of the first phase. This effect cannot be obtained by classical (one small parameter) homogenization. To cite this article: G.P. Panasenko, G. Virnovsky, C. R. Mecanique 331 (2003). 相似文献
8.
将三阶微扰理论应用于单晶GaAs半导体,结合与实际相接近的能带结构,得到了GaAs中三光子吸收系数的解析式表达式,在考虑了激发电子的逃逸过程的情况下,进而推导了负电子亲和势GaAs光电阴极中三光子光电发射的发射系数的解析表达式.两表达式得到的理论数值分别与用ns量级脉宽、2.06μm波长的激光测得的GaAs中三光子吸收系数和GaAs(Cs,O)光电阴极中三光子发射系数的实验值相比较,吻合较好. 相似文献
9.
Mihai V. Putz 《International journal of quantum chemistry》2006,106(2):361-389
A unified Mulliken valence with Parr ground‐state electronegativity picture is presented. It provides a useful analytical tool on which the absolute hardness as well ionization potential and electron affinity functionals are based. For all these chemical reactivity indices, systematic approximate density functionals are formulated within density functional softness theory and are applied to atomic systems. For the absolute hardness, a special relationship with the new electronegativity ansatz and a particular atomic trend paralleling the absolute electron affinity are established that should complement and augment the earlier finite‐difference energetic approach. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2006 相似文献
10.
Relative permeability functions for immiscible displacements in porous media show a wide range of profiles. Although, this
behavior is well known, its impact on the stability of the displacement process is unexplored. Our analysis clearly demonstrates
for the first time that the viscous instability characteristics of two-phase flows are governed not only by their end point
values, but are strongly dependent on the actual profile of relative permeability functions. Linear stability analysis predicts
the capacity of the flow to develop large scale fingers which can result in substantial bypassing of the resident fluid. It
is observed that relative permeability functions attributed to drainage processes yield a more unstable displacement as compared
to functions related to imbibition processes. Moreover, instability is observed to increase for those relative permeability
functions which result from increased wettability of the wetting fluid. High accuracy numerical simulations show agreement
with these predictions and demonstrate how large amplitude viscous fingers result in significant bypassing for certain relative
permeability functions. In the nonlinear regime, the finger amplitude grows at a rate ∝ t1/2 initially, drops to t1/4 at a later time and finally grows ∝ t. The basic mechanisms of finger interaction, however, are not substantially influenced by relative permeability functions. 相似文献